Influence of Sodium and Potassium Ions on Dihydrogen Phosphate Anion Raman Spectra

doi:10.11944/j.issn.1000-0518.2020.07.200079

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (7): 823-829.DOI: 10.11944/j.issn.1000-0518.2020.07.200079

• Full Papers • Previous Articles Next Articles

Influence of Sodium and Potassium Ions on Dihydrogen Phosphate Anion Raman Spectra

ZHANG Yanping^a,b, XUE Dongfeng^a,b,*

^aState Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Acdemy of Sciences,Changchun 130022,China;
^bCollege of Applied Chemistry and Engineering,University of Science and Technology of China,Hefei 230026,China

Received:2020-03-19 Published:2020-07-01 Online:2020-07-07
Contact: XUE Dongfeng, professor; Tel:0431-85262294; E-mail:dongfeng@ciac.ac.cn; Research interests:multiscale crystallization of functional materials
Supported by:
Supported by the National Natural Science Foundation of China(No.51832007)

Abstract

Abstract: Dihydrogen phosphate anion (H₂PO^-₄) solution has important research value in biological buffering, molecular recognition and crystal growth. Taking KH₂PO₄ (KDP) and NaH₂PO₄ (NaDP) solutions as research objects, the influence of sodium and potassium ions on cluster aggregation and chemical bond vibration of H₂PO^-₄ solution was studied by in situ micro-Raman spectra. It was discussed that the difference of monovalent ions (K⁺, Na⁺) and the concentration of the solution played an important role in the Raman shift variation and nucleation induction time of H₂PO^-₄ vibration. The results show that the variation of Raman shift and the nucleation induction time increase with the increase of the solution-phase electronegativity of cations and the decrease of the concentration. In the Raman spectra, it is observed that the P(OH)₂ and PO₂ bands shift in the process of nucleation. It means that the cluster configuration is gradually stable and chemical bonding becomes clear, which deepens the understanding of solution structure and chemical bond during crystallization.

Key words: in situ Raman spectra, sodium ions, potassium ions, dihydrogen phosphate anion, solution crystallization, clusters, aggregation

ZHANG Yanping, XUE Dongfeng. Influence of Sodium and Potassium Ions on Dihydrogen Phosphate Anion Raman Spectra[J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 823-829.

