Fe基催化剂上二氧化碳加氢制C2+烃的研究进展

doi:10.11944/j.issn.1000-0518.2016.02.150431

摘要/Abstract

摘要：

将二氧化碳(CO₂)催化加氢转化为具有高附加值的烃类化合物,既可减缓大气中CO₂浓度的攀升速度,又符合可持续发展战略,对环境和社会均具有重要意义。本文综述了Fe基催化剂上CO₂加氢制C₂+烃的研究进展,着重介绍了反应路径及机理、催化剂研制及反应器设计,展望了CO₂制烃的研究前景。

关键词: 二氧化碳, 催化加氢, Fe基催化剂, 烃类合成

Abstract:

Catalytic conversion of carbon dioxide(CO₂) to value-added hydrocarbons is of great environmental and social importance, which can not only reduce CO₂ concentration in the atmosphere, but also conform with sustainable development strategy. This paper reviews the progress in catalytic conversion of CO₂ to C₂+ hydrocarbons over Fe-based catalyst. Reaction pathway and mechanism, catalyst preparation and reactor design are emphatically introduced. In addition, the future of hydrocarbons synthesis via CO₂ hydrogenation is also summarized.

Key words: carbon dioxide, hydrogenation, Fe-based catalyst, hydrocarbons synthesis

丁凡舒,聂小娃,刘民,宋春山,郭新闻. Fe基催化剂上二氧化碳加氢制C₂+烃的研究进展[J]. 应用化学, 2016, 33(2): 123-132.

DING Fanshu,NIE Xiaowa,LIU Min,SONG Chunshan,GUO Xinwen. Research Progress in Catalytic Conversion of Carbon Dioxide to C₂+ Hydrocarbons over Fe-Based Catalysts[J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 123-132.

