Influence of 3-Aminopropyltriethoxysilane on Natural Aging Property of Polyurethane/Al-Sm2O3 Composite Coatings

doi:10.11944/j.issn.1000-0518.2017.04.160260

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (4): 430-435.DOI: 10.11944/j.issn.1000-0518.2017.04.160260

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Influence of 3-Aminopropyltriethoxysilane on Natural Aging Property of Polyurethane/Al-Sm₂O₃ Composite Coatings

ZHANG Weigang^a^*(),XU Guoyue^b,XUE Lianhai^a,CHEN Yaxi^a

^aCollege of Materials and Chemical Engineering,Chuzhou University,Chuzhou,Anhui 239000,China
^bCollege of Material Science and Technology,Nanjing University of Aeronautics and Astronautics,Nanjing 211106,China

Received:2016-06-21 Accepted:2016-09-05 Published:2017-03-31 Online:2017-03-31
Contact: ZHANG Weigang
Supported by:
Supported by the National Natural Science Foundation of China(No.40772033), University Natural Science Research Key Project of Anhui Province(No.KJ2016A535), Research Projects of Chuzhou University(No.2015PY02), Scientific Research Start Foundation Project of Chuzhou University(No.2015qd15)

Abstract

Abstract:

Polyurethane(PU)/Al-Sm₂O₃ composite coatings were modified by silane coupling agent 3-aminopropyltriethoxysilane(KH550). The variation of natural aging property before and after modification was systematically investigated from the perspectives of functional properties and mechanical properties. The results indicate that the stability of infrared emissivity of PU/Al-Sm₂O₃ composite coatings for natural aging is significantly enhanced after KH550 modification. The infrared emission of modified coatings is significantly lower than that of unmodified coatings under the same conditions. The dispersion of Sm₂O₃ particles on the coatings' surface is more uniform after modified by KH550. The near-infrared light absorption intensity has increased, and this leads to a 1.06 μm near-infrared reflectivity of modified coatings, which is significantly lower than that of unmodified coatings. The coatings' hardness has good stability for natural aging before and after modification. The hardness can maintain for 3 H. The adhesion strength and impact strength of the unmodified coatings are significantly affected by natural aging, but it can be significantly strengthened after KH550 modification to maintained at 1 grade and 50 kg·cm after natural aging for 4 months, respectively.

Key words: composite coatings, infrared emissivity, near-infrared reflectivity, natural aging property, mechanical properties

ZHANG Weigang, XU Guoyue, XUE Lianhai, CHEN Yaxi. Influence of 3-Aminopropyltriethoxysilane on Natural Aging Property of Polyurethane/Al-Sm₂O₃ Composite Coatings[J]. Chinese Journal of Applied Chemistry, 2017, 34(4): 430-435.