References

[1] Warwick C, Guerreiro A, Soares A.Sensing and Analysis of Soluble Phosphates in Environmental Samples: A Review[J]. Biosens Bioelectron,2012,41(1):1-11.
[2] Kirby A J, Lima M F,da Silva D,et al. Efficient Intramolecular General Acid Catalysis of Nucleophilic Attack on a Phosphodiester[J]. J Am Chem Soc,2006,128(51):16944-16952.
[3] Wang X,Vorpagel E R,Yang X,et al. Experimental and Theoretical Investigations of the Stability, Energetics, and Structures of H₂PO^-₄, H₂P₂O^2-₇, and H₃P₃O^2-₁₀ in the Gas Phase[J]. J Phys Chem A,2001,105(45):10468-10474.
[4] Pluharová E,Oncák M,Seidel R,et al. Transforming Anion Instability into Stability:Contrasting Photoionization of Three Protonation Forms of the Phosphate Ion Upon Moving into Water[J]. J Phys Chem B,2012,116(44):13254-13264.
[5] Jiang L,Sun S,Heine N,et al. Large Amplitude Motion in Cold Monohydrated Dihydrogen Phosphate Anions H₂PO^-₄(H₂O):Infrared Photodissociation Spectroscopy Combined with Ab Initio Molecular Dynamics Simulations[J]. Phys Chem Chem Phys,2014,16(4):1314-1318.
[6] Sun S,Jiang L,Liu J,et al. Microhydrated Dihydrogen Phosphate Clusters Probed by Gas Phase Vibrational Spectroscopy and First Principles Calculations[J]. Phys Chem Chem Phys,2015,17(39):25714-25724.
[7] DONG Zhiyun,ZHANG Xiaoyu,ZENG Zhengquan,et al. Anthracene-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO^-₄[J]. Chinese J Appl Chem,2020,37(1):80-87(in Chinese).
董智云,张晓宇,曾政权,等. 基于蒽-苯并咪唑鎓的荧光传感器对H₂PO^-₄的高选择性识别[J]. 应用化学,2020,37 (1):80-87.
[8] Duchateau G,Feit M D,Demos S G. Strong Nonlinear Growth of Energy Coupling During Laser Irradiation of Transparent Dielectrics and Its Significance for Laser Induced Damage[J]. J Appl Phys,2012,111(9):093106.
[9] Ren X,Xu D,Xue D. Crystal Growth of KDP, ADP, and KADP[J]. J Cryst Growth,2008,310(7/8/9):2005-2009.
[10] Xu D,Xue D. Chemical Bond Analysis of the Crystal Growth of KDP and ADP[J]. J Cryst Growth,2006,286(1):108-113.
[11] Sun C,Xue D. In Situ IR Spectral Observation of NH₄H₂PO₄ Crystallization:Structural Identification of Nucleation and Crystal Growth[J]. J Phys Chem C,2013,117(37):19146-19153.
[12] D′Amico F,Bencivenga F,Gessini A,et al. Investigation of Acetic Acid Hydration Shell Formation through Raman Spectra Line-Shape Analysis[J]. J Phys Chem B,2012,116(44):13219-13227.
[13] Sarmiento A,Maguregui M,Martinez(Arkarazo I,et al. Raman Spectroscopy as a Tool to Diagnose the Impacts of Combustion and Greenhouse Acid Gases on Properties of Built Heritage[J]. J Raman Spectrosc:An International Journal for Original Work in all Aspects of Raman Spectroscopy, Including Higher Order Processes, and also Brillouin and Rayleigh Scattering,2008,39(8):1042-1049.
[14] Ocenášek J,Novák P,Prušáková L. Kinetics of the Laser-Induced Solid Phase Crystallization of Amorphous Silicon—Time-Resolved Raman Spectroscopy and Computer Simulations[J]. Appl Surf Sci,2017,392:867-871.
[15] Mošner P,Kupetska O,Koudelka L,et al. Physical Properties and Structural Studies of Lithium Borophosphate Glasses Containing TeO₂[J]. J Solid State Chem,2019,270:547-552.
[16] ZHOU Kai,WENG Ying,HOU Qingqing,et al. Preparation, Crystal Structure and Solubility of Organic Salt Hydrate of Berberine-Genistein[J]. Chinese J Appl Chem,2019,36(2):230-235(in Chinese).
周凯,翁莹,侯青青,等. 黄连素-染料木素有机盐水合物的制备,晶体结构及溶解性[J]. 应用化学,2019,36(2):230-235.
