Synthesis, Crystal Structure and Third-Order Nonlinear Optical Properties of methanoanthracene-stilbazolium Tetraphenylborate

Chinese Journal of Applied Chemistry ›› 2010, Vol. 27 ›› Issue (01): 58-62.

• Full Papers • Previous Articles Next Articles

Synthesis, Crystal Structure and Third-Order Nonlinear Optical Properties of methanoanthracene-stilbazolium Tetraphenylborate

ZHANG Qian1, LIU Zhao-Di1, LIU Hui-Jun1, WU Jie-Ying1, ZHOU Hong-Ping1, YANG Jia-Xiang1,2, TIAN Yu-Peng1,2*

(1.Department of Chemistry,Anhui Province Key Laboratory of
Functional Inorganic Materials,Anhui University,Hefei 230039;
2.State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093)

Received:2009-01-20 Revised:2009-07-30 Published:2010-01-10 Online:2010-01-10

Abstract

Abstract:

A novel substituent styryl pyridinium tetraphenylborate, 4-N,N-dimethylamino-4’-N’-9 -methanoanthracene-stilbazolium tetraphenylborate, was synthesized and characterized by means of IR, ¹H NMR, ¹³C NMR, MS-EI and X-ray single-crystal diffraction. The compound crystallizes in monoclinic space group P2₁/c with a = 1.2557 (1) nm, b = 1.539 (1) nm, c = 2.2202 (8) nm, β =101.099(1) °, and V = 4.2105(4) nm³, Z = 4, D_c = 1.159 g×cm^-3. The nonlinear optical properties of the compound were investigated by virtue of 1064 nm nanosecond laser beam, and the results show that the novel pyridinium salt has a TPA coefficient of β = 0.028 cm / GW，a TPA cross-section of σ = 8.68×10^-48 cm⁴×s×photon^-1.

Key words: Substituent styryl pyridinium salt

CLC Number:

O621.3

ZHANG Qian, LIU Zhao-Di, LIU Hui-Jun, TUN Jie-Ying, ZHOU Hong-Ping, YANG Jia-Xiang, TIAN Yu-Peng. Synthesis, Crystal Structure and Third-Order Nonlinear Optical Properties of methanoanthracene-stilbazolium Tetraphenylborate[J]. Chinese Journal of Applied Chemistry, 2010, 27(01): 58-62.

References

1 He G S, Tan L S, Zheng Q D, Prasad P N. Chem.Rev[J], 2008, 111, 472.

2 Coe BJ, Samoc M, Samoc A. J Phys Chem A[J], 2007, 111, 472.

3 Ford P C, Cariati E, Bourassa J, Chem. Rev[J], 1999, 99, 3625

4 Ren Y, Yu X Q, Zhang D J, Wang D, Zhang M L, Xu G B, Zhao X, Tian Y P, Shao Z S, Jiang M H. J Mater Chem[J], 2002, 12:3431

5 Ishii K, Hoshino S, Kobayashi N. Inorg Chem[J], 2004, 43, 7969

6 Coe B J, Samoc M, Samoc A . J Phys Chem A[J], 2007, 111:472.

7 Lobana T S, Castineiras R A, Turner P. Inorg Chem[J], 2003, 42, 4731

8 Chen Guang-Xu(陈光需), WU Heng-Fu(吴恒富), LUO Jun-Shan(骆俊山), KONG Lin (孔林), WU Jie-Ying(吴杰颖). Chinese J of Synth Chem (合成化学)[J], 2008, 16: 431.

9 Belfield K D, Ren X, Eric W. Van Stryland, David J. Hagan, Vladislav Dubikovsky, and Edward J. Miesak. J Am Chem Soc[J], 2000, 122: 1217

10 Zhao C. F, He C. S, Bhawalkar J. D, Park C. K, Prasad P. N, Chem. Mater. [J], 1995, 7, 1979-1983.

11 Jordan G, Hörhold T. W. S.H. H., Adv. Funct. Mater. [J]2003, 13, 751

12 Zheng Q. D, He G. S, Lin T. C, Prasad P. N, J. Mater. Chem., [J]2003, 13, 2499

13 Iwase Y, Kamada K, Ohta K, Kondo K, J. Mater. Chem., [J] 2003, 13, 1575

14 Yamasak K, Joudkazis S, Watanabe M, Sun H B, Matsuo S, Misawa H. Appl Phys Lett[J], 2002, 30: 774.

15 Demas J N, Crosby G A. J Phys Chem[J], 1971, 75: 991

16 Bahae M S, Said A A, Wei T H, Hagan D J, Stryland W V, IEEE J. Quantum Electron[J], 1990, 26: 760

17 Zhou J, Pun E Y B, Zhang X H. Opt Soc Am B[J], 2001, 18: 1456.

18 Tsai C Y, Chen S P, Wen T C. Chem Phys[J], 1999, 240: 191

19 Yu B L, Zhu C S, Gang F X, Chen H B, Huang Y S. Acta Optica Sinica[J], 1997, 17: 423.

20 He G S, Xu G C, Prasad P N, Reinhardt B A, Bhatt J C, Dillard A G. Opt Lett, 1995, 20: 435.

21 He G S, Swiatkiewicz J, Jiang Y, Prasad P N. J Phys Chem A[J], 2000, 104: 4805

22 Zhou G Y, Wang X M, Wang D, Wang C, Shao Z S, Fang Q, Jiang M H. Opt Commun, 2001, 190: 345

[1]	YAO Yuanyong1,2, WU Lanyan1, SHU Hua1, TANG Bangcheng1, XUE Wei2. Synthesis of α-Aminophosphonates by Bronsted Acid Catalysis [J]. Chinese Journal of Applied Chemistry, 2014, 31(12): 1428-1433.
[2]	ZHOU Weijie, SUN Xiaoqiang, XI Haitao*. Synthesis and Fluorescence Properties of Hyaluronic Acid Derivatives Containing Fluorinated Coumarin [J]. Chinese Journal of Applied Chemistry, 2014, 31(08): 916-921.
[3]	YIN Zhigang*, GUO Haiyan, QIAN Hengyu, ZHANG Tongyan, QIN Jinwan, ZHANG Yingjun. Synthesis and Application of a Special Colorant Used in Preparing Yellow Polyurethane Elastic Membrane [J]. Chinese Journal of Applied Chemistry, 2014, 31(08): 901-910.
[4]	ZENG Wei, CHEN Fuxue*. Recent Advances in Radical Trifluoromethylation Reactions [J]. Chinese Journal of Applied Chemistry, 2014, 31(06): 627-641.
[5]	XIAO Liwei*, KONG jie, ZHOU Qiuxiang, HU Yueli. One Pot Synthesis of β-Amino Ketone Derivatives Catalyzed by Polystyrene-supported Ferric Chloride [J]. Chinese Journal of Applied Chemistry, 2014, 31(06): 715-720.
[6]	KE Fang1*, WU Wen2, LI Peng1, LIN Chen1. Microwave-assisted Synthesis of Benzothiazole Derivatives in Aqueous Solution [J]. Chinese Journal of Applied Chemistry, 2014, 31(06): 721-725.
[7]	FENG Cuilan*, XU Haiyun, LIU Lantao, WANG Jing, LIU Ying. Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe₃O₄ Nanoparticles Under Solvent-free and Ligand-free Conditions [J]. Chinese Journal of Applied Chemistry, 2014, 31(05): 536-540.
[8]	ZHAO Xuejing, ZHU Jie, LU Ming*. Improvement of the Oxidation Process in the Synthesis of 2,6-Diamino-3,5-dinitropyrazine-1-oxide [J]. Chinese Journal of Applied Chemistry, 2014, 31(01): 41-49.
[9]	DUAN Zhifang, LI Chongbi*, WU Xufang, CHEN Gang. Solid Phase Grinding Synthesis and Plant Growth Activities of Arylureido-acylthiourea Derivatives [J]. Chinese Journal of Applied Chemistry, 2013, 30(12): 1429-1433.
[10]	LI Yanqin1*, YU Fengli2, ZHUANG Shengli1. Improved Synthetic Method and Characterization of Emedastine Difumarate [J]. Chinese Journal of Applied Chemistry, 2013, 30(11): 1285-1288.
[11]	ZHANG Feng1, FANG Zheng1, LI Xiaolin1, HE Wei1, YUAN Aibang2, GUO Kai2*. Applications of Ugi Reaction to the Synthesis of Natural Products [J]. Chinese Journal of Applied Chemistry, 2013, 30(11): 1237-1249.
[12]	GUO Wenyan1,2, CHEN Jianxin1*. A New Method for Synthesizing α-Aminoamide Compounds [J]. Chinese Journal of Applied Chemistry, 2013, 30(10): 1114-1119.
[13]	WANG Chaolei, WANG Zeqing, MA Tingli*. Synthesis of Porphyrin Dyes with Electron Donate-withdraw Structure and Their Applications in Dye-sensitized Solar Cells [J]. Chinese Journal of Applied Chemistry, 2013, 30(07): 757-763.
[14]	SHI Dongxin, CHEN Jiaojiao*, DU Xianli, WANG Lele, JIANG Yi, REN Rongrong. Synthesis of Chiral Functional Monomers Containing L-Amino Acid Groups and Their Copolymers with N-isopropylacrylamide [J]. Chinese Journal of Applied Chemistry, 2013, 30(07): 740-744.
[15]	WANG Weidong1,4*, SUN Guofu2, SHI Zhengchun3,4, SHIMO Tetsuro4. Photosynthesis of Two Oxa Macrocyclic Compounds [J]. Chinese Journal of Applied Chemistry, 2013, 30(04): 378-382.

Synthesis, Crystal Structure and Third-Order Nonlinear Optical Properties of methanoanthracene-stilbazolium Tetraphenylborate

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments