Solvothermal Synthesis and Characterization of Cs8Mn4Sn4Se16 and [Ni(1,2-dap)3]2Cd2Sn2S8 (1,2-dap:1,2-Propanediamine)Chains

doi:10.11944/j.issn.1000-0518.2018.06.170234

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (6): 700-707.DOI: 10.11944/j.issn.1000-0518.2018.06.170234

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Solvothermal Synthesis and Characterization of Cs₈Mn₄Sn₄Se₁₆ and [Ni(1,2-dap)₃]₂Cd₂Sn₂S₈ (1,2-dap:1,2-Propanediamine)Chains

HAN Wenjing^a,BAIYIN Menghe^a^b^*()

^aCollege of Chemistry & Environmental Science;
^bKey Laboratory for Physics and Chemistry of Functional Materials,Inner Mongolia Normal University,Hohhot 010022,China

Received:2017-06-29 Accepted:2017-08-29 Published:2018-06-01 Online:2018-05-28
Contact: BAIYIN Menghe
Supported by:
Supported by the National Natural Science Foundation of China(No.21461019), the Natural Science Foundation Project of Inner Mongolia(No.2016MS0225)

Abstract

Abstract:

The chalcogenidostannate compound Cs₈Mn₄Sn₄Se₁₆(1) and [Ni(1,2-dap)₃]₂Cd₂Sn₂S₈(2) were solvothermally synthesized by using the alkali metal in 1,4-butanediamine, and 1,2-propanediamine(1,2-dap) coordinated transition metal as guest cations, respectively. Single-crystal X-ray, ultraviolet-visible(UV-Vis) diffuse reflectance spectroscopy and thermogravimetric analysis and differential scanning calorimetry(TG-DSC) indicate that the compounds 1 and 2 belong to orthorhombic system Fddd group and Cmcm group. Both 1 and 2 consist of one-dimensional straight anionic chains composed of edge sharing tetrahedron SnQ₄(Q=S, Se) or TMQ₄(TM=Mn, Cd). The UV-visble diffuse reflectance data show that the band gaps of compounds 1 and 2 are 1.70 eV and 2.21 eV, respectively, which implies that compounds 1 and 2 have semiconductor properties. The TG-DSC results indicate good thermal stability of compunds 1 and 2 in some temperature condition.

Key words: solvothermal synthesis, multi-chalcogenidostannates, crystal structure, characterization

HAN Wenjing,BAIYIN Menghe. Solvothermal Synthesis and Characterization of Cs₈Mn₄Sn₄Se₁₆ and [Ni(1,2-dap)₃]₂Cd₂Sn₂S₈ (1,2-dap:1,2-Propanediamine)Chains[J]. Chinese Journal of Applied Chemistry, 2018, 35(6): 700-707.

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Solvothermal Synthesis and Characterization of Cs₈Mn₄Sn₄Se₁₆ and [Ni(1,2-dap)₃]₂Cd₂Sn₂S₈ (1,2-dap:1,2-Propanediamine)Chains

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