参考文献

[1]	International Energy Agency. CO2 Emissions from Fuel Combustion Highlights[M]. France:OECD/IEA,2013.
[2]	LIANG Binglian,DUAN Hongmin,HOU Baolin,et al.Progress in the Catalytic Hydrogenation of Carbon Dioxide to Light Olefins[J]. Chem Ind Eng Prog,2015,34(10):3746-3754(in Chinese). 梁兵连,段洪敏,侯宝林,等. 二氧化碳加氢合成低碳烯烃的研究进展[J]. 化工进展,2015,34(10):3746-3754.
[3]	Iglesias G M,de Vries C,Claeys M,et al. Chemical Energy Storage in Gaseous Hydrocarbons via Iron Fischer Tropsch Synthesis from H2/CO2-Kinetics, Selectivity and Process Considerations[J]. Catal Today,2015,242,Part A(0):184-192.
[4]	Song C. Global Challenges and Strategies for Control, Conversion and Utilization of CO2 for Sustainable Development Involving Energy, Catalysis, Adsorption and Chemical Processing[J]. Catal Today,2006,115(1/2/3/4):2-32.
[5]	Hall W K,Kokes R J,Emmett P H. Mechanism Studies of the Fischer-Tropsch Synthesis. The Addition of Radioactive Methanol, Carbon Dioxide and Gaseous Formaldehyde[J]. J Am Chem Soc,1957,79(12):2983-2989.
[6]	Dwyer D J,Somorjai G A. Hydrogenation of CO and CO2 over Iron Foils:Correlations of Rate, Product Distribution, and Surface Composition[J]. J Catal,1978,52(2):291-301.
[7]	Riedel T,Schaub G,Jun K W,et al.Kinetics of CO2 Hydrogenation on a K-Promoted Fe Catalyst[J]. Ind Eng Chem Res,2001,40(5):1355-1363.
[8]	Martins J,Batail N,Silva S,et al.CO2 Hydrogenation with Shape-Controlled Pd Nanoparticles Embedded in Mesoporous Silica:Elucidating Stability and Selectivity Issues[J]. Catal Commun,2015,58:11-15.
[9]	Lin Q,Liu X Y,Jiang Y,et al.Crystal Phase Effects on the Structure and Performance of Ruthenium Nanoparticles for CO2 Hydrogenation[J]. Catal Sci Technol,2014,4(7):2058-2063.
[10]	Owen R E, O'Byrne J P, Mattia D,et al. Cobalt Catalysts for the Conversion of CO2 to Light Hydrocarbons at Atmospheric Pressure[J]. Chem Commun,2013,49(99):11683-11685.
[11]	Newsome D S. The Water-Gas Shift Reaction[J]. Catal Rev,1980,21(2):275-318.
[12]	Schulz H. Short History and Present Trends of Fischer Tropsch Synthesis[J]. Appl Catal,A,1999,186(1/2):3-12.
[13]	Chew L M,Kangvansura P,Ruland H,et al.Effect of Nitrogen Doping on the Reducibility, Activity and Selectivity of Carbon Nanotube-Supported Iron Catalysts Applied in CO2 Hydrogenation[J]. Appl Catal,A,2014,482:163-170.
[14]	Wang H,Hodgson J,Shrestha T B,et al.Carbon Dioxide Hydrogenation to Aromatic Hydrocarbons by Using an Iron/Iron Oxide Nanocatalyst[J]. Beilstein J Nanotechnol,2014,5:760-769.
[15]	Willauer H D,Ananth R,Olsen M T,et al. Modeling and Kinetic Analysis of CO2 Hydrogenation Using a Mn and K-Promoted Fe Catalyst in a Fixed-Bed Reactor[J]. J CO2 Util,2013,3/4:56-64.
[16]	LIU Yekui,WANG Li,HOU Dong,et al.Study on Thermodynamics of Balanceable Reaction System for Hydrogenation of Carbon Dioxide to Light Alkenes[J]. Chinese J Catal,2004,25(3):210-218(in Chinese). 刘业奎,王黎,侯栋,等. 二氧化碳加氢合成低碳烯烃反应平衡体系热力学研究[J]. 催化学报,2004,25(3):210-218.
[17]	Wang L C,Tahvildar Khazaneh M,Widmann D,et al.TAP Reactor Studies of the Oxidizing Capability of CO2 on a Au/CeO2 Catalyst—A First Step Toward Identifying a Redox Mechanism in the Reverse Water-Gas Shift Reaction[J]. J Catal,2013,302:20-30.
[18]	HE Xiaoxiang,GU Xiongyi,FAN Chen,et al.DFT Study of Reverse Water-Gas Shift Reaction on Fe3O4 Surface[J]. J East China Univ Sci Technol(Nat Sci Ed),2011,37(4):424-429(in Chinese). 何孝祥,顾雄毅,范琛,等. Fe3O4表面逆水煤气反应的DFT研究[J]. 华东理工大学学报(自然科学版),2011,37(4):424-429.
[19]	Saeidi S, Amin N A S, Rahimpour M R. Hydrogenation of CO2 to Value-Added Products—A Review and Potential Future Developments[J]. J CO2 Util,2014,5:66-81.
[20]	Lee S C,Kim J S,Shin W C,et al.Catalyst Deactivation During Hydrogenation of Carbon Dioxide:Effect of Catalyst Position in the Packed Bed Reactor[J]. J Mol Catal A-Chem,2009,301(1/2):98-105.
[21]	Lo J M H,Ziegler T. A First-Principle Study of Chain Propagation Steps in the Fischer-Tropsch Synthesis on Fe(100)[J]. J Phys Chem C,2008,112(35):13681-13691.
[22]	Cheng J,Hu P,Ellis P,et al.Density Functional Theory Study of Iron and Cobalt Carbides for Fischer-Tropsch Synthesis[J]. J Phys Chem C,2009,114(2):1085-1093.
[23]	Niemantsverdriet J W, Van der Kraan A M, Van Dijk W L, et al. Behavior of Metallic Iron Catalysts During Fischer-Tropsch Synthesis Studied with Moessbauer Spectroscopy, X-Ray Diffraction, Carbon Content Determination, and Reaction Kinetic Measurements[J]. J Phys Chem Lett,1980,84(25):3363-3370.
[24]	Riedel T,Schulz H,Schaub G,et al.Fischer-Tropsch on Iron with H2/CO and H2/CO2 as Synthesis Gases:The Episodes of Formation of the Fischer-Tropsch Regime and Construction of the Catalyst[J]. Top Catal,2003,26(1/2/3/4):41-54.
[25]	Bae J W,Park S J,Lee Y J,et al.Effects of Reaction Variables on Fischer Tropsch Synthesis with co-Precipitated K/FeCuAlOx Catalysts[J]. Catal Lett,2011,141(6):799-807.
[26]	Ding M,Yang Y,Wu B,et al.Transformation of Carbonaceous Species and Its Influence on Catalytic Performance for Iron-Based Fischer Tropsch Synthesis Catalyst[J]. J Mol Catal A-Chem,2011,351:165-173.
[27]	De Smit E,Cinquini F,Beale A M,et al.Stability and Reactivity of ε-χ-θ Iron Carbide Catalyst Phases in Fischer-Tropsch Synthesis:Controlling μ(C)[J]. J Am Chem Soc,2010,132(42):14928-14941.
[28]	Mogorosi R P,Fischer N,Claeys M,et al.Strong-Metal-Support Interaction by Molecular Design:Fe-Silicate Interactions in Fischer Tropsch Catalysts[J]. J Catal,2012,289:140-150.
[29]	Yang C,Zhao H,Hou Y,et al.Fe5C2 Nanoparticles:A Facile Bromide-Induced Synthesis and as an Active Phase for Fischer-Tropsch Synthesis[J]. J Am Chem Soc,2012,134(38):15814-15821.
[30]	HUANG Zhier,LI Zhe. Investigation on the Chemical State of Fe Catalysts for Fischer-Tropsch Synthesis[J]. J Fuel Chem Technol,1988,16(4):313-320(in Chinese). 黄止而,李哲. FT合成铁催化剂化学形态的研究[J]. 燃料化学学报,1988,16(4):313-320.
[31]	HOU Wenjuan,WU Baoshan,AN Xia,et al.Effect of K on Slurry Fischer-Tropsch Synthesis over Fe-Cu-K-SiO2 Catalysts[J]. J Fuel Chem Technol,2008,36(2):186-191(in Chinese). 侯文娟,吴宝山,安霞,等. 浆态床F-T合成Fe/Cu/K/SiO2催化剂中K助剂作用的研究[J]. 燃料化学学报,2008,36(2):186-191.
[32]	Liu K,Suo H,Zhang C,et al.An Active Fischer-Tropsch Synthesis FeMo/SiO2 Catalyst Prepared by a Modified Sol-Gel Technique[J]. Catal Commun,2010,12(2):137-141.
[33]	Sai Prasad P S,Bae J W,Jun K-W,et al. Fischer Tropsch Synthesis by Carbon Dioxide Hydrogenation on Fe-based Catalysts[J]. Catal Surv Asia,2008,12(3):170-183.
[34]	ZHAO Le. Progress of Fe-Based Catalysts in Fischer-Tropsch Synthesis[J]. J Zhejiang Univ Technol,2008,36(6):642-647(in Chinese). 赵乐. Fischer-Tropsch合成铁基催化剂研究进展[J]. 浙江工业大学学报,2008,36(6):642-647.
[35]	WANG Guiru,WANG Anjie,LIU Jing,et al.Katalyst and Katalysis[M]. Dalian:Dalian University of Technology Press,2000(in Chinese). 王桂茹,王安杰,刘靖,等. 催化剂与催化作用[M]. 大连:大连理工出版社,2000.
[36]	Hou W,Wu B,An X,et al.Effect of the Ratio of Precipitated SiO2 to Binder SiO2 on Iron-Based Catalysts for Fischer Tropsch Synthesis[J]. Catal Lett,2007,119(3/4):353-360.
[37]	Wan H,Wu B,Xiang H,et al.Fischer Tropsch Synthesis:Influence of Support Incorporation Manner on Metal Dispersion, Metal Support Interaction, and Activities of Iron Catalysts[J]. ACS Catal,2012,2(9):1877-1883.
