Corrosion Resistance of Dodecyltriethoxysilane/Graphene Oxide Composite Film on 430 Stainless Steel

doi:10.11944/j.issn.1000-0518.2015.01.140088

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (1): 93-98.DOI: 10.11944/j.issn.1000-0518.2015.01.140088

• Full Papers • Previous Articles Next Articles

Corrosion Resistance of Dodecyltriethoxysilane/Graphene Oxide Composite Film on 430 Stainless Steel

CAO Zhiyong^a,b, LU Chen^b, QU June^b, ZHEN Guohui^b, CHENG Cong^b, WANG Hairen^b*

(^aDepartment of Material Science and Engineering，Huazhong University of
Science and Technology,Wuhan 430074,China;
^bDepartment of Material Science and Engineering，Key Laboratory of Green
Preparation and Application for Materials,Hubei University,Wuhan 430062,China)

Received:2014-03-21 Revised:2014-06-23 Published:2015-01-06 Online:2015-01-06
Contact: WANG Hairen, professor; Tel:027-88661729; E-mail:whr9999whr@163.com; Research interests:treatment on metal surface
Supported by:
Supported by the National Natural Science Foundation of China(No.51001045)

Abstract

Abstract:

The novel dodecyltriethoxysilane(DTES)/graphene oxide(GO) composite film is prepared via onestep electrodeposition onto 430 stainless steels. Raman spectroscopy measurement and scanning electron microscopy(SEM) measurement suggest efficient encapsulation of GO. Both electrochemical impedance spectroscopy measurement and polarization tests show that composite films have effectively improved the corrosion resistance of 430 stainless steel in 3.5% mass fraction of NaCl solution. The excellent corrosion resistance of well-dispersed GO fill the crack of silane matrix, and the corrosion medium encounter a more tortuous path in traversing in silane matrix, resulting in an improved corrosion protection performance of the composite films.

Key words: graphene oxide, stainless steel, silane, electrodeposition, corrosion protection

CLC Number:

O646
TG172

CAO Zhiyong, LU Chen, QU June, ZHEN Guohui, CHENG Cong, WANG Hairen. Corrosion Resistance of Dodecyltriethoxysilane/Graphene Oxide Composite Film on 430 Stainless Steel[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 93-98.

References

[1] WANG Zaide,DENG Yun. Study of Silane Pretreatment to Improve Corrosion Resistance of Coatings on Aluminum Alloy[J]. Paint Coat Ind ,2013,43(7):76-80(in Chinese).
王再德,邓赟. 硅烷预处理提高铝合金表面涂层耐腐蚀性的研究[J]. 涂料工业,2013,43(7):76-80.
[2] JIANG Weili,WANG Ying,LIU Huarong, et al . Preparation of Environmental Metal Surface Protection Agents and Study on Corrosion Protection[J]. Heilongjiang Sci ,2011,2(2):13-15(in Chinese).
姜卫丽,王颖,刘华荣,等. 环保型金属表面处理剂的制备及耐蚀性能研究[J]. 黑龙江科学,2011,2(2):13-15.
[3] SHI Min,PANG Zhicheng,XU Yudong, et al . Research and Prospect of Silane Treatment on Metal Surface[J]. Met Funct Mater ,2011,18(6):62-66(in Chinese).
石敏,庞志成,许育东,等. 硅烷化金属表面处理的研究进展及展望[J]. 金属功能材料,2011,18(6):62-66.
[4] XU Yudong,CHEN Yunbang,SHI Min, et al . Surface Treatment Application of Silane on Metals[J]. Met Funct Mater ,2011,18(5):65-69(in Chinese).
许育东,陈云帮,石敏,等. 金属表面硅烷化处理应用的研究[J]. 金属功能材料,2011,18(5):65-69.
[5] YAN Bin,CHEN Hongxia,CHEN Jiabin. Current Status and Perspectives in Study of Organo-Functional Silane Films for Corrosion Prevention and Protection of Metals[J]. Mater Prot ,2009,42(3):54-57(in Chinese).
闫斌,陈宏霞,陈嘉宾. 功能性有机硅烷膜对金属腐蚀防护的研究现状及展望[J]. 材料保护,2009,42(3):54-57.
[6] Woo H,Reucroft P J,Jacob R J. Electrodeposition of Organofunctional Silanes and Its Influence on Structural Adhesive Bonding[J]. J Adhes Sci Technol ,1993,7(7):681-697.
[7] Palanivel V,Zhu D Q,Van Ooij W J, et al . Nanoparticle-filled Silane Films as Chromate Replacements for Aluminum Alloys[J]. Prog Org Coat ,2003,47(3/4):384-392.
[8] Kovtyukhova N I,Ollivier P J Martin B R, et al . Layer-by-layer Assembly of Ultrathin Composite Films From Micron-sized Graphite Oxide Sheets and Polycations[J]. Chem Mater ,1999,11(3):771-778.
[9] TAN Pingheng,LI Feng,CHENG Huiming. Raman Spectroscopy In Carbons:From Nanotube to Diamond[M]. Beijing:Press of Chemical Industry,2007(in Chinese).
谭平恒,李峰,成会明. 碳材料的拉曼光谱——从纳米管到金刚石[M]. 北京:化学工业出版社,2007.
[10] Ramesh P,Bhagyalakshmi S,Sampath S. Prepareation and Physicochemical and Electrochemical Charaeterization of Exfoliated Graphite Oxide[J]. J Colloid Interface Sci ,2004,274(1):95-102.
[11] Chieu T C,Dresselhaus M S,Endo M. Raman Studies of Benzene-derived Graphite Fibers[J]. Phys Rev B ,1982,26:5867-5877.
[12] Wang D H,Choi D W,Li J, et al .,Self-assembled TiO₂/graphene Hybrid Nanostructures for Enhanced Li-ion Insertion[J]. ACS Nano ,2009,3:907-914.
[13] CAO Chu'nan,ZHANG Jianqing. An Introduction To Electrochemical Impedance Spectroscopy[M]. Beijing:Press of Science,2002:156-160(in Chinese).
曹楚南,张鉴清. 电化学阻抗谱导论[M] . 北京:科学出版社,2002:156-160.

