Preparation and Performance of Bisphenol F-Type Polyimides Film

doi:10.3724/SP.J.1095.2011.00754

Chinese Journal of Applied Chemistry ›› 2011, Vol. 28 ›› Issue (12): 1370-1374.DOI: 10.3724/SP.J.1095.2011.00754

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Preparation and Performance of Bisphenol F-Type Polyimides Film

LI Yuan¹, LI Guijuan1, DING Mengxian^2,3, WANG Zhen^3*

(1.School of Chemical Engineering,Changchun University of Technology,Changchun；
2.The Company of Gaoqi Polyimides Material,Changchun;
3.Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022)

Received:2010-12-23 Revised:2011-04-11 Published:2011-12-10 Online:2011-12-10

Abstract

Abstract:

A novel bisphenol F-type dianhydride(BPFDA) monomer was synthesized using 4-chlorophthalimide through hydration, acidification, and dehydration. Its structure was determined with 1H NMR and IR. Two types of polyimide films were prepared with the dianhydride and 4,4′-diaminodiphenyl ether(ODA) or 4,4′-methylene dianiline(MDA) via conventional one-step method in N,N′-dimethylacetamide. The obtained polyamic acid was then further imidized into polyimide films and characterized. Results show that the glass-transition temperatures of the polyimide films were 200 and 204 ℃；the temperatures of 5% mass loss were 506.50 and 459.10 ℃； and the tensile strength of the films were 110 and 100 MPa, respectively.

Key words: BPFDA, Polyimide, Thermal property, Mechanical properties.

CLC Number:

O631

LI Yuan1, LI Guijuan1, DING Mengxian2,3, WANG Zhen3*. Preparation and Performance of Bisphenol F-Type Polyimides Film[J]. Chinese Journal of Applied Chemistry, 2011, 28(12): 1370-1374.

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Preparation and Performance of Bisphenol F-Type Polyimides Film

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