Effects of 1,2-Butanediol Comonomer on the Crystallization Behavior and Mechanical Properties of Poly(ethylene terephthalate)

doi:10.11944/j.issn.1000-0518.2019.02.180380

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (2): 170-175.DOI: 10.11944/j.issn.1000-0518.2019.02.180380

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Effects of 1,2-Butanediol Comonomer on the Crystallization Behavior and Mechanical Properties of Poly(ethylene terephthalate)

ZHONG　Zhenxing^a^b,LIU Guilan^c,LI Yonghai^c,LI Lianguo^c,HUANG Yan^a,ZHANG Guangyu^a^*(),SU Zhaohui^a

^aState Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
^bUniversity of Science and Technology of China,Hefei 230026,China
^cChangchun GBT Biochemical Co.,Ltd.,Changchun 130102,China

Received:2018-11-29 Published:2019-02-01 Online:2019-01-31
Contact: ZHANG Guangyu
Supported by:
Fund item:Supported by the Jilin Province and Chinese Academy of Sciences Science and Technology Cooperation Special Funds for High-tech Industrialization(No.2017SYHZ0017)

Abstract

Abstract:

In this work, poly(ethylene terephthalate)(PET) homopolymer and copolymers were synthesized from biomass-derived ethylene glycol containing 0, 2.0%, 2.7%, and 5.6% mole fraction of 1,2-butanediol(1,2-BDO) in order to explore the effects of the comonomer on the crystallization behavior and the mechanical properties of the PET. The polymers were investigated by Fourier transform infrared spectroscopy(FTIR), differential scanning calorimetry(DSC), and mechanical testing. It is found that the melting temperature, crystallization rate and crystallinity of the PET decrease as mole fraction of 1,2-BDO comonomer increases, indicating that the incorporation of the 1,2-BDO units can disrupt the ordered structure of the PET chains and therefore hinder the crystallization. In addition, the tensile strength of PET materials decreases while the flexural modulus and strength increase slightly at higher 1,2-BDO mole fraction.

Key words: poly(ethylene terephthalate), copolymers, 1, 2-butanediol, crystallization behavior, mechanical properties

ZHONG　Zhenxing, LIU Guilan, LI Yonghai, LI Lianguo, HUANG Yan, ZHANG Guangyu, SU Zhaohui. Effects of 1,2-Butanediol Comonomer on the Crystallization Behavior and Mechanical Properties of Poly(ethylene terephthalate)[J]. Chinese Journal of Applied Chemistry, 2019, 36(2): 170-175.

References

[1]	Huber G W,Iborra S,Corma A.Synthesis of Transportation Fuels from Biomass:Chemistry, Catalysts, and Engineering[J]. Chem Rev,2006,106(9):4044-4098.
[2]	Gallezot P.Conversion of Biomass to Selected Chemical Products[J]. Chem Soc Rev,2012,41(4):1538-1558.
[3]	Climent M J,Corma A,Iborra S.Conversion of Biomass Platform Molecules into Fuel Additives and Liquid Hydrocarbon Fuels[J]. Green Chem,2014,16(2):516-547.
[4]	Corma A,Iborra S,Velty A.Chemical Routes for the Transformation of Biomass into Chemicals[J]. Chem Rev,2007,107(6):2411-2502.
[5]	Rose M,Palkovits R.Isosorbide as a Renewable Platform Chemical for Versatile Applications-Quo Vadis?[J]. ChemSusChem,2011,5(1):167-176.
[6]	Fenouillot F,Rousseau A,Colomines G,et al. sPolymers from Renewable 1,4:3,6-Dianhydrohexitols (Isosorbide, Isomannide and Isoidide):A Review[J]. Prog Polym Sci,2010,35(5):578-622.
[7]	Mäki-Arvela P,Simakova I L,Salmi T,et al. Production of Lactic Acid/Lactates from Biomass and Their Catalytic Transformations to Commodities[J]. Chem Rev,2014,114(3):1909-1971.
[8]	HAN Guocheng.Development and Application of Environment-Friendly Polyester Material[J]. Plast Sci Technol,2018,46:121-126(in Chinese). 韩国程. 环保型聚酯材料的发展及应用[J]. 塑料科技,2018,46:121-126.
[9]	Tsai T Y,Naveen B,Shiu W C,et al. An Advanced Preparation and Characterization of the PET/MgAl-LDH Nanocomposites[J]. RSC Adv,2014,4(49):25683-25691.
[10]	Wang D R,Luo F L,Shen Z Y,et al. A Study on the Crystallization Behavior and Mechanical Properties of Poly(ethylene terephthalate) Induced by Chemical Degradation Nucleation[J]. RSC Adv,2017,7(59):37139-37147.
[11]	Xiao B,Zhen M Y,Pang J F,et al. Synthesis and Characterization of Poly(ethylene terephthalate) from Biomass-Based Ethylene Glycol:Effects of Miscellaneous Diols[J]. Ind Eng Chem Res,2015,54:5862-5869.
[12]	Fann D M,Huang S K,Lee J Y.DSC Studies on the Crystallization Characteristics of Poly(Ethylene Terephthalate) for Blow Molding Applications[J]. Polym Eng Sci,1998,38(2):265-273.
[13]	Deshmukh G S,Pathak S U,Peshwe D R,et al. Effect of Uncoated Calcium Carbonate and Stearic Acid Coated Calcium Carbonate on Mechanical, Thermal And Structural Properties of Poly(Butylene Terephthalate)(PBT)/Calcium Carbonate Composites[J]. Bull Mater Sci,2010,33(3):277-284.

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Effects of 1,2-Butanediol Comonomer on the Crystallization Behavior and Mechanical Properties of Poly(ethylene terephthalate)

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