References

[1]	Zhang W Y,Lu C H,Ni Y R,et al.Preparation and Characterization of Sm2O3/Cu Mosaic Structure with Infrared Absorptive Properties and Low Infrared Emissivity[J]. Mater Lett,2012,87:13-16.
[2]	HUANG Yun,HE Wei,XU Zhongzi,et al.Preparation and Properties of Doped-ZAO Powders[J]. J Funct Mater,2009,40(3):494-497(in Chinese). 黄芸,何伟,许仲梓,等. 掺铝氧化锌粉末的制备及其性能研究[J]. 功能材料,2009,40(3):494-497.
[3]	YUAN Le,WENG Xiaolong,LU Hu,et al.Preparation and Infrared Reflection Performance of Al/Cr2O3 Composite Particles[J]. J Inorg Mater,2013,28(5):545-550(in Chinese). 袁乐,翁小龙,卢虎,等. Al/Cr2O3复合粉体的制备及红外反射特性研究[J]. 无机材料学报,2013,28(5):545-550.
[4]	ZHANG Weigang,XU Guoyue,XUE Lianhai.Nera-infrared Absorption and Infrared Emissivity Properties of Polyurethane/bronze-Sm2O3 Composite Coatings[J]. J Mater Eng,2016,44(1):115-119(in Chinese). 张伟钢,徐国跃,薛连海. 聚氨酯/青铜-Sm2O3复合涂层的近红外吸收与发射率性能[J]. 材料工程,2016,44(1):115-119.
[5]	LI Yongmei,SHEN Xiaodong,CUI Sheng.Preparation for SmBO3 Coated with ZAO Nano-composited Powder[J]. J Funct Mater Devices,2010,16(4):353-357(in Chinese). 李永梅,沈晓冬,崔升. ZAO包覆SmBO3纳米复合粒子的制备[J]. 功能材料与器件学报,2010,16(4):353-357.
[6]	Zhang Q T,Meng X F,Wang L X,et al.Preparation and Spectra Properties of BaO-A12O3 -P2O5-Sm2O3 System Protection Glasses[J]. J Rare Earth,2006,24(2):207-210.
[7]	XING Honglong,GUO Wenmei,TAO Qiyu,et al.Preparation and Properties of Infrared-laser Compatible Stealth Coating with Waterborne Polyurethane[J]. Laser Infrared,2013,43(7):761-765(in Chinese). 邢宏龙,郭文美,陶启宇,等. 聚氨酯基红外-激光兼容隐身涂层性能研究[J]. 激光与红外,2013,43(7):761-765.
[8]	ZHANG Weigang,XU Guoyue,QIAO Jialiang,et al.Low Emissivity at 8~14 μm and Low Near-infrared Reflective Properties of Al-Sm2O3/polyurethane Composite Coatings[J]. Acta Mater Compos Sin,2014,31(2):436-440(in Chinese). 张伟钢,徐国跃,乔加亮,等. Al-Sm2O3/聚氨酯复合涂层的近红外低反射与8~14 μm低发射率性能[J]. 复合材料学报,2014,31(2):436-440.
[9]	ZUO Xiang,ZHAO Xuanke,WANG Lianfen,et al.Laser/infrared Compatible Stealth Technique Based on One-dimensional Single-negative Photonic Crystal[J]. Ship Electron Eng,2014,34(2):141-146(in Chinese). 左翔,赵选科,王莲芬,等. 基于一维单负光子晶体的激光/红外兼容隐身技术研究[J]. 舰船电子工程,2014,34(2):141-146.
[10]	CHENG Hongfei,HUANG Daqing.Research Progress in Multi-spectrum Compatible Stealth Materials[J]. J Aeronaut Mater,2014,34(5):93-99(in Chinese). 程红飞,黄大庆. 多频谱兼容隐身材料研究进展[J]. 航空材料学报,2014,34(5):93-99.
[11]	Yan X X,Xu G Y.Corrosion and Mechanical Properties of Epoxy-polyurethane/bronze Composite Coatings with Low Infrared Emissivity[J]. Surf Coat Technol,2010,205(7):2307-2312.
[12]	Yan X X,Xu G Y.Synergy Effect of Silane and CTAB on Corrosion-resistant Property of Low Infrared Emissivity Cu/Polyurethane Coating Formed on Tinplate[J]. Surf Coat Technol,2010,204(9/10):1514-1520.
[13]	Yan X X,Xu G Y.Lifetime Prediction of Low Infrared Emissivity Coatings in 3wt% NaCl Solution[J]. Measurement,2011,44(8):1448-1452.
[14]	LIU Fujie,QI Yuhong,ZHANG Zhanping.Influence of Curing Ggent and Silane Coupling Agent on the Properties of Silicone Coatings[J]. China Surf Eng,2014,27(1):114-119(in Chinese). 刘福杰,齐育红,张占平. 固化剂和硅烷偶联剂对有机硅涂层性能的影响[J]. 中国表面工程,2014,27(1):114-119.
[15]	LI Heng,LI Cheng,WANG Jiayu,et al.Effect of a Silane Coupling Agent on Corrosion Performance of Tetraethoxysilane Hybrid Coating[J]. Corros Sci Prot Technol,2011,23(1):49-52(in Chinese). 李恒,李澄,王加余,等. 硅烷偶联剂KH550对正硅酸乙酯杂化涂层抗腐蚀性能的影响[J]. 腐蚀科学与防护技术,2011,23(1):49-52.
[16]	YAN Xiaoxing,MAO Weiguo,WU Yan,et al.Performance of Waterborne UV-curable Wood Coatings Modified by Silane Coupling Agent[J]. Furniture,2013,34(6):29-32(in Chinese). 闫小星,毛卫国,吴燕,等. 硅烷偶联剂改性对水性UV固化木器涂料性能的影响[J]. 家具,2013,34(6):29-32.
[17]	Yan X X,Xu G Y.Influence of Silane Coupling Agent on Corrosion-resistant Property in Low Infrared Emissivity Cu/polyurethane Coating[J]. Prog Org Coat,2012,73:232-238.

Influence of 3-Aminopropyltriethoxysilane on Natural Aging Property of Polyurethane/Al-Sm₂O₃ Composite Coatings

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