[1]	Nan-Yu LIN, Feng GAO, Jiang-Ying QU, Jing-Jing TU, Wei-Jun ZHONG, Yun-Hao ZANG. Preparation of Super-hydrophilic/Underwater Oil-phobic High Silicon Cloth and Its Oil-water Separation Performance [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 449-459.
[2]	Yue-Hua ZHAO, Da-Peng WANG. Coadsorption Kinetics of Amino‑Functionalized Graphene Oxide and Fatty Acids at the Water/Oil Interface [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1274-1284.
[3]	Shan SHAO, Jian ZHANG, Kai-Qiang DENG, Jie YANG, Shao-Ming YANG. Detection of Dopamine by Enzyme‑Free Sensor Constructed by Nickel‑Cobalt Bimetallic‑porphyrin Organic Framework Composites [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1098-1107.
[4]	Qing-Fang NIU, Xin AI, Yi-Xuan WANG, Fang-Jiu HE, Bi LUO, Wen-Ting LIANG, Chuan DONG. Synthesis of Three‑Dimensional Reduced Graphene Oxide/β‑Cyclodextrin Complex and Its Electrochemical Detection of Levofloxacin in Water [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1129-1137.
[5]	Yi-Xin XU, Shuang WANG, Jing QUAN, Wan-Ting GAO, Tian-Qun SONG, Mei YANG. Preparation of Molybdenum Disulfide Quantum Dots/Reduced Graphene Oxide Composites and Their Photocatalytic Degradation of Organic Dyes， Tetracyclines and Cr（VI） [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 769-778.
[6]	LIU Wen-Bin, YANG Sha-Sha, HUANG Guo-Lin, FAN Li-Jiao, XIE Yu-Ming. Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 658-667.
[7]	ZHANG Ya-Jing, WANG Xiao-Hui, XU Ya-Juan, LIU Wen-Shu, ZHAO Li-Hui. Preparation of Graphene Nano-Drug Carrier System and Its Killing Effect on Tumor Cells [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 693-703.
[8]	XIAO Haimei, CAI Lei, ZHANG Zhaohui, CHEN Shan, ZHOU Shu, FU Jinli. Preparation of Ion-Imprinted Polymers Based on Magnetic Graphene Oxide/MIL-101 (Cr) and Selective Adsorption of Cu(Ⅱ) and Pb(Ⅱ) [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1076-1086.
[9]	GAO Siheng, YANG Yu, WU Jinling, QIN Lixia, KANG Shizhao, LI Xiangqing. Preparation and Photoelectric Performance of Graphene Oxide/Ultrafine Silver Composite [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 923-929.
[10]	WANG Wei, LI Juan, BAI Ru, HAN Zhen, FENG Xuewei, SUN Yue. Preparation of Au/Polyacrylamide@Graphene Oxide/Nano-palladium Electrode via Metal-Free Visible-Light-Induced Atom Transfer Radical Polymerization and Its Detection of Ethanol [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 595-603.
[11]	MA Hao, ZHAO Xue, LI Kunlan, SHAO Guolin, AN Qingda, YANG Liyu, WEI Ligang. Evaluation of Silane Imidazolium Bis(trifluoromethane)sulfonimide Ionic Liquid Stationary Phase for Gas Chromatography [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 447-454.
[12]	HUO ZhaoHui, YANG Xiaoshan, CHEN Xiaoli, ZHANG Gang, YIN Wei, CAO Manli, SHI Lei, QIU Yanxuan. Preparation of Ag/Two-Dimensional Graphitic Carbon Nitride/Reduced Graphene Oxide Composite and Its Photocatalytic Degradation of Antibiotics [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 471-480.
[13]	DONG Xun, ZHU Xiaping, CUI Ting. Preparation and Properties of Mercapto Bentonite [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 1156-1163.
[14]	YU Zhiqiang, QU Jiangying, LI Jielan, ZANG Yunhao, GU Jianfeng, GAO Feng. Assembly of Graphene Oxide-Based Flexible Generator and Its Water Evaporation Power Generation Performance [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 1164-1171.
[15]	YU Zhiqiang, QU Jiangying, LI Jielan, ZANG Yunhao, GU Jianfeng, GAO Feng. Assembly of Graphene Oxide-Based Flexible Generator and Its Water Evaporation Power Generation Performance [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 0-0.

Corrosion Resistance of Dodecyltriethoxysilane/Graphene Oxide Composite Film on 430 Stainless Steel

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments