Studies on the Aromatic Ring Stacking Interaction of the Cu(Ⅱ)-Bipyridyl-Phenylcarboxylic Acid System by Extraction Method

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (1): 107-108.

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Studies on the Aromatic Ring Stacking Interaction of the Cu(Ⅱ)-Bipyridyl-Phenylcarboxylic Acid System by Extraction Method

Xu Jinghua^1,2, Gong Yuqiu¹, Huang Xian¹

Department of Chemistry, Hangzhou University, Hangzhou 310028

Received:1995-06-19 Revised:1995-09-25 Published:1996-02-10 Online:1996-02-10

Abstract

Abstract: The stacking interactions of aromatic rings in the Cu²⁺bpy-PCA^-system (bpy=2,2'-bipyridyl,PCA=phenylcarboxylic acid)have been studied by extraction method in perchloric acid medium. The content of the stacked isomers of the extracted species [Cu(hy-)(PCA)2O)]⁺ increases in the order; Bz^- < PAc^- < PPr^- < PBu^-.The composition of complexes has been determined by slope method and elemental analysis.

Key words: aromatic ring stacking interaction, copper, bipyridyl, phenylcarboxylic acid

Xu Jinghua, Gong Yuqiu, Huang Xian. Studies on the Aromatic Ring Stacking Interaction of the Cu(Ⅱ)-Bipyridyl-Phenylcarboxylic Acid System by Extraction Method[J]. Chinese Journal of Applied Chemistry, 1996, 0(1): 107-108.

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Studies on the Aromatic Ring Stacking Interaction of the Cu(Ⅱ)-Bipyridyl-Phenylcarboxylic Acid System by Extraction Method

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