Research Progress of Layered Transition Metal Oxides Cathode Materials for Sodium-ion Batteries

doi:10.19894/j.issn.1000-0518.220320

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (4): 583-596.DOI: 10.19894/j.issn.1000-0518.220320

• Energy Materials • Previous Articles Next Articles

Research Progress of Layered Transition Metal Oxides Cathode Materials for Sodium-ion Batteries

Wen-Jun SHI, Zhong-Hui SUN(), Zhong-Qian SONG, XU-Jia NAN, Dong-Xue HAN, Li NIU()

Center for Advanced Analytical Science，School of Chemistry and Chemical Engineering，Guangzhou University，Guangzhou 510006，China

Received:2022-10-07 Accepted:2023-01-10 Published:2023-04-01 Online:2023-04-17
Contact: Zhong-Hui SUN,Li NIU
About author:lniu@gzhu.edu.cn；
cczhsun@gzhu.edu.cn
Supported by:
the National Natural Science Foundation of China(22204028);Guangzhou Science and Technology Plan Proiect(202201010245)

Abstract

Abstract:

Layered transition metal oxide cathode materials for sodium-ion batteries have the characteristics of low price and high specific capacity， which is an important support for energy transition in the future and has great development potential. In the process of charging and discharging， the typical layered oxide cathode materials with the most promising development and application will produce a series of changes affecting their electrochemical properties with the insertion and extration of sodium-ion. Therefore， the modification of cathode materials is particularly important. The current mainstream failure mechanism， modification methods， challenges and key problems to be solved in the future development are summarized and put forward.

Key words: Sodium-ion battery, Layered metal oxides, Cathode materials, Modification methods

CLC Number:

O646

Wen-Jun SHI, Zhong-Hui SUN, Zhong-Qian SONG, XU-Jia NAN, Dong-Xue HAN, Li NIU. Research Progress of Layered Transition Metal Oxides Cathode Materials for Sodium-ion Batteries[J]. Chinese Journal of Applied Chemistry, 2023, 40(4): 583-596.

Figures/Tables 9

Fig.1 Development of lithium ion and sodium ion batteries

Table 1 Comparison of physicochemical properties of sodium ions and lithium ions［25］

	Cationradius/nm	A_r/（g·mol^-1）	E/V（νs.SHE）	mp/℃	Capacity/（mA·h·g^-1）	Relative cost
Lithium ion	0.076	6.9	-2.71	180.5	3 829	1
Sodium ion	0.098	23	-3.04	97.7	1 165	0.7

Fig.2 Structure diagram and phase transition process of layered mental oxides［38］

Fig.3 （a） PXRD pattern for NVPF-NTP；（b）FT-IR；（c） High-resolution V2p XPS spectrum；（d） Rate capabilities from 0.1 to 40 C and the corresponding GCD curves；（e） The cycling stabilities at different rates of 1 C for 1000 cycles and 20 C for 2000 cycles；（f） The electrochemical performance of Sb-CNT//NVPF-NTP full cell［44］

Fig.4 （a） Capacity retentions as a function of cycle numbers；（b） The undoped P2-NM sample；（c） The conventional doped sample；（d） By forming high density of nanoprecipitates， the 3D network structure can effectively suppress bulk cracking［63］

Fig.5 （a） HEO cathode crystal structure evolution；（b） The evolution （003） peaks during the charge-discharge process；（c） Retention of the discharge capacity and Coulombic efficiency at rates of 3 C［29］

Fig.6 （a） Schematic structures of NLNFM and NLNFMB；（b） Contour maps of charge density on corresponding planes in NLNFM and NLNFMB［90］

Fig.7 （a） Cycle performances of pristine and ZnO-coated samples at a current density of 0.5 C；（b） Rate performances of pristine and ZnO-coated （molar ratio of Zn2+ and NNMO=0.01， 0.03， 0.05 and 0.07） samples at different current densities （0.1， 0.2， 0.5， 1， 2 and 0.1 C）； Specific capacity vs. voltage curves for the （c） pristine and （d） 5% ZnO-coated electrodes at different cycles at a current density of 0.5 C with corresponding capacity retention rate vs. cycle number［95］

Fig.8 Schematic illustration of byproducts on the surface of bare and NaPO3-coated Na2/3［Ni1/3Mn2/3］O2［96］

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Research Progress of Layered Transition Metal Oxides Cathode Materials for Sodium-ion Batteries

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