金属硫(磷)化物用于电化学析氢反应

doi:10.11944/j.issn.1000-0518.2018.09.180180

摘要/Abstract

摘要：

电化学分解水(Water Splitting)是获得高纯度氢能的重要手段。因此,开发具有高活性低成本的电化学析氢反应(Hydrogen Evolution Reaction,HER)催化剂成为目前能源环境的研究热点之一。本文总结了常用于HER反应的过渡金属硫化物以及磷化物非贵金属催化剂材料的合成方法,并且概况了如何构建特殊结构的金属硫化物及磷化物材料以调高材料的HER催化反应性能的方法,为开发其它高活性的非贵金属催化剂提供依据。

关键词: 金属硫化物, 金属磷化物, 电化学, 析氢反应

Abstract:

Water Splitting is an important method for hydrogen production in high purity and large quantities. Thus, developing high-performance, low-cost catalysts for hydrogen evolution reaction(HER) is of great importance. In this review, we systematically summarize the synthetic method for metal sulfide/phosphide-based catalysts as non-precious metal catalysts for HER reaction, and the method for enhancing the HER catalytic activity through constructing metal sulfide/phosphide with unique structure, which can provide guidance for developing new type HER catalysts with high catalytic activity.

Key words: metal sulfide, metal phosphide, electrochemistry, hydrogen evolution reaction

于鹏,李景虹. 金属硫(磷)化物用于电化学析氢反应[J]. 应用化学, 2018, 35(9): 1093-1101.

YU Peng,LI Jinghong. Metal Sulfide(Phosphide) for Electrocatalytic Hydrogen Evolution Reaction[J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1093-1101.

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