PREPARATION OF SINGLE-ION POLYMER CONDUCTOR—COMBLIKE POLYMERS WITH CARBOXYLATE GROUPS

Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (6): 14-18.

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PREPARATION OF SINGLE-ION POLYMER CONDUCTOR—COMBLIKE POLYMERS WITH CARBOXYLATE GROUPS

Hu Xiance, Liu Wanyu, Jiang Weiguo, Zong Huijuan

Department of Materials Science and Engineering, University of Science and Technology of China, 230026 Hefei

Received:1992-12-09 Revised:1993-06-04 Published:1993-12-10 Online:1993-12-10

Abstract

Abstract: The single-ion conducting polymer electrolytes with carboxylate groups immobilized on the backbones have been synthesized by alcoholysis of maleic anhydride-styrene or maleic anhydride-vinyl acetate copolymers with PEO monomethyl ether. The plasticized comblike polymeric lithium salt film showed conductivity up to 10^-6 S/cm at room temperature. The effects of polymer structure, cation radius, plasticizer, temperature and frequency on the conductivity were investigated.

Key words: maleic anhydride-vinyl acetate copolymer, maleic anhydride-styrene copolymer, polymer single-ion conductor, preparation

Hu Xiance, Liu Wanyu, Jiang Weiguo, Zong Huijuan. PREPARATION OF SINGLE-ION POLYMER CONDUCTOR—COMBLIKE POLYMERS WITH CARBOXYLATE GROUPS[J]. Chinese Journal of Applied Chemistry, 1993, 0(6): 14-18.

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PREPARATION OF SINGLE-ION POLYMER CONDUCTOR—COMBLIKE POLYMERS WITH CARBOXYLATE GROUPS

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