ON THE COORDINATION CONDITIONS OF AI IN MOLECULAR SIEVE SAPO-5

Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (4): 61-63.

• Report • Previous Articles Next Articles

ON THE COORDINATION CONDITIONS OF AI IN MOLECULAR SIEVE SAPO-5

Zhao Daqing¹, Qiu Shilun¹, Pang Wenqin¹, Jing Fengying², Wu Yijie², Xiao Yianwen²

1. Department of Chemistry, Jilin University, Changchun 130023;
2. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun

Received:1991-04-08 Revised:1991-08-20 Published:1992-08-10 Online:1992-08-10

Abstract

Abstract: The molecular sieves SAPO-5 have been synthesized by hydrothermal crystallization from Pr₃N-P₂O₅-Al₂O₃-SiO₂-H₂O-HF.Experiments of preparation conditions show that the key for the successful preparation of SAPO-5 lies in the formation of AlPO₄ gel.The ²⁷Al NMR results showed that in this case Al is four-coordinated.Tripropylamine was used as a template to stabilize tetrahedral Al and prevent it from attack of water.The EPMA analysis showed that an isomorphic substitution of P and A for Si occurs in SAPO-5 crystals.

Key words: molecular sieve, SAPO-5, preparation, hydrothermal crystallization, ²⁷Al NMR, EPMA

Zhao Daqing, Qiu Shilun, Pang Wenqin, Jing Fengying, Wu Yijie, Xiao Yianwen. ON THE COORDINATION CONDITIONS OF AI IN MOLECULAR SIEVE SAPO-5[J]. Chinese Journal of Applied Chemistry, 1992, 0(4): 61-63.

[1]	Jin LIN, Fang-Zhu WANG, Ling-Ling LYU. Preparation of Pseudo-boehamite from Industrial Materials and Its Application in Selective Hydrogenation of Isophorone [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 79-90.
[2]	Xian WANG, Xiao-Long YANG, Rong-Peng MA, Chang-Peng LIU, Jun-Jie GE, Wei XING. Atomic Dispersion Ir‑N‑C Catalysts for Anode Anti‑poisoning Electrolysis in Fuel Cell [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1202-1208.
[3]	Mei-Lun ZHANG, Hong-Ran LING, Zai-Chun SUN, Bing-Chu MEI, Wei-Wei LI. Research Progress on the Preparation Methods of BaMgF₄ Powders [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 900-911.
[4]	Li-Jun WU, Shou-Jie GUO, Chao ZHANG, Zhi-Sheng LI, Wei-Cong LI, Chang-Chun YANG. In⁃situ Electrochemical Preparation of Li⁃Na Alloy and the Co⁃storage of Li⁺ and Na⁺ Ions [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1757-1765.
[5]	XU Feng, ZHANG Kun, YIN Feng-Qin, XU Fei, PANG Yu-Xuan, CHEN Shi-Ting. Research Progress in Preparation and Application of Anion Imprinted Polymers [J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 123-135.
[6]	LI Lin, QIAN Si-Hua, LYU Tian-Qi, WANG Yu-Hui, ZHENG Jian-Ping. Recent Progress of Library Construction for Next-generation Sequencing [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 11-23.
[7]	GAO Siheng, YANG Yu, WU Jinling, QIN Lixia, KANG Shizhao, LI Xiangqing. Preparation and Photoelectric Performance of Graphene Oxide/Ultrafine Silver Composite [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 923-929.
[8]	FAN Zhe,ZHANG Shengsheng,TANG Jiahao,FAN Ping. Structure, Preparation and Application of Graded Nanomaterials [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 489-501.
[9]	WANG Yichen, LUO Jing, LIU Ren, DAI Shenghua. Progress in Preparation of Graphene Hollow Microspheres [J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1374-1383.
[10]	CHEN Chonglai, ZHANG Wenxia, QIU Jianping, JIA Aiping, LUO Mengfei. Catalytic Decomposition of Ozone by Manganese Oxide Supported on Cordierite Honeycomb Ceramics [J]. Chinese Journal of Applied Chemistry, 2020, 37(11): 1293-1300.
[11]	ZHU Zhaoyang, JIANG Aifeng, XIA Debin, WANG Ping, LIN Kaifeng, FAN Jizhuang, FAN Ruiqing, YANG Yulin. Stability of Aluminum Hydride Etherates and Its Solid-State Conversion to Alpha-Aluminum Hydride [J]. Chinese Journal of Applied Chemistry, 2019, 36(9): 1069-1075.
[12]	SU Fengmei, ZHANG Da, LIANG Feng. Progress in Preparation and Modification of Nano-catalytic Materials by Low-Temperature Plasma [J]. Chinese Journal of Applied Chemistry, 2019, 36(8): 882-891.
[13]	SHI Wenlu, QIAO Qingdong, LI Qi, REN Tieqiang, YU Tingyun. Alkylation of Benzene with Coal Oil to Heavy Alkylbenzene Catalyzed by Urea Modified β-Molecular Sieve [J]. Chinese Journal of Applied Chemistry, 2019, 36(3): 291-299.
[14]	LI Xiancai, TIAN Minglei, CHENG Yuwen, WANG Xiu. Preparation and Characterization of Yb Ion-Imprinted Polymers Based on MCM-41 Molecular Sieve Surface [J]. Chinese Journal of Applied Chemistry, 2019, 36(2): 203-211.
[15]	WU Xiangkun,ZHAN Qiushe,ZHANG Lan,ZHANG Suojiang. Progress on Microstructural Optimization and Controllable Preparation Technology for Lithium Ion Battery Electrodes [J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1076-1092.

ON THE COORDINATION CONDITIONS OF AI IN MOLECULAR SIEVE SAPO-5

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments