二氧化硫在化学资源化利用中的研究进展

doi:10.19894/j.issn.1000-0518.210078

摘要/Abstract

摘要：

二氧化硫（SO₂）过量排放对自然环境造成了严重威胁，使得SO₂的捕集和利用在工业生产中被广泛关注。目前，SO₂的捕集技术已经相对成熟，对捕集后SO₂的高附加值利用成为当前的热点问题。在SO₂利用方法中，化学资源化利用由于具有原子经济性高、能耗低等优点，是实现SO₂高附加值最有前景的方法之一。本文综述了SO₂在无机反应中的氧化、还原反应，有机反应中的小分子、大分子方面的转化研究进展。介绍了SO₂在化学资源化利用中的反应机理、反应条件、转化效果，以及不同催化剂的应用对反应效果的影响等情况；指出了在SO₂化学利用中反应条件严苛、对催化剂依赖性高等方面的问题；展望了在SO₂化学资源化利用研究中的进一步重点研究方向。

关键词: 二氧化硫, 化学利用, 还原, 氧化, 催化, 加成, 共聚

Abstract:

Excessive emission of sulfur dioxide (SO₂) poses a serious threat to the natural environment, making the capture and utilization of SO₂widely concerned in industrial production. Currently, technologies of capturing SO₂have been relatively mature, and the value-added utilization of the captured SO₂has become a hot-point issue. Among various SO₂utilization technologies, chemical utilization is considered to be one of the most promising methods for realizing value-addition of SO₂because of the advantages of excellent atomic economy and low energy consumption. In this paper, the oxidation and reduction of SO₂and organic synthesis using SO₂in inorganic and organic reactions are reviewed. The reaction mechanism and reaction conditions of conversion of SO₂, and the influence of different catalysts on the reactions are introduced. The challenges of severe reaction conditions and high dependence on catalysts in chemical utilization of SO₂are pointed out. The further research directions of chemical utilization of SO₂are prospected.

Key words: Sulfur dioxide, Chemical utilization, Reduction, Oxidation, Catalysis, Addition, Polymerization

中图分类号:

O613
O627

陈颖, 胡天丁, 刘云利, 张蒲, 支云飞, 陕绍云. 二氧化硫在化学资源化利用中的研究进展[J]. 应用化学, 2022, 39(02): 223-234.

Ying CHEN, Tian-Ding HU, Yun-Li LIU, Pu ZHANG, Yun-Fei ZHI, Shao-Yun SHAN. Research Progress on Chemical Resourse Utilization of Sulfur Dioxide[J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 223-234.

图/表 10

图1 SO2化学资源化利用途径示意图

Fig.1 Scheme of SO2chemical resource utilization

图2 CO还原SO2反应程序机理图［17］

Fig.2 Mechanism of reduction of SO2by CO［17］

图3 系列三组分钴基催化剂催化SO2还原机理图［25］

Fig.3 SO2reduction catalyzed by a series of three-component cobalt-based catalysts［25］

图4 V2O5WO3／TiO2催化剂上SO2反应生成SO3的反应示意图［38］

Fig.4 Conversion of SO2to SO3on V2O5WO3／TiO2catalyst［38］

图5 利用铜尾矿去除SO2的反应机理［41］

Fig.5 Mechanism for removing SO2using copper tailing［41］

图6 SO2捕获固定法合成环亚硫酸酯（2a）［51］

Fig.6 Synthesis of sulfite 2a by SO2capture and fixation method［51］

图7 钯催化芳基硼酸、SO2和肼三组分反应可能的机理［61］

Fig.7 Possible mechanism of the three-component reaction of aryl boric acid，SO2and hydrazine catalyzed by palladium［61］

图8 光催化下SO2合成二烷基砜的合成机制［68］

Fig.8 Synthesis mechanism of dialkyl sulfone from SO2under photocatalysis［68］

图9 纤维素Cr（Salen）型催化剂催化SO2与环氧环己烷共聚机理图［77］

Fig.9 Mechanism of SO2and cyclohexene oxide copolymerization catalyzed by cellulose Cr（Salen）type catalyst［77］

图10 SO2和可再生丁香酚反应示意图［44］

Fig.10 Scheme of reaction between SO2and regenerated eugenol［44］

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