Performance of Phosphotungstic Acid-Urea/Ferroferric Oxide Magnetic Oxidative Desulfurization Catalyst

doi:10.11944/j.issn.1000-0518.2015.03.140234

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (3): 317-321.DOI: 10.11944/j.issn.1000-0518.2015.03.140234

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Performance of Phosphotungstic Acid-Urea/Ferroferric Oxide Magnetic Oxidative Desulfurization Catalyst

SONG Pengyue^a, ZHU Jiang^a, YU Bohao^a, WANG Xuyang^a, YANG Jiao^a, LI Yumeng^a, LI Chuanpeng^b, YANG Xiaoyu^c, CHEN Lidong^{a, *}, JIANG Chunjie^{a, *}

^aFaculty of Chemistry and Chemical Engineering,Institute of Chemistry for Functionalized Materials,Liaoning Normal University,Dalian,Liaoning 110629,China
^bAnalysis and Testing Center,Beihua University,Jilin,Jilin 132013,China
^cPetroChina Dalian Petrochemical Company,Dalian,Liaoning 116032,China

Received:2014-07-03 Accepted:2014-11-05 Published:2015-03-02 Online:2015-03-02
Contact: Lidong CHEN,Chunjie JIANG
About author:Co-corresponding author:JIANG Chunjie, professor; Tel:0411-82156708; E-mail:jiangcj@lnnu.edu.cn; Research interests:synthesis and catalysis of polyacid, biomass conversion
Supported by:
Supported by the National Natural Science Fundation of China(No.21171082), Research Fund for the Doctoral Program of Liaoning Province(No.2013106)

Abstract

Abstract:

Oxidation catalysts of organic sulfide were synthesized by the ferromagnetic Fe₃O₄ matrix and phosphotungstic acid urea complexes(PAUC). The properties of products were characterized by IR, XRD, Raman and TG. With introduction of oxidation catalysts of organic sulfide, it is found that PAUC exists on Fe₃O₄ support in a Keggin structure and there is a chemical bond effect between them. If the H₂O₂ oxidation of ethanethiol proceeds in n-hexane, the oxidation activity of ethanethiol over ferromagnetic Fe₃O₄ matrix is increased in the presence of the PAUC. The effect of urea on activity has been discussed.

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Key words: phosphotungstic acid, magnetic iron oxide, ethanethiol, urea, hydrogen peroxide

CLC Number:

SONG Pengyue, ZHU Jiang, YU Bohao, WANG Xuyang, YANG Jiao, LI Yumeng, LI Chuanpeng, YANG Xiaoyu, CHEN Lidong, JIANG Chunjie. Performance of Phosphotungstic Acid-Urea/Ferroferric Oxide Magnetic Oxidative Desulfurization Catalyst[J]. Chinese Journal of Applied Chemistry, 2015, 32(3): 317-321.

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Performance of Phosphotungstic Acid-Urea/Ferroferric Oxide Magnetic Oxidative Desulfurization Catalyst

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