Research Progress of Carbon‑Encapsulated Iron‑Based Nanoparticles Electrocatalysts for Zinc‑Air Batteries

doi:10.19894/j.issn.1000-0518.210573

Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (10): 1488-1500.DOI: 10.19894/j.issn.1000-0518.210573

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Research Progress of Carbon‑Encapsulated Iron‑Based Nanoparticles Electrocatalysts for Zinc‑Air Batteries

Dan WANG, Xian-Biao HOU, Xing-Kun WANG, Zhi-Cheng LIU, Huan-Lei WANG, Ming-Hua HUANG()

School of Materials Science and Engineering，Ocean University of China，Qingdao 266100，China

Received:2021-12-21 Accepted:2022-04-20 Published:2022-10-01 Online:2022-10-05
Contact: Ming-Hua HUANG
About author:huangminghua@ouc.edu.cn
Supported by:
the National Natural Science Foundation of China(21775142);the Natural Science Foundation of Shandong Province(ZR2020ME038)

Abstract

Abstract:

Zinc-air batteries （ZABs） are regarded as one of the most promising candidates for a new generation of advanced energy conversion and storage devices， while the inferior activity and stability of air cathode electrocatalysts largely hinder the widespread application of ZABs. The extensive efforts for exploring and designing high active yet stable air cathode catalysts is， therefore， indispensable for the improvement of ZABs performance. Recently， carbon-encapsulated iron-based nanoparticles have been reported to exhibit excellent oxygen catalytic performance on account of their resistance to corrosion， oxidation， and aggregation under harsh conditions， and have been widely used as cathode materials for ZABs. As a result， we systematically summarize the applications of carbon-encapsulated transition metal iron-based materials as cathode catalysts for ZABs. In this review， the basic principle of ZABs and challenges faced by air cathode catalysts are firstly expounded. Then， the research progress of the carbon-encapsulated iron-based nanoparticles electrocatalysts （such as iron-based and its alloy， carbide， oxide and phosphide， et al.） are emphatically discussed and analyzed. Finally， the future development perspectives of carbon-encapsulated iron-based electrocatalysts in the applications of ZABs are put forward.

Key words: Carbon-encapsulated iron-based catalysts, Air cathode catalysts, Oxygen reduction reaction, Oxygen evolution reaction, Zinc-air battery

CLC Number:

O646.5

Dan WANG, Xian-Biao HOU, Xing-Kun WANG, Zhi-Cheng LIU, Huan-Lei WANG, Ming-Hua HUANG. Research Progress of Carbon‑Encapsulated Iron‑Based Nanoparticles Electrocatalysts for Zinc‑Air Batteries[J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1488-1500.

Figures/Tables 7

Fig.1 Schematic illustration of the principle of zinc air battery［16］

Fig.2 （a） Schematic illustration for the synthesis of HPCM-5［22］；（b） ORR polarization curves of HPCM-5 and Pt/C in O2 saturated 0.1 mol/L KOH electrolyte［22］；（c） Chronoamperometric curves for HPCM-5 and Pt/C at 0.5 V［22］；（d） Discharge polarization curves and corresponding power density of the zinc air batteries assembled as cathodes by HPCM-5 and Pt/C［22］；（e） Long-term discharge curves of zinc air battery based on HPCM-5 at a current density of 10 and 50 mA/cm2［22］；（f） Schematic illustration for the synthesis of CoFe@NC/CC［23］

Fig.3 （a） Schematic illustration for preparation of FeNi@NCNT-CP［24］；（b） Discharge polarization and power density curves of zinc air battery based on FeNi@NCNT-CP， Pt/C and IrO2， respectively［24］；（c） Schematic illustration for preparation of NiCoFe@N-CNFs［25］；（d） Schematic illustration for preparation of NPC/FeCo@NCNT［26］；（e） Galvanostatic charge-discharge cycling curves of zinc air battery assembled by NPC/FeCo@NCNT and Pt/C+RuO2 at 10 mA/cm2， respectively［26］

Fig.4 （a） Schematic illustration of the synthesis procedure for Fe@C-NG/NCNTs［27］；（b） Schematic illustration of the synthesis procedure for D-BNGFe-2-900［28］；（c） ORR polarization curves of D-BNGFe-2-900 and Pt/C［28］；（d） Galvanostatic charge-discharge cycling curves of zinc air batteries based on D-BNGFe-2-900∥NiFe-LDH@CF and Pt/C+RuO2 （40 min for one cycle） at 10 mA/cm2， respectively［28］；（e） Schematic illustration of the synthesis procedure for Fe7C3@FeNC［31］

Fig.5 （a） Schematic illustration of the fabricated process of Fe3O4@PCN［34］；（b） Schematic illustration of the fabricated process of Fe x @N/HCSs［36］；（c） Schematic illustration of the fabricated process of Fe3C/Fe2O3@NGNs［37］； The zinc air batteries performances with Fe3C/Fe2O3@NGNs and Pt/C+IrO2；（d） Specific capacity at current density of 20 mA/cm2［37］；（e） Discharge polarization and power density curves［37］；（f） Schematic illustration of the fabricated process of FeO x @N-PHCS［38］

Fig.6 （a） Schematic illustration for the synthesis of Fe2P/FeP-PNC［42］；（b） ORR polarization curves of Fe2P/FeP-PNC in 0.1 mol/L HClO4 electrolyte［42］；（c） Discharging polarization and corresponding power density curves with cathode catalysts of Fe2P/FeP-PNC［42］；（d） Schematic illustration for the synthesis of C-ZIF/LFP［43］；（e） Schematic illustration for the synthesis of FECNFS-NP［41］；（f） Polarization curves and corresponding power density curves of the zinc air battery with FECNFS-NP as the catalyst［41］；（g） Long-time discharge curves of the zinc air battery with FECNFS-NP as the catalyst［41］

Table 1 Performance comparison of carbon?encapsulated iron?based catalysts applied in zinc air batteries

分类 Classification	催化剂 Catalyst	电解液 Electrolyte	开路电压 Open circuit voltage/V	最大功率密度 Peak power density/ （mW·cm^-2）	循环次数 Cycle number	参考文献 Ref.
铁及合金纳米颗粒 Iron and ferroalloys nanoparticles	Fe@C?NG/NCNTs	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.37	101.2	297	［27］
	1.5FeNi@NCNT	6 mol/L KOH+0.2 mol/L ZnCl₂	1.44	114	100	［44］
	NiCoFe@N?CNFs	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.32	147	120	［25］
	Fe_1.2Co@NC/NCNT	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.43	194	300	［45］
	FeCo?N/C	6 mol/L KOH	-	89.9	140	［46］
	FeNi@NCNT?CP	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.551	200	250	［24］
	NPC/FeCo@NCNT	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.429	151.3	100	［26］
	FeCo@NC?g	6 mol/L KOH+0.2 mol/L ZnCl₂	1.456	190.2	120	［47］
	CoFe@NC?SE	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.58	102	288	［48］
碳化物纳米颗粒 Carbide nanoparticles	Fe/Fe₃C@NCNT?750	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	-	198	500	［49］
	D?BNGFe?2?900	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	-	142	610	［28］
	Fe?2?WNPC?NCNTs	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.43	101.3	200	［50］
	Fe₇C₃@FeNC	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.41	66.8	120	［31］
	Fe/Fe₃C@Fe?N_x?C	6 mol/L KOH	-	147	200	［51］
氧化物纳米颗粒 Oxide nanoparticles	4Fe₃O₄@PCN?800	6 mol/L KOH	1.423	156.8	-	［34］
	FeO_x@N?PHCS	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.41	93.6	25	［38］
	Fe₂₀@N/HCSs	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.57	140.8	-	［36］
	CoC_x/（Co_0.55Fe_1.945）₂P@C	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.50	131	60	［52］
	Fe?CNSs?N	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.27	106.8	-	［53］
	C?FePPDA?900	6 mol/L KOH	-	106	-	［32］
	Fe₃C/Fe₂O₃@NGNs	6 mol/L KOH	1.46	139.8	-	［34］
磷化物纳米颗粒 Phosphide nanoparticles	FeCo?P?2	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.415	205	-	［37］
	C?ZIF/LFP	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.5	140	-	［40］
	FeCNFs?NP	6 mol/L KOH+0.2 mol/L Zn（Ac）₂	1.4	97	-	［38］

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Research Progress of Carbon‑Encapsulated Iron‑Based Nanoparticles Electrocatalysts for Zinc‑Air Batteries

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