Effect of Ionic Liquid on the Performance of Perovskite Solar Cells

doi:10.11944/j.issn.1000-0518.2018.02.170106

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (2): 216-223.DOI: 10.11944/j.issn.1000-0518.2018.02.170106

• Full Papers • Previous Articles Next Articles

Effect of Ionic Liquid on the Performance of Perovskite Solar Cells

ZHAO Liping^a^b,WANG Zhen^a^*(),DONG Xiandui^a^*()

^aPolymer Composites Engingeering Laboratory,Changchun Institute of Applied Chemistry,Chinese Acdemy of Sciences,Changchun 130022,China
^bUniversity of Chinese Acdemy of Sciences,Beijing 100049,China

Received:2017-04-12 Accepted:2017-07-03 Published:2018-02-01 Online:2018-01-29
Contact: WANG Zhen,DONG Xiandui
Supported by:
Supported by the Science and Technology Support Project of Jiangsu Province(No.BE2014147)

Abstract

Abstract:

Controling the morphology of the perovskite film is an effective way to improve the photoelectric conversion efficiency of the cells. In this work, 1-ethyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] imide(EMITFSI), 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] imide(HMITFSI) and 1-ethyl-3-methy-limidazolium bis(fluorosulfonyl) imide(EMIFSI) were prepared. Perovskite active layers were dealed with ionic liquid dispersed into the chlorobenzene solution, the morphology of the perovskite layer and the performance of perovskite solar cells were investigated. The results indicate that the fill factor of perovskite solar cells dealed with HMITFSI is enhanced from 0.71 to 0.74, and the photoelectric conversion efficiency is increased, and that the morphology of perovskite is also improved. However, the performance of perovskite solar cells dealed with EMITFSI and EMIFSI are declined. It is HMI cation that improves the morphology of perovskite.

Key words: ionic liquid, perovskite, soaking treatment, morphology

ZHAO Liping, WANG Zhen, DONG Xiandui. Effect of Ionic Liquid on the Performance of Perovskite Solar Cells[J]. Chinese Journal of Applied Chemistry, 2018, 35(2): 216-223.

References

[1]	Kojima A,Teshima K,Shirai Y,et al.Organometal Halide Perovskites as Visible-light Sensitizers for Photovoltaic Cells[J]. J Am Chem Soc,2009,131(17):6050-6051.
[2]	Im J H,Lee C R,Lee J W,et al.6.5% Efficient Perovskite Quantum-dot-sensitized Solar Cell[J]. Nanoscale,2011,3(10):4088-4093.
[3]	Kim H S,Lee C R,Im J H,et al.Lead Iodide Perovskite Sensitized All-solid-state Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%[J]. Sci Rep,2012,2:591.
[4]	Saliba M,Matsui T,Domanski K,et al.Incorporation of Rubidium Cations into Perovskite Solar Cells Improves Photovoltaic Performance[J]. Scince,2016,354(6309):206-209.
[5]	SHAO Zhipeng,PAN Xu,ZHANG Xuhui,et al.Influence of Structure and Morphology of Perovskite Films on the Performance of Perovskite Solar Cells[J]. Acta Chim Sin,2015,73(3):267-271(in Chinese). 邵志鹏,潘旭,张旭辉,等. 薄膜结构及形貌对钙钛矿电池性能的影响[J]. 化学学报,2015,73(3):267-271.
[6]	ZHU Lifeng,SHI Jiangjian,LI Dongmei,et al.Effect of Mesoporous TiO2 Layer Thickness on the Cell Performance of Perovskite Solar Cells[J]. Acta Chim Sin,2015,73(3):261-266(in Chinese). 朱立峰,石将建,李冬梅,等. 多孔 TiO2层厚度对钙钛矿太阳能电池性能的影响[J]. 化学学报,2015,73(3):261-266.
[7]	Kim J K,Matic A,Ahn J H,et al.An Imidazolium Based Ionic Liquid Electrolyte for Lithium Batteries[J]. J Power Sources,2010,195(22):7639-7643.
[8]	Shamsipur M,Beigi A A M,Termouri M,et al. Physical and Electrochemical Properties of Ionic Liquids 1-Ethyl-3-methylimidazolium Etrafluoroborate, 1-Butyl-3-methylimidazolium Trifluoromethanesulfonate and 1-Butyl-1-methyl-pyrrolidinium Bis(trifluoromethylsulfonyl)mide[J]. J Mol Liq,2010,157(1):43-50.
[9]	Balducci A, Bardi U,Caporali S,et al.Ionic Liquids for Hybrid Supercapacitors[J]. Electrochem Commun,2004,6(6):566-570.
[10]	Balducci A,Dugas R,Taberna P L,et al.High Temperature Carbon-carbon Supercapacitor Using Ionic Liquid as Electrolyte[J]. J Power Sources,2007,165(2):922-927.
[11]	Padiha J C,Basso J,Trindade L,et al.Ionic Liquids in Proton Exchange Membrane Fuel Cells:Efficient Systems for Energy Generation[J]. J Power Sources,2010,195(19):6483-6485.
[12]	Schmid C,Gluck T,Schmidt-Naake G,et al.Modification of Nafion Membranes by Impregnation with Ionic Liquids[J]. Chem Eng Technol,2008,31(1):13-22.
[13]	ZHANG Yingfeng,LI Changjiang,BAO Fushan.Classification, Synthesis and Application of Ionic Liquids[J]. Chinese J Chem Educ,2005,26(2):7-12(in Chinese). 张英锋,李长江,包富山. 离子液体的分类、合成与应用[J]. 化学教育,2005,26(2):7-12.
[14]	Michot C,Armand M,Gauthier M,et al.Materials Useful as Electrolytic Solutes:US Patent 6365301[P],2002.
[15]	Eperon G E,Burlakov V M,Docampo P,et al.Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells[J]. Adv Funct Mater,2014,24(1):151-157.
[16]	Che M,Zhu Y L,Yao D S,et al.Enhancing Current Density of Perovskite Solar Cells Using TiO2-ZrO2 Composite Scaffold Layer[J]. Mater Sci Semicond Process,2016,56:29-36.
[17]	Liu M,Johnston M B,Snaith H J,et al.Efficient Planar Heterojunction Perovskite Solar Cells by Vapour Deposition[J]. Nature,2013,501(7467):395-398.
[18]	Im J H. Jang I H,Pellet N,et al.Growth of CH3NH3PbI3 Cuboids with Controlled Size for High-efficiency Perovskite Solar Cells[J]. Nat Nanotechnol,2014,9(11):927-932.
[19]	You J,Hong Z,Yang Y,et al.Low-temperature Solution-processed Perovskite Solar Cells with High Efficiency and Flexibility[J]. ACS Nano,2014,8(2):1674-1680.

Effect of Ionic Liquid on the Performance of Perovskite Solar Cells

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Hui-Hui LI, Kai-Sheng YAO, Ya-Nan ZHAO, Li-Na FAN, Yu-Lin TIAN, Wei-Wei LU. Ionic Liquid-Modulated Synthesis of Pt-Pd Bimetallic Nanomaterials and Their Catalytic Performance for Ammonia Borane Hydrolysis to Generate Hydrogen [J]. Chinese Journal of Applied Chemistry, 2023, 40(4): 597-609.
[2]	Qi-Hang CHEN, Fei-Jian XU, Feng WANG, Shuang-Chan FU, Ying-Hao YU. Research Progress of Deep Eutectic Solvent and Its Application Prospects as Antistatic Agents [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 341-359.
[3]	Peng BU, Hong-Liang LI. Preparation and Upconversion Luminescence Study of Rare Earth Yb³⁺/Tm³⁺ Doped NaGd（MO₄）₂ Phosphors [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 374-379.
[4]	Ting WANG, Qi WEI, Qiang FU, Wei LI, Shi-Wei WANG. Review of Perovskite Photovoltaic Cell Encapsulation Material and Technology [J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1321-1344.
[5]	Guo-Hua DONG, Li-Juan HAO, Wen-Zhi ZHANG, Dong-Feng CHAI, Ming ZHAO, Kun LANG. Recent Progress on the Application of Carbon Quantum Dots Nano⁃materials in Lead Halogen Perovskite Solar Photoelectric Devices [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 707-722.
[6]	Yong-Xin TANG, Li-Wu NIE. Effect of Epoxy Resin Content on the Performance of Luminous Resin Permeable Concrete [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1665-1671.
[7]	Shuang WU, De-Yang ZHAO, Sheng-Han WU, Li-Gang WEI, Na LIU, Qing-Da AN. Insights into the Dissolution of Lignin Model Phenolic Monomer in 1‑Butyl‑3‑methylimidazolium Methanesulfonate Aqueous Solutions Using Two‑Dimensional Correlation Infrared Spectroscopy [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1600-1609.
[8]	Ou-Wen HE, Chang-Fu SUN, Hong-Bing YU. Optimization on the Production of Furfural from Corncob in Cheap Ionic Liquid System [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 272-282.
[9]	NIU Zhan-Ning, TANG Hao-Qing, ZHENG Chao, TIAN Tian, ZHENG Li-Yun. Study on [RESA]Br@-COOH@Fe₃O₄ with Density Functional Theory [J]. Chinese Journal of Applied Chemistry, 2021, 38(7): 825-835.
[10]	ZHU Meng-Meng, BAI Jue-Yao, CHEN Ren-Jie, LI Hui-Li. Synthesis and Properties of B-Site Doped All-Inorganic Perovskite Quantum Dots [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1541-1555.
[11]	Ai-Hua CHEN, Cheng-Yun ZHANG, Zi-Chao DENG, Ya-Lan SUN. Structure Control of Liquid Crystalline Block Copolymers in Liquid⁃Phase Self⁃assembly [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1255-1267.
[12]	Yong-Jie CUI, Jia-Xin ZHONG, Xun-Fan LIAO, Yi-Wang CHEN. Research Progress of Liquid Crystal Molecules for Application in Organic Solar Cells [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1326-1339.
[13]	ZHOU Chao, SHENG Cheng-Ju, WEN Lin-Lin. Preparation of Imidazolium Salt-based Poly(ionic liquids) Antibacterial Agent and Its Application in Hydrogel Dressing [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 51-59.
[14]	LIU Ning, WANG Danfeng, WU Suyun, LIU Shuilin, FU Lin, LIU Yuejin. Catalytic Synthesis of Bisphenol F over Short-Channeled Mesoporous Molecular Sieve Zr-Ce-SBA-15 Supported Acidic Ionic Liquids [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1038-1047.
[15]	ZHANG Jingjing, XIAO Xin, SHI Dongjian, CHEN Mingqing. Morphology Regulation of Polydopamine Self-polymerization on the Surface of Strongly Electronegative Microspheres [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 756-763.