Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (9): 1069-1075.DOI: 10.11944/j.issn.1000-0518.2019.09.190032

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Stability of Aluminum Hydride Etherates and Its Solid-State Conversion to Alpha-Aluminum Hydride

ZHU Zhaoyangab,JIANG Aifenga,XIA Debina,WANG Pinga,LIN Kaifenga,FAN Jizhuanga(),FAN Ruiqinga,YANG Yulina*()   

  1. aMIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage,School of Chemistry and Chemical Engineering,Harbin Institute of Technology,Harbin 150001,China
    bScience and Technology on Aerospace Chemical Power Laboratory,Xiangyang 441003,China
  • Accepted:2019-04-23 Published:2019-09-05 Online:2019-09-05
  • Contact: Yulin YANG
  • Supported by:
    Supported by the National Key R&D Program of China(No.2017YFB1300104), the National Natural Science Foundation of China(No.21571042, No.21873025), and the Science Foundation of Aerospace(No.6141B0626020201, No.6141B0626020101)

Abstract:

The problem of whether α-AlH3 crystallized by aluminum hydride etherates(AlH3·nEt2O) stored for varying time is systematically studied. First, AlH3·nEt2O was prepared by a conventional method and stored under a nitrogen atmosphere for 1 to 20 days, and then α-AlH3 was prepared by a solid phase and vacuum crystallizing technique based on the AlH3·nEt2O. XRD, TGA and SEM analysis show that the ether composition gradually decreases during storage and α-AlH3 with higher purity can be prepared within 10 days of storage. However, after 10 days, γ-AlH3 with smaller particle size appeared. Finally, we confirm that the amount of ether in AlH3·nEt2O is directly related to the quality of prepared α-AlH3. Another highlight of this paper is the abandonment of the toxic reagent toluene used in conventional processes. This also provides a possibility for the kilogram preparation of α-AlH3.

Key words: aluminum hydride, preparation, storage