应用化学 ›› 2016, Vol. 33 ›› Issue (2): 123-132.DOI: 10.11944/j.issn.1000-0518.2016.02.150431

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Fe基催化剂上二氧化碳加氢制C2+烃的研究进展

丁凡舒a,聂小娃a,刘民a,宋春山ab,郭新闻a*()   

  1. a大连理工大学化工学院工业催化系,宾州-大连联合能源研究中心,精细化工国家重点实验室 辽宁 大连 116024
    b宾夕法尼亚州立大学能源研究所 美国 16802
  • 收稿日期:2015-12-04 接受日期:2016-01-11 出版日期:2016-02-01 发布日期:2016-02-01
  • 通讯作者: 郭新闻
  • 基金资助:
    国家自然科学基金资助项目(21503029,21503027);中央高校基本科研业务费专项资金资助(DUT15ZD236,DUT15RC(3)027)

Research Progress in Catalytic Conversion of Carbon Dioxide to C2+ Hydrocarbons over Fe-Based Catalysts

DING Fanshua,NIE Xiaowaa,LIU Mina,SONG Chunshanab,GUO Xinwena*()   

  1. aState Key Laboratory of Fine Chemicals,PSU-DUT Joint Center for Energy Research,School of Chemical Engineering,Dalian University of Technology,Dalian,Liaoning 116024,China
    bDepartment of Energy and Mineral Engineering,EMS Energy Institute,PSU-DUT Joint Center for Energy Research,Pennsylvania State University,University Park,16802,USA
  • Received:2015-12-04 Accepted:2016-01-11 Published:2016-02-01 Online:2016-02-01
  • Contact: GUO Xinwen
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.21503029,No.21503027), the Fundamental Research Funds for the Central Universities(No.DUT15ZD236, No.DUT15RC(3)027)

摘要:

将二氧化碳(CO2)催化加氢转化为具有高附加值的烃类化合物,既可减缓大气中CO2浓度的攀升速度,又符合可持续发展战略,对环境和社会均具有重要意义。本文综述了Fe基催化剂上CO2加氢制C2+烃的研究进展,着重介绍了反应路径及机理、催化剂研制及反应器设计,展望了CO2制烃的研究前景。

关键词: 二氧化碳, 催化加氢, Fe基催化剂, 烃类合成

Abstract:

Catalytic conversion of carbon dioxide(CO2) to value-added hydrocarbons is of great environmental and social importance, which can not only reduce CO2 concentration in the atmosphere, but also conform with sustainable development strategy. This paper reviews the progress in catalytic conversion of CO2 to C2+ hydrocarbons over Fe-based catalyst. Reaction pathway and mechanism, catalyst preparation and reactor design are emphatically introduced. In addition, the future of hydrocarbons synthesis via CO2 hydrogenation is also summarized.

Key words: carbon dioxide, hydrogenation, Fe-based catalyst, hydrocarbons synthesis