[17] ZHONG Zhenxing,LIU Guilan,LI Yonghai,et al. Effects of 1,2-Butanediol Comonomer on the Crystallization Behavior and Mechanical Properties of Poly(ethylene terephthalate)[J]. Chinese J Appl Chem,2019,36(2):170-175(in Chinese).
钟振兴,刘桂兰,李永海,等. 1,2-丁二醇共聚对聚对苯二甲酸乙二醇酯结晶行为及力学性能的影响[J]. 应用化学,2019,36(2):170-175.
[18] YE Shaofeng,LIU Wenxian,SHA Dongyong,et al. Two-Dimensional Materials Assembled Bubble Foam-like Hybrid for Supercapacitor Applications[J]. Chinese J Appl Chem,2018,35(3):351-355(in Chinese).
叶绍凤,刘文贤,沙东勇,等. 泡沫状二维复合材料的合成及超级电容器性能[J]. 应用化学,2018,35(3):351-355.
[19] XU Xiaolong,HAO Zhendong,LI Haoqiang,et al. Modification of LiFePO₄ Based on Zeolite Imidazolate Framework-8[J]. Chinese J Appl Chem,2018,35(8):939-945(in Chinese).
徐小龙,郝振东,李浩强,等. 基于沸石咪唑酯骨架-8 LiFePO₄的改性[J]. 应用化学,2018,35(8):939-945.
[20] Lu G,Xia H,Sun D,et al. Cluster Formation in Solid-Liquid Interface Boundary Layers of KDP Studied by Raman Spectroscopy[J]. Phys Status Solidi A,2001,188(3):1071-1076.
[21] Syed K A,Pang S F,Zhang Y,et al. Micro-Raman Observation on the H₂PO^-₄ Association Structures in a Supersaturated Droplet of Potassium Dihydrogen Phosphate (KH₂PO₄)[J]. J Chem Phys,2013,138(2):024901.
[22] Lee S,Wi H S,Jo W,et al. Multiple Pathways of Crystal Nucleation in an Extremely Supersaturated Aqueous Potassium Dihydrogen Phosphate (KDP) Solution Droplet[J]. Proc Natl Acad Sci USA,2016,113(48):13618-13623.
[23] Rudolph W W. Raman- and Infrared-Spectroscopic Investigations of Dilute Aqueous Phosphoric Acid Solutions[J]. Dalton Trans,2010,39(40):9642-9653.
[24] Sun C,Chen X,Xue D. Hydrogen Bonding Paradigm in the Formation of Crystalline KH₂PO₄ from Aqueous Solution[J]. Cryst Growth Des,2017,17(6):3178-3184.
[25] Preston C M,Adams W. A Laser Raman Spectroscopic Study of Aqueous Orthophosphate Salts[J]. J Phys Chem,1979,83(7):814-821.
[26] Crettez J M,Misset J P,Coquet E. Vibrations and Force Constants of the Hexagonal Lithium Iodate Crystal[J]. J Chem Phys,1979,70(9):4194-4198.
[27] Coronel A C,Zinczuk J,Fernandez L E,et al. An Experimental and Theoretical Vibrational Study of 3,3,6,6-Tetramethyl-1,2,4,5-Tetrathiane[J]. Vib Spectrosc,2015,81: 40-45.
[28] Shaver J M,Christensen K A,Pezzuti J A,et al. Structure of Dihydrogen Phosphate Ion Aggregates by Raman-Monitored Serial Dilution[J]. Appl Spectrosc,1998,52(2):259-264.
[29] Cerreta M K,Berglund K A. The Structure of Aqueous Solutions of Some Dihydrogen Orthophosphates by Laser Raman Spectroscopy[J]. J Cryst Growth,1987,84(4):577-588.
[30] Xue D,Wang H. In-Situ Micro-Spectroscopy Technique for Chemical Bonding During Nucleation:A Transition from Soft Bond to Stiff Bond[J]. Sci China Tech Sci,2020,63DOI:10.1007/s11431-020-1535-1.
[31] Ben Mabrouk K,Kauffmann T H,Aroui H,et al. Raman Study of Cation Effect on Sulfate Vibration Modes in Solid State and in Aqueous Solutions[J]. J Raman Spectrosc,44(11):1603-1608.
[32] Li K,Li M,Xue D. Solution-Phase Electronegativity Scale:Insight into the Chemical Behaviors of Metal Ions in Solution[J]. J Phys Chem A,2012,116(16):4192-4198.
[33] Li K,Xue D. Estimation of Electronegativity Values of Elements in Different Valence States[J]. J Phys Chem A,2006,110(39):11332-11337.
[34] Rajbanshi A,Wan S,Custelcean R. Dihydrogen Phosphate Clusters: Trapping H₂PO^-₄ Tetramers and Hexamers in Urea-Functionalized Molecular Crystals[J]. Cryst Growth Des,2013,13(5):2233-2237.

