Preparation of β-PbO2/TiO2 Nanotube Array Electrode and Electrocatalysis Degradation of Phenol

doi:10.3724/SP.J.1095.2014.30559

Chinese Journal of Applied Chemistry

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Preparation of β-PbO₂/TiO₂ Nanotube Array Electrode and Electrocatalysis Degradation of Phenol

HONG Ping¹, WANG Fengwu^1*, XU Mai², WEI Lin³, FANG Wenyan², WEI Yijun², ZHU Chuangao²

(1.School of Chemistry and Chemical Engineering, Anhui University,Hefei 230601,China;
2.School of Chemistry and Chemical Engineering,Huainan Normal University,Huainan 232001,China;
3.School of Chemical Engineering,Anhui University of Science and Technology,Huainan 232001,China)

Received:2013-11-08 Revised:2013-12-19 Published:2014-09-03 Online:2014-09-03

Abstract

Abstract: The β-PbO2/TiO2 nanotubes(β-PbO2/TiO2-NTs) electrode was prepared using the anodic oxidation method and pulsed electrochemical deposition(PED). The properties of β-PbO2/TiO2-NTs electrode were characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The results indicate that β-PbO2 nanoparticles are successfully dispersed inside the TiO2 nanotubes. The degradation of phenol was carried out to test the electrocatalytic performance of the β-PbO2/TiO2-NTs electrode, which indicated that the β-PbO2/TiO2-NTs electrode had high electrocatalytic activities and the COD removal rate of phenol reached up to 83%.

Key words: TiO2 nanotubes, pulsed electrochemical deposition, &, beta, -PbO2, electrocatalysis, phenol

CLC Number:

O643

HONG Ping1, WANG Fengwu1*, XU Mai2, WEI Lin3, FANG Wenyan2, WEI Yijun2, ZHU Chuangao2. Preparation of β-PbO₂/TiO₂ Nanotube Array Electrode and Electrocatalysis Degradation of Phenol[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30559.

References

[1] Fujishima A,Honda K. Electrochemical Photocatalysis of Water at a Semiconductor Electrode[J]. Nature,1972,238](5358):37-38.

[2] Park H,Kim W R,Jeong H T,et al. Fabrication of Dye-Sensitized Solar Cells by Transplanting Highly Ordered TiO2 Nanotube Arrays[J]. Sol Energ Mat Sol C,2011,95](1):184-189.

[3] Liang H C,Li X Z. Effects of Structure of Anodic TiO2 Nanotube Arrays on Photocatalytic Activity for the Degradation of 2,3-Dichlorophenol in Aqueous Solution[J]. J Hazard Mater,2009,162](2/3):1415-1422.

[4] Chu D B,Xu M,Lu J,et al. Electrocatalytic Reduction of Diethyl Oximinomalonate at a Ti/Nanoporous TiO2 Electrode[J] . Electrochem Commun,2008,10]:350-353.

[5] Foong T R B，Shen Y，Hu X,et al. Template-Directed Liquid ALD Growth of TiO2 Nanotube Arrays:Properties and Potential in Photovoltaic Devices[J]. Adv Funct Maters,2010,20](9):1390-1396.

[6] Yoriya S,Paulose M,Varghese O K,et al. Fabrication of Vertically Oriented TiO2 Nanotube Arrays using Dimethyl Sulfoxide Electrolytes[J]. J Phys Chem C,2007,111](37):13770-13776.

[7] Prakasam H E,Shankar K,Paulose M,et al. A New Benchmark for TiO2 Nanotube Arrays Growth by Anodization[J]. J Phys Chem C,2007,111](20):7235-7241.

[8] FANG Zhi. ZHOU Qingxiang. Research Advances of TiO2 Nanotube Array in Environmental Field[J]. Acta Chim Sin,2012,70]:1767-1774(in Chinese).

房治,周庆祥. TiO2 纳米管阵列在环境领域的研究进展[J]. 化学学报,2012,70]:1767-1774.

[9] Chen S G,Paulose M,Ruan C M,et al. Electrochemically Synthesized CdS Nanoparticle-Modified TiO2 Nanotube-Array Photoelectrodes:Preparation, Characterization, and Application to Photoelectrochemical Cells[J]. Photochem Photobiol A,2006,177](2/3):177-184.

[10] Lei L C,Su Y L ,Zhou M H,et al. Fabrication of Multi-Non-Metal-Doped TiO2 Nanotubes by Anodization in Mixed Acid Electrolyte[J]. Mater Res Bull,2007,42](12):2230-2236.

[11] Mohapatra S K，Banerjee S，Misra M. Synthesis of Fe2O3/TiO2 Anorod-Nanotube Arrays by Filling TiO2 Nanotubes with Fe[J]. Nanotechnology,2008,19](31):315-321.

[12] Lin C J,Yu Y H,Liou Y H. Free-Standing TiO2 Nanotube Array Films Sensitized with CdS as Highly Active Solar Light-Driven Photocatalysts[J]. Appl Catal B:Environ,2009,93](1/2):119-125.

[13] MENG Xianglong,LI Hongyi,WANG Jinshu. Electrocatalytic Properties of Pt-TiO2 Nanotubes Electrode Prepared by Pulse Electrodeposition Method[J]. Chem J Chinese Univ,2012,5](33):1021-1024(in Chinese).

孟祥龙，李洪义，王金淑. 脉冲电沉积法制备Pt-TiO2纳米管电极及其电催化性能[J]. 高等学校化学学报,2012,5](33):1021-1024.

[14] SUN Mojie,HU Quan,Li Jian,et al. Preparation of ZnFe2O4/TiO2 Nanotube Array Electrode and Photoelectrocatalysis Degradation of Phenol[J]. Acta Chim Sin,2013,71]:213-220(in Chinese).

孙墨杰,胡全,李健,等. ZnFe2O4/TiO2纳米管阵列电极的制备及光电催化降解苯酚的研究[J]. 化学学报,2013,71]:213-220.

[15] Hou Y，Li X Y，Zou X J,et al. Photoeletrocatalytic Activity of a Cu2O-Loaded Self-Organized Highly Oriented TiO2 Nanotube Array Electrode for 4-Chlorophenol Degradation[J]. Environ Sci Technol,2009,43](3):858-863.

[16] Cao J L,Zhao H Y,Cao F H,et al. Electrocatalytic Degradation of 4-Chlorophenol on F-Doped PbO2 Anodes[J]. Electrochim Acta,2009,54](9):2595-2602.

[17] Li G T,Qu J H,Zhang X W,et al. Electrochemically Assisted Photocatalytic Degradation of Acid Orange 7 with β-PbO2 Electrodes Modified by TiO2[J]. Water Res,2006,40](2):213-220.

[18] Ma Q，Liu S J，Weng L Q,et al. Growth， Structure and Photocatalytic Properties of Hierarchical Cu-Ti-O Nanotube Arrays by Anodization[J]. J Alloys Compd,2010,501](2):333-338.

[19] Casellato U,Cattarin S,Musiani M. Preparation of Porous PbO2 Electrodes by Electrochemical Deposition of Composites[J]. Electrochim Acta,2003,48](27):3991-3998.

Preparation of β-PbO₂/TiO₂ Nanotube Array Electrode and Electrocatalysis Degradation of Phenol

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