应用化学 ›› 1996, Vol. 0 ›› Issue (6): 67-68.

• 研究简报 • 上一篇    下一篇

铜卟啉、钒氧卟啉的合成

王煜, 何明威, 王军强, 武靖荣   

  1. 山西大学化学系 太原 030006
  • 收稿日期:1996-02-27 修回日期:1996-08-07 出版日期:1996-12-10 发布日期:1996-12-10
  • 基金资助:
    山西省自然科学基金;山西省留学归国人员基金

Synthesis of Tetraphenylporphine Copper(Ⅱ)and Vanadium(Ⅳ) Oxide

Wang Yu, He Mingwei, Wang Junqiang, Wu Jingrong   

  1. Department of Chemistry, Shanxi University, Taiyuan 030006
  • Received:1996-02-27 Revised:1996-08-07 Published:1996-12-10 Online:1996-12-10

摘要: 合成金属叶琳,通常是先合成叶琳,再将叶琳与金属盐反应,经柱色谱分离后得到目标化合物.本文报道以酚为溶剂,使毗咯、芳香醛和乙酸铜或钒氧乙酞丙酮反应,一步合成铜叶琳、钒氧叶琳的方法.

关键词: 卟啉, 铜卟啉, 钒氧卟啉, 合成

Abstract: Title compounds have been prepared by treating pyrrol with Ar-CHO and copper(Ⅱ) acetate or vanadyl acetylacetonate in one-step route.Three phenols are used as solvents.The experimental results show that 2,4-dichlorophenol is the best one for preparation.

Key words: porphyrin, synthesis, tetraphenylporphine vanadium(Ⅳ) oxide, tetraphenylporphine copper(