Colorimetric Sensors for Anion Recognition Based on Benzeneazophenol

doi:10.11944/j.issn.1000-0518.2019.12.190084

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (12): 1447-1455.DOI: 10.11944/j.issn.1000-0518.2019.12.190084

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Colorimetric Sensors for Anion Recognition Based on Benzeneazophenol

LIN Shengsheng^a,HE Qingyun^a,ZHOU Jiamin^a,ZHAO Mingpeng^a,FENG Zongcai^b,YU Biao^b,SONG Xiumei^a^b^*()

^aInstitute for Advanced Materials,Lingnan Normal University,Zhanjiang 524048,China;
^bSchool of Chemistry and Chemical Engineering,Lingnan Normal University,Zhanjiang 524048,China

Received:2019-04-01 Accepted:2019-07-11 Published:2019-12-01 Online:2019-12-10
Contact: SONG Xiumei
Supported by:
Supported by the National Natural Science Foundation of China(No.21805125), the Science and Technology Planning Project of Zhanjiang(No.2015A020203), and the Innovation and Entrepreneurship Training Program for College Students(No.201810579701)

Abstract

Abstract:

Three colorimetric sensors S1, S2 and S3 based on azobenzene containing different numbers of active phenolic hydroxyl groups have been designed and synthesized. The sensors in CH₃CN exhibit high sensitivity toward F^-, H₂PO4- and AcO^-. The detection limit of S1, S2 and S3 was determined to be 1.25×10^-73.62×10^-7 mol/L for F^-. The sensitivity of sensors S1, S2 and S3 for anions were affected by the configuration, charge density and basicity of anions. ¹H NMR titration has been performed to study reaction mechanism, which was considered to be direct consequence of hydrogen-bonding between the phenolic group of sensor and anion.

Key words: azobenzene, colorimetric recognition, anion, chemosensors, phenolic hydroxyl group

LIN Shengsheng, HE Qingyun, ZHOU Jiamin, ZHAO Mingpeng, FENG Zongcai, YU Biao, SONG Xiumei. Colorimetric Sensors for Anion Recognition Based on Benzeneazophenol[J]. Chinese Journal of Applied Chemistry, 2019, 36(12): 1447-1455.

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Colorimetric Sensors for Anion Recognition Based on Benzeneazophenol

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