[38]	Yan S R,Jun K W,Hong J S,et al. Promotion Effect of Fe-Cu Catalyst for the Hydrogenation of CO2 and Application to Slurry Reactor[J]. Appl Catal,A,2000,194/195:63-70.
[39]	Ding F,Zhang A,Liu M,et al.Effect of SiO2-Coating of FeK/Al2O3Catalysts on Their Activity and Selectivity for CO2 Hydrogenatio to Hydrocarbons[J]. RSC Adv,2014,4(17):8930-8938.
[40]	Ding F,Zheng B,Song C,et al.Modification of Fe-K/Al2O3 Catalysts with TEOS for Carbon Dioxide Hydrogenation into Hydrocarbons[J]. Prepr Symp-Am Chem Soc,Div Fuel Chem,2012,57(1):444-445.
[41]	Kou Y,Suo Z H,Niu J Z,et al.Surface Coordinate Geometry of Iron Catalysts-Hydrogenation of CO2 over Fe/ZrO2 Prepared by a Novel Method[J]. Catal Lett,1995,35(3/4):271-277.
[42]	Wang J,You Z,Zhang Q,et al.Synthesis of Lower Olefins by Hydrogenation of Carbon Dioxide over Supported Iron Catalysts[J]. Catal Today,2013,215:186-193.
[43]	Dry M E,Shingles T,Boshoff L J,et al.Heats of Chemisorption on Promoted Iron Surfaces and the Role of Alkali in Fischer-Tropsch Synthesis[J]. J Catal,1969,15(2):190-199.
[44]	XU Longya,WANG Qingxia,LIN Liwu,et al.Study of Fe/Silicalite-2 Catalyst for Producing Light Olefines from CO2 Hydrogenation[J]. J Fuel Chem Technol,1997,25(2):170-174(in Chinese). 徐龙伢,王清遐,林励吾,等. Fe/Silicalite-2催化剂表面CO2加氢反应性能的研究[J]. 燃料化学学报,1997,25(2):170-174.
[45]	XU Longya,WANG Qingxia,LIN Liwu,et al.Study of Fe/Silicalite-2 Catalyst for CO2 Hydrogenation to Light Olefins Ⅲ.Catalytic Performance of K-Fe-MnO/Silicalite-2[J]. Nat Gas Chem Ind,1997,22(4):6-10(in Chinese). 徐龙伢,王清遐,林励吾,等. CO2加氢制低碳烯烃的Fe/Silicalite催化剂研究Ⅲ.K-Fe-MnO/Silicalite-2催化剂性能考察[J]. 天然气化工,1997,22(4):6-10.
[46]	Nam S S,Kim H,Kishan G,et al.Catalytic Conversion of Carbon Dioxide into Hydrocarbons over Iron Supported on Alkali Ion-Exchanged Y-zeolite Catalysts[J]. Appl Catal,A,1999,179(1/2):155-163.
[47]	Huo C F,Wu B S,Gao P,et al.The Mechanism of Potassium Promoter:Enhancing the Stability of Active Surfaces[J]. Angew Chem Int Edit,2011,50(32):7403-7406.
[48]	DING Fanshu. Investigation of Iron-Based Catalysts for C5+ Hydrocarbons Synthesis from CO2 Hydrogenation[D]. Dalian: Dalian University of Technology,2014(in Chinese). 丁凡舒. 二氧化碳加氢合成C5+烃反应中铁基催化剂的性能研究[D]. 大连:大连理工大学,2014.
[49]	Abbott J,Clark N J,Baker B G. Effects of Sodium, Aluminium and Manganese on the Fischer-Tropsch Synthesis over Alumina-Supported Iron Catalysts[J]. App Catal,1986,26:141-153.
[50]	Xu L,Wang Q,Liang D,et al.The Promotions of MnO and K2O to Fe/silicalite-2 Catalyst for the Production of Light Alkenes from CO2 Hydrogenation[J]. Appl Catal,A,1998,173(1):19-25.
[51]	Li T,Yang Y,Zhang C,et al.Effect of Manganese on an Iron-Based Fischer Tropsch Synthesis Catalyst Prepared from Ferrous Sulfate[J]. Fuel,2007,86(7/8):921-928.
[52]	Al-Dossary M,Ismail A A, Fierro J L G,et al. Effect of Mn Loading onto MnFeO Nanocomposites for the CO2 Hydrogenation Reaction[J]. Appl Catal,B,2015,165:651-660.
[53]	Li S,Krishnamoorthy S,Li A,et al.Promoted Iron-Based Catalysts for the Fischer Tropsch Synthesis:Design, Synthesis, Site Densities, and Catalytic Properties[J]. J Catal,2002,206(2):202-217.
[54]	King D L,Faz C. Desulfurization of Tier 2 Gasoline by Divalent Copper-Exchanged Zeolite Y[J]. Appl Catal,A,2006,311:58-65.
[55]	ZHENG Bin,ZHANG Anfeng,LIU Min,et al.Properties of the Nano-Particle Fe-Based Catalyst for the Hydrogenation of Carbon Dioxide to Hydrocarbons[J]. Acta Phys-Chim Sin,2012,28(8):1943-1950(in Chinese). 郑斌,张安峰,刘民,等. 纳米铁基催化剂在CO2加氢制烃中的性能[J]. 物理化学学报,2012,28(8):1943-1950.
