应用化学 ›› 2024, Vol. 41 ›› Issue (4): 484-495.DOI: 10.19894/j.issn.1000-0518.230373
• 综合评述 • 上一篇
收稿日期:
2023-11-28
接受日期:
2024-02-11
出版日期:
2024-04-01
发布日期:
2024-04-28
通讯作者:
黄科科
基金资助:
Yi ZHANG, Yu-Tong CHEN, Jing-Yu SHI, Ke-Ke HUANG()
Received:
2023-11-28
Accepted:
2024-02-11
Published:
2024-04-01
Online:
2024-04-28
Contact:
Ke-Ke HUANG
About author:
kkhuang@jlu.edu.cnSupported by:
摘要:
近几年,应用碳材料负极和有机电解液的液态锂离子电池(LIBs)的弊端日益凸显,电解液泄漏和过热燃烧等安全事故频发。 另外,传统的LIBs也无法满足当今社会对高能量密度电池的需求。 由于上述LIBs存在的诸多缺点,市场急需开发兼顾高能量密度与高安全性能的新型电池,现已发现可通过引入固态电解质的途径来实现。 固态锂电池(SSLBs)相较于传统的LIBs,具有较高的能量密度、较宽的工作温度范围和更高的安全性。 其中,固态电解质作为固态电池的重要元件之一,对电池性能的影响至关重要。 石榴石Li7La3Zr2O12凭借其高锂离子电导率(1×10-4~1×10-3 S/cm)、宽电化学窗口(9 V)以及对锂负极的高稳定性等优点,在众多固态电解质中脱颖而出。 本综述就提高石榴石基电解质锂离子电导率的研究予以总结: 首先,介绍了Li7La3Zr2O12晶体结构并分析了结构与电导率之间的关系; 然后,综述了几种提高电导率的方法,包括引入掺杂离子、改进烧结技术和添加烧结助剂等; 最后,提出了石榴石基固态电池的未来发展的挑战,为固态电解质相关研究提供参考。
中图分类号:
张轶, 陈宇童, 师靖宇, 黄科科. 石榴石Li7La3Zr2O12固态电解质电导率优化策略研究进展[J]. 应用化学, 2024, 41(4): 484-495.
Yi ZHANG, Yu-Tong CHEN, Jing-Yu SHI, Ke-Ke HUANG. Research Progress of Optimizing Conductivity of Garnet-Type Solid Electrolyte Li7La3Zr2O12[J]. Chinese Journal of Applied Chemistry, 2024, 41(4): 484-495.
图1 (a)立方相和(b)四方相Li7La3Zr2O12结构[33]; (c)立方相和(d)四方相中锂排列的环状结构[31]
Fig.1 The structure of (a) cubic and (b) tetragonal Li7La3Zr2O12[33]; The loop structures constructed by Li atomic arrangement in (c) cubic and (d) tetragonal phase[31]
图3 (a) Li6.4A0.2La3Zr2O12(A=Al、Fe、Ga)的Nyquist图[42]; (b) LLZO中Zr位点掺杂离子半径和离子电导率总结[61]; (c)高密度和低密度LLZO中锂成核和传播机制示意图[62]
Fig.3 (a) Nyquist plots of Li6.4A0.2La3Zr2O12 (A=Al, Fe, Ga)[42]; (b) Summary of dopant ion radius and ion conductivity of Zr site in LLZO[61]; (c) Schematic illustration of Li nucleation and propagation mechanisms in high-density and low-density LLZO[62]
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