Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (5): 97-99.

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Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride

Cui Tong¹, Fu Chengguang²

1. Department of Food Science, Hebei Agriculture University, Baoding 071000;
2. Research Centre of Physical and Chemical Analysis, Hebei University, Baoding

Received:1995-12-25 Revised:1996-05-16 Published:1996-10-10 Online:1996-10-10

Abstract

Abstract: The kinetic study showed that the water content has an important effect on the hydrolysis rate of phthalimidyl benzene sulphonyl chloride(Phisyl-Cl). The PH of the reaction medium should be higher than 8.0 and 9.0 for derivatization with primary and secondary amines respectively. The hydrolysis of Phisyl-Cl is inhibited by adding solid NaHCO₃ instead of its saturated solution to the medium to promote derivatization.

Key words: phthalimidylbenzene sulphonyl chloride, amine, derivatizing reagent, derivatization

Cui Tong, Fu Chengguang. Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride[J]. Chinese Journal of Applied Chemistry, 1996, 0(5): 97-99.

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Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride

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