[56]	ZHENG Bin. The Synthesis and Properties of the Fe-Based Catalyst for the Hydrogenation of Carbon Dioxide to Hydrocarbons[D]. Dalian:Dalian University of Technology,2012(in Chinese). 郑斌. 二氧化碳加氢制烃类铁基催化剂的制备及性能[D]. 大连:大连理工大学,2012.
[57]	Schulz H,Riedel T,Schaub G. Fischer-Tropsch Principles of co-Hydrogenation on Iron Catalysts[J]. Top Catal,2005,32(3/4):117-124.
[58]	Riedel T,Claeys M,Schulz H,et al.Comparative Study of Fischer-Tropsch Synthesis with H2/CO and H2/CO2Syngas Using Fe- and Co-based Catalysts[J]. Appl Catal,A,1999,186(1/2):201-213.
[59]	Jun K W,Lee S J,Kim H,et al.Support Effects of the Promoted and Unpromoted Iron Catalysts in CO2vHydrogenation[M]. Studies in Surface Science and Catalysis. Elsevier,1998.
[60]	ZHANG Su,WANG Chengyu,PAN Lijin,et al.57Fe Mossbauer Spectroscopy of Supported Fischer-Tropsch Iron Catalystsp[J]. J Fuel Chem Technol,1988,16(4):289-297(in Chinese). 章素,王承玉,潘立金,等. 57Fe穆斯堡尔谱研究费-托合成铁催化剂I.担载型铁催化剂制备条件的考察[J]. 燃料化学学报,1988,16(4):289-297.
[61]	Dorner R W,Hardy D R,Williams F W,et al.K and Mn Doped Iron-Based CO2 Hydrogenation Catalysts:Detection of KAlH4 as Part of the Catalyst's Active Phase[J]. Appl Catal,A,2010,373(1/2):112-121.
[62]	Ding F,Zhang A,Liu M,et al.CO2 Hydrogenation to Hydrocarbons over Iron-based Catalyst:Effects of Physicochemical Properties of Al2O3 Supports[J]. Ind Eng Chem Res,2014,53(45):17563-17569.
[63]	BAI Rongxian,TAN Yisheng,HAN Yizhuo. Hydrogenation of Carbon Dioxide to Isoalkanes over Fe-Zn-Zr/Zeolite Composite Catalysts I. Effects of Zeolites on Catalytic Performance of the Catalysts[J]. Chinese J Catal,2004,25(3):223-226(in Chinese). 白容献,谭猗生,韩怡卓. Fe-Zn-Zr/分子筛复合催化剂上CO2加氢合成异构烷烃I.不同分子筛对催化剂性能的影响[J]. 催化学报,2004,25(3):223-226.
[64]	Hu B,Frueh S,Garces H F,et al. Selective Hydrogenation of CO2 and CO to Useful Light Olefins over Octahedral Molecular Sieve Manganese Oxide Supported Iron Catalysts[J]. Appl Catal,B,2013,132/133:54-61.
[65]	LI Jie. CO2 Hydrogenation to Hydrocarbons over Fe Supported on Ordered Mesoporous Carbons[D]. Dalian:Dalian University of Technology,2014(in Chinese). 李捷. 碳材料负载Fe催化CO2加氢制烃类的研究[D]. 大连:大连理工大学,2014.
[66]	MU Dengyou. Hydrogenation of CO2 to Hydrocarbons over Iron Nanoparticles Confined in Nanoporous Carbons[D]. Dalian:Dalian University of Technology,2014(in Chinese). 慕灯友. Fe@C催化二氧化碳加氢制烃类的研究[D]. 大连:大连理工大学,2014.
[67]	Fujimoto K,Yokota K. Effective Hydrogenation of Carbon-Dioxide with 2-Stage Reaction System[J]. Chem Lett,1991,4:559-562.
[68]	Kim J S,Lee S,Lee S B,et al.Performance of Catalytic Reactors for the Hydrogenation of CO2 to Hydrocarbons[J]. Catal Today,2006,115(1/2/3/4):228-234.
[69]	Kang S H,Bae J W,Cheon J Y,et al.Catalytic Performance on Iron-Based Fischer Tropsch Catalyst in Fixed-Bed and Bubbling Fluidized-Bed Reactor[J]. Appl Catal,B,2011,103(1/2):169-180.
[70]	Satthawong R,Koizumi N,Song C,et al.Light Olefin Synthesis from CO2 Hydrogenation over K-promoted Fe-Co Bimetallic Catalysts[J]. Catal Today,2015,251:34-40.
[71]	Satthawong R,Koizumi N,Song C,et al.Comparative Study on CO2 Hydrogenation to Higher Hydrocarbons over Fe-Based Bimetallic Catalysts[J]. Top Catal,2014,57(6/7/8/9):588-594.
[72]	Satthawong R,Koizumi N,Song C,et al. Bimetallic Fe-Co Catalysts for CO2Hydrogenation to Higher Hydrocarbons[J]. J CO2 Util,2013,3/4:102-106.
[73]	Farsi M,Jahanmiri A. Application of Water Vapor-Permselective Alumina Silica Composite Membrane in Methanol Synthesis Process to Enhance CO2 Hydrogenation and Catalyst Life Time[J]. J Ind Eng Chem,2012,18(3):1088-1095.

Fe基催化剂上二氧化碳加氢制C₂+烃的研究进展

Research Progress in Catalytic Conversion of Carbon Dioxide to C₂+ Hydrocarbons over Fe-Based Catalysts

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