Influence of Sodium and Potassium Ions on Dihydrogen Phosphate Anion Raman Spectra

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yue YANG, Shi-Wen HUANG, Yue TONG, Ze-Da CHEN, Ben-Hua MA, Chuan-Dong DOU. Donor-Acceptor Type Chiral Tetracoordinate Organoboranes and Their Optical Properties [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 743-748.
[2]	GUO Yong-Yan, TIAN Yan-Fei, DANG Ming-Ming, YANG Ping, LONG Yun-Fei. Preparation of Thiourea Coordinated Chromium Black T Stabilized Silver Nanoclusters under Alkaline Environment [J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 195-201.
[3]	CAI Zhi-Feng, WU Liang-Liang, QI Kai-Fei, DENG Chen-Hua, ZHANG Shen, ZHANG Cai-Feng. Synthesis of Proline-Stabilized Cu Nanoclusters for Detection of Picric Acid [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 107-115.
[4]	ZHANG Shen, GUO Yuyu. One-Pot Synthesis of Fluorescent Polyvinyl Pyrrolidone-Stabilized Cu Nanoclusters for the Determination of Quercetin [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1069-1075.
[5]	CAI Zhifeng, CHEN Siying, PANG Shulin, SONG Shuang, JIA Kang, MAO Yujin, TIAN Fang, ZHANG Caifeng. Synthesis of 2-Mercaptobenzimidazole-Functionalized Water-Soluble Copper Nanoclusters and Their Application to the Determination of Ag⁺ [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 587-594.
[6]	GUO Yongyan, ZENG Weiwei, YANG Ping, TIAN Yanfei, LONG Yunfei. Synthesis of Silver Nanoclusters Stabilized by pH-Regulated Chromotropic Acid 2R [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 54-60.
[7]	CHENG Jinhua, JIANG Hongji. Study on Self-assembly Behaviors of an Amphiphilic Block Polymer by Terminally Grafting Tetraphenylethene-Based Aggregation-Induced Emission Active Moietys [J]. Chinese Journal of Applied Chemistry, 2019, 36(4): 440-450.
[8]	DANG Lifang,WANG Ruixin,XIE Meina,JIAO Weizhou. Research Progress of Polyoxometalates and Their Self-aggregation Behaviors in Solution [J]. Chinese Journal of Applied Chemistry, 2018, 35(6): 625-644.
[9]	WANG Tao,MA Lamaocao,MA Hengchang. Research Progress on Cell Imaging Based on the Aggregation-induced Emission Fluorescent Probes [J]. Chinese Journal of Applied Chemistry, 2018, 35(10): 1155-1165.
[10]	LI Yueqing,WU Qianqian,SONG Qilin,CAO Lei,QIN Qiuyan,XU Yan,ZHAO Weijie. Synthesis and Anti-platelet Aggregation Assay of Cinnamoyl-tyramine Amide Analogues [J]. Chinese Journal of Applied Chemistry, 2018, 35(10): 1174-1183.
[11]	LI Yueqing, WU Qianqian, SONG Qilin, CAO Lei, QIN Qiuyan, XU Yan, ZHAO Weijie. Synthesis and Anti-platelet Aggregation Assay of Cinnamoyl-tyramine Amide Analogues [J]. Chinese Journal of Applied Chemistry, 2018, 35(10): 0-0.
[12]	SHI Weining,XU Yongqian,SUN Shiguo,LI Hongjuan. Research Progress on Application of Fluorescent Sensors Based on Squaraine Dyes [J]. Chinese Journal of Applied Chemistry, 2017, 34(12): 1433-1449.
[13]	SHANG Yazhuo, WANG Yuqin, DONG Xiuyan, ZHU Yunfeng, LIU Honglai. Effect of Sodium Dodecyl Sulfate on Interfacial Aggregation Behavior of Zwitterionic Imidazole Surfactant 3-(1-Dodecyl-3-imidazolio)propanesulfonate [J]. Chinese Journal of Applied Chemistry, 2016, 33(6): 641-648.
[14]	LIU Daiming, FANG Kuanjun*, CAI Yuqing. Interaction Between Cetyltrimethyl Ammonium Chloride and C.I. Direct Blue 199 [J]. Chinese Journal of Applied Chemistry, 2013, 30(09): 1054-1059.
[15]	LOU Shaofeng1, ZHANG Hua1, ZHANG Peipei1, TIAN Liqiang1, NIE Huali1, QUAN Jing1,2, ZHU Limin1. Synthesis and Temperature Sensitivity of N-isopropylacryamide Copolymers with Glucose Pendant [J]. Chinese Journal of Applied Chemistry, 2013, 30(04): 408-412.