Research Progress of Activated Persulfate by MOFs-Based Catalyst in Wastewater Treatment

doi:10.19894/j.issn.1000-0518.230009

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (7): 938-950.DOI: 10.19894/j.issn.1000-0518.230009

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Research Progress of Activated Persulfate by MOFs-Based Catalyst in Wastewater Treatment

Zhen-Chun TANG, Xin-Quan ZHOU, Pei-Pei WANG, Juan MIAO, Ning ZHANG, Rui-Chang ZHANG, Xue-Feng WEI()

School of Chemistry and Chemical Engineering，Henan University of Science and Technology，Luoyang 471000，China

Received:2023-01-15 Accepted:2023-05-23 Published:2023-07-01 Online:2023-07-19
Contact: Xue-Feng WEI
About author:xfwei@haust.edu.cn
Supported by:
the Intellectual Introduction Project of Henan Province(HNGD2022058);the Key Scientific Research Project of Colleges and Universities of Henan Province(23A610010)

Abstract

Abstract:

Metal-organic frameworks （MOFs） material， as a new multifunctional material， has attracted more and more attention in the field of water treatment of catalytic activation in advanced oxidation technology， due to its high surface area， adjustable pore structure， excellent thermal and chemical stability. This paper focuses on the research progress of activating persulfate by MOFs-based catalyst in the field of water treatment in recent five years. In this paper， various MOFs-based catalyst and their common synthesis methods in persulfate activation are introduced. Then， the oxidation mechanisms of MOFs-based catalyst during the activation of persulfate are summarized； the common modification methods of MOFs-based catalyst are introduced. Finally， some suggestions for the future research direction of activated persulfate by MOFs-based catalyst are put forward. This review will help to deepen the understanding of MOFs-based catalyst activating persulfate to degrade organic pollutants， and provide theoretical reference for the development of new heterogeneous MOFs-based catalysts based on PS activation.

Key words: Metal-organic frameworks, Advanced oxidation technology, Persulfate, Synthetic method, Oxidation mechanism, Modification

CLC Number:

O643

Zhen-Chun TANG, Xin-Quan ZHOU, Pei-Pei WANG, Juan MIAO, Ning ZHANG, Rui-Chang ZHANG, Xue-Feng WEI. Research Progress of Activated Persulfate by MOFs-Based Catalyst in Wastewater Treatment[J]. Chinese Journal of Applied Chemistry, 2023, 40(7): 938-950.

Figures/Tables 6

Fig.1 Topological structures and structural primitives of several typical MOFs-based catalyst

Table 1 Summary of MOFs-based catalyst in the field of persulfate activation

MOFs-based catalyst	Strengths	Precursor	Catalyst	Contaminant	Ref.
MILs catalysts	Porosity， large surface area and unsaturated metal coordination	MIL-88A（Fe）	MIL-88A（Fe）/MoS₂	Bisphenol A	［24］
		MIL-88B（Fe）	MGA	Norfloxacin	［25］
		MIL-53（Fe）	MIL-53（Fe）/BiOCl	Rhodamine B	［26］
		MIL-101（Fe）	CuS@MIL-101（Fe）	Coumarin	［27］
		MIL-53（Fe）	Mn-MIL-53（Fe）	Tetracycline	［31］
		MIL-101（Fe）	g-C₃N₄/MIL-101（Fe）	Bisphenol A	［49］
ZIFs catalysts	Good thermal and chemical stability	ZIF-8	Fe₃O₄-MnO₂-ZIF-8	Bisphenol A	［36］
		ZIF-67	ZIF-67	Rhodamine B	［37］
		ZIF-9	ZIF-9	Rhodamine B	［39］
		ZIF-12	ZIF-12	Rhodamine B	［39］
n-BTCs catalysts	Contains Lewis acid active sites	Co-BTC	Co-BTC（A） Co-BTC（B）	Dibutyl phthalate	［40］
n-BTCs catalysts	Contains Lewis acid active sites	HKUST-1	HKUST-1	Rhodamine B	［43］

Fig.2 Schematic diagram of synthesis of MOFs-based catalyst［50］

Fig.3 Oxidation mechanism diagram of activated persulfate from several typical MOFs-based catalyst. （A） Possible mechanism diagram of SO4?- participating in the degradation of 4-chlorophenol in Co3O4@ MOFs nanoreactor［56］；（B） The ·OH production on MIL-100（Fe）［57］；（C） Schematic diagram of 1O2 participating in degradation in Cu-TCPP（BA）-MOF/PMS/Vis system［44］；（D） Fe-MOF-74@SiO2 diagram of possible mechanism of activation of PS to produce SO4?- and ·OH［58］

Table 2 MOFs-based catalysts and their activation of persulfates produce main reactive oxygen species

Catalyst	Precursor	Contaminant	Oxidant	Removal rate/%	ROS	Ref.
M/Z₂	ZIF-67 MIL-101（Fe）	2-Chlorophenol （0.78 mmol/L）	PMS（0.98 mmol/L）	90	SO $4 ? -$ ·OH ¹O₂	［23］
MSMIL	MIL-88A（Fe）	Bisphenol A （0.11 mmol/L）	PMS（1.63 mmol/L）	98.2	SO $4 ? -$ ·OH·O $2 ? -$ ¹O₂	［24］
CuS@MIL-101（Fe）	MIL-101（Fe）	Coumarin （0.03 mmol/L）	PMS（0.5 mmol/L）	100	SO $4 ? -$ ·OH ¹O₂	［27］
Fe₃O₄-MnO₂-ZIF-8	ZIF-8	Bisphenol A （0.26 mmol/L）	PMS（0.98 mmol/L）	100	SO $4 ? -$ ·OH	［36］
ZIF-67/PAN	ZIF-67	Acid yellow 17 （0.91 mmol/L）	PMS（1.63 mmol/L）	95.1	SO $4 ? -$ ·OH	［38］
Co-BTC（A）	Co-BTC	Dibutyl phthalate （0.018 mmol/L）	PMS（1.08 mmol/L）	100	SO $4 ? -$ ·OH	［40］
Cu-MOF-74/PVDF	MOF-74	Rhodamine B （0.04 mmol/L）	PMS（1.5 mmol/L）	97.1	SO $4 ? -$ ·OH	［47］

Table 2 MOFs-based catalysts and their activation of persulfates produce main reactive oxygen species

Catalyst	Precursor	Contaminant	Oxidant	Removal rate/%	ROS	Ref.
M/Z₂	ZIF-67 MIL-101（Fe）	2-Chlorophenol （0.78 mmol/L）	PMS（0.98 mmol/L）	90	SO $4 ? -$ ·OH ¹O₂	［23］
MSMIL	MIL-88A（Fe）	Bisphenol A （0.11 mmol/L）	PMS（1.63 mmol/L）	98.2	SO $4 ? -$ ·OH·O $2 ? -$ ¹O₂	［24］
CuS@MIL-101（Fe）	MIL-101（Fe）	Coumarin （0.03 mmol/L）	PMS（0.5 mmol/L）	100	SO $4 ? -$ ·OH ¹O₂	［27］
Fe₃O₄-MnO₂-ZIF-8	ZIF-8	Bisphenol A （0.26 mmol/L）	PMS（0.98 mmol/L）	100	SO $4 ? -$ ·OH	［36］
ZIF-67/PAN	ZIF-67	Acid yellow 17 （0.91 mmol/L）	PMS（1.63 mmol/L）	95.1	SO $4 ? -$ ·OH	［38］
Co-BTC（A）	Co-BTC	Dibutyl phthalate （0.018 mmol/L）	PMS（1.08 mmol/L）	100	SO $4 ? -$ ·OH	［40］
Cu-MOF-74/PVDF	MOF-74	Rhodamine B （0.04 mmol/L）	PMS（1.5 mmol/L）	97.1	SO $4 ? -$ ·OH	［47］

Table 3 Comparison of common modification methods and activation efficiency of PS in MOFs-based catalyst

Modification method	Catalyst	Precursor	Contaminant	Oxidant	Time/min	Removal rate/%	Ref.
Ion doping	Mn-MIL-53（Fe）（200 mg/L）	MIL-53（Fe）	Tetracycline （30 mg/L）	PMS （0.98 mmol/L）	60	93.2	［31］
Combined functional material	CoFe₂O₄/ZIF-8 （50 mg/L）	ZIF-8	Methylene blue （20 mg/L）	PMS （0.98 mmol/L）	60	97.9	［62］
Ion doping	FeCu-MOF （600 mg/L）	Fe-MOF	Methylene blue （64 mg/L）	PMS （6 mmol/L）	30	100	［71］
Functional group modification	NH₂-MIL-88B（Fe）（600 mg/L）	MIL-88B（Fe）	Acid orangeⅡ（20 mg/L）	PMS （1.3 mmol/L）	25	97	［72］
Construction of core-shell structure	α-Fe₂O₃/ZIF-67 （100 mg/L）	ZIF-67	Ciprofloxacin （20 mg/L）	PMS （0.65 mmol/L）	30	100	［74］
Combined functional material	Mn₃O₄/ZIF-8 （400 mg/L）	ZIF-8	Rhodamine B （10 mg/L）	PMS （0.98 mmol/L）	60	98	［76］

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Research Progress of Activated Persulfate by MOFs-Based Catalyst in Wastewater Treatment

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