Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe3O4 Nanoparticles Under Solvent-free and Ligand-free Conditions

doi:10.3724/SP.J.1095.2014.30340

Chinese Journal of Applied Chemistry

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Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe₃O₄ Nanoparticles Under Solvent-free and Ligand-free Conditions

FENG Cuilan^*, XU Haiyun, LIU Lantao, WANG Jing, LIU Ying

(College of Chemistry and Chemical Engineering,Shangqiu Normal University,Shangqiu 476000,China)

Received:2013-07-08 Revised:2013-09-18 Published:2014-05-10 Online:2014-05-10
Contact: FENG

Abstract

Abstract: Magnetite nanoparticles as efficient catalyst for C—O cross-coupling reaction of aryl bromide with phenol under solvent-free and ligand-free conditions were described. Under the optimized conditions:130 ℃, 48 h and 7% molar fraction of Fe3O4, the yield of diaryl ether reaches up to 94.7%. The separated magnetite nanoparticles catalyst can be recycled for 4 runs in the C—O cross-coupling reaction without significantly loss of catalytic activity.

Key words: cross-coupling, magnetic Fe3O4 nanoparticles, diaryl ether, arylation, recyclability

CLC Number:

O621.3

FENG Cuilan*, XU Haiyun, LIU Lantao, WANG Jing, LIU Ying. Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe₃O₄ Nanoparticles Under Solvent-free and Ligand-free Conditions[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30340.

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Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe₃O₄ Nanoparticles Under Solvent-free and Ligand-free Conditions

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