STUDIES ON WHITE POWDERY TUNGSTIC ACID ⅩⅧ.PREPARATION AND PROPERTIES OF DIMETHY SULFOXIDE COORDINATED MULTIVALENT METAL DECATUNGSTATES

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (6): 23-27.

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STUDIES ON WHITE POWDERY TUNGSTIC ACID ⅩⅧ.PREPARATION AND PROPERTIES OF DIMETHY SULFOXIDE COORDINATED MULTIVALENT METAL DECATUNGSTATES

Zhu Sisan, Yue Bin, Wu Xinguo, Wang Qilan, Gu Yidong

Department of Chemistry, Fudan University, Shanghai 200433

Received:1990-09-10 Revised:1991-01-03 Published:1991-12-10 Online:1991-12-10

Abstract

Abstract: The title compounds have been successfully prepared in DMSO-H2O medium from whitepowdery tungstic acid. They are DMSO coordinated decatungstates, exist as well definedcrystals: [M(Ⅰ)(DMSO)₄ (H₂O₂)]₂ [W₁₀O₃₂](M = Cu, Zn, Co, Ni),[(VO)(Ⅰ)(DMSO)₄(H₂O)]₂[W₁₀O₃₂] and [M(Ⅲ) (DMSO)₈]₄[W₁₀O₃₂]₃·8H₂O (M=Pr, Nd). The results ofelemental and thermal analyes, IR and UV spectra are presented. Their stabilities in solutionshave also been examined.

Key words: white powdery tungstic acid, dimethyl sulfoxide complex, metal decatungstate, preparation

Zhu Sisan, Yue Bin, Wu Xinguo, Wang Qilan, Gu Yidong. STUDIES ON WHITE POWDERY TUNGSTIC ACID ⅩⅧ.PREPARATION AND PROPERTIES OF DIMETHY SULFOXIDE COORDINATED MULTIVALENT METAL DECATUNGSTATES[J]. Chinese Journal of Applied Chemistry, 1991, 0(6): 23-27.

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STUDIES ON WHITE POWDERY TUNGSTIC ACID ⅩⅧ.PREPARATION AND PROPERTIES OF DIMETHY SULFOXIDE COORDINATED MULTIVALENT METAL DECATUNGSTATES

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