铁酸铜负极材料的微波合成和电化学性能

doi:10.11944/j.issn.1000-0518.2015.10.150099

摘要/Abstract

摘要：

以十六烷基三甲基溴化铵(CTAB)为模板,硝酸铁和硝酸铜为起始物,采用一步微波法,再经过简单的热处理制备了CuFe₂O₄负极材料,采用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅里叶红外光谱(FT-IR)等测试技术表征材料的结构和形貌。电化学测试表明,在100 mA/g电流密度,0.01~3.0 V电压条件下,材料的首周嵌脱锂比容量分别为1202.2和873.2 mA·h/g,循环50周后,嵌锂比容量仍保持在近650 mA·h/g,显示出优异的电化学性能。

关键词: 微波反应, 电化学性能, 铁酸铜, 锂离子电池

Abstract:

The copper ferrite was prepared by an one-pot microwave assisted sintering process with cetrimonium bromide(CTAB) as the template and copper and ionic nitrates as the reactants. The morphology and microstructure of the products were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), and FT-IR spectroscopy. The as-prepared CuFe₂O₄ exhibits excellent electrochemical performance with the lithiation/delithiation capacity of 1202.2 mA·h/g and 873.2 mA·h/g(at the current 100 mA/g), respectively, and the capacities are maintained over 650 mA·h/g even after 50 charge/discharge cycles.

Key words: microwave synthesis, electrochemical performance, ferrite, lithium ion battery

王锋,胡新良,张鹏,赵双琪,丁瑜. 铁酸铜负极材料的微波合成和电化学性能[J]. 应用化学, 2015, 32(10): 1184-1189.

WANG Feng,HU Xinliang,ZHANG Peng,ZHAO Shuangqi,DING Yu. Microwave Assisted Synthesis and Electrochemical Performance of Copper Ferrite as Anode Material for Lithium-ion Battery[J]. Chinese Journal of Applied Chemistry, 2015, 32(10): 1184-1189.

参考文献

[1]	Rajagopalan B,Oh E Suok,Chung J S. The Effect of Diethylenetriamine on the Solvothermal Reactions of Polyethyleneimine-graphene Oxide/Lithium Titanate Nanocomposites for Lithium Battery Anode[J]. J Power Sources,2015,275:702-711.
[2]	Yi T F,Fang Z K,Deng L,et al.Enhanced Electrochemical Performance of aA Novel Li4Ti5O12 Composite as Anode Material for Lithium-ion Battery in a Broad Voltage Window[J]. Ceram Int,2015,41(2 Part A):2336-2341.
[3]	Goodenough J B. Electrochemical Energy Storage in A Sustainable Modern Society[J]. Energy Environ Sci,2014,7(1):14-18.
[4]	Goodenough J B. Evolution of Strategies for Modern Rechargeable Batteries[J]. Acc Chem Res,2013,46(5):1053-1061.
[5]	Ding Y,Yang Y F,Shao H X. One-Pot Synthesis of NiFe2O4/C Composite as An Anode Material for Lithium-ion Batteries[J]. J Power Sources,2013,244:610-613.
[6]	Poizot P,Laruelle S,Grugeon S,et al.Nano-Sized Transition-metal Oxides as Negative-electrode Materials for Lithium-Ion Batteries[J]. Nature,2000,407(6803):496-499.
[7]	Xu S D,Zhuang Q C,Wang J,et al.New Insight into Vinylethylene Carbonate as A Film Forming Additive to Ethylene Carbonate-Based Electrolytes for Lithium-ion Bbatteries[J]. Int J Electrochem Sci,2013,8(6):8058-8076.
[8]	Ren S H,Zhao X Y,Chen R Y,et al.A Facile Synthesis of Encapsulated CoFe2O4 into Carbon Nanofibres and Its Application as Conversion anodes for Lithium Ion Batteries[J]. J Power Sources,2014,260:205-210.
[9]	Liu L,Sun L M,Liu J,et al.Enhancing the Electrochemical Properties of NiFe2O4 Anode for Lithium Ion Battery Through a Simple Hydrogenation Modification[J]. Int J Hydrogen Energy,2014,39(21):11258-11266.
[10]	Ding Y,Yang Y F,Shao H X. High Capacity ZnFe2O4 Anode Material for Lithium Ion Batteries[J]. Electrochim Acta,2011,56:9433-9438.
[11]	Jiang F,Yang L W,Tian Y,et al.Bi-Component MnO/ZnO Hollow Microspheres eEmbedded in Rreduced Graphene Oxide as Electrode Materials for Enhanced Lithium Storage[J]. Ceram Int,2014,40(3):4297-4304.
[12]	Yao L M,Hou X H,Hu S J,et al.Green Synthesis of Mesoporous ZnFe2O4/C Composite Microspheres as Superior Anode Materials for Lithium-Ion Batteries[J]. J Power Sources,2014,258:305-313.
[13]	Xiong Q Q,Tu J P,Shi S J,et al.Ascorbic Acid-assisted Synthesis of Cobalt Ferrite (CoFe2O4) Hierarchical Flower-like Microspheres with Enhanced Lithium Storage Properties[J]. J Power Sources,2014,256:153-159.
[14]	Peng S J,Li L L,Srinivasan M. Electrospun CuFe2O4 Nanotubes as Anodes for High-performance Lithium-ion Bbatteries[J]. J Energy Chem,2014,23(3):301-307.
[15]	Silva M D P,Silva F C,Sinfronio F S M,et al. The Effect of Cobalt Substitution in Crystal Structure and Vibrational Modes of CuFe2O4 Powders Obtained by Polymeric Precursor method[J]. J Alloys Compd,2014,584:573-580.
[16]	Xi Y P,Zhang Y H,Su Z. Microwave Synthesis of Li3V2(PO4)3/C as Positive-electrode Materials for Rechargeable Lithium Batteries[J]. J Alloys Compd,2015,628:396-400.
[17]	Zhong C,Wang J Z,Wexler D,et al.Microwave Autoclave Synthesized Multi-layer Graphene/Single-walled Carbon Nanotube Composites for Free-standing Lithium-ion Battery Anodes[J]. Carbon,2014,66:637-645.
[18]	Jafta C J,Mathe M K,Manyala N,et al.Microwave-assisted Synthesis of High-voltage Nanostructured LiMn1.5Ni0.5O4 Spinel:Tuning the Mn3+ Content and Electrochemical Performance[J]. ACS Appl Mater Interfaces,2013,5(15):7592-7598.
[19]	YIN Huajie,YANG Jiping. Synthesis of One-dimensional Polyaniline Nanostructures in the Presence of Cathionic Surfactant[J]. Chem J Chinese Univ,2011,32(11):2700-2705(in Chinese). 尹华杰,杨继萍. 阳离子表面活性剂作用下制备一维纳米结构聚苯胺[J]. 高等学校化学学报,2011,32(11):2700-2705.
[20]	Ding Y,Yang Y F,Shao H X. Synthesis and Characterization of Nanostructured CuFe2O4 Anode Material for Lithium Ion Battery[J]. Solid State Ionics,2012,217:27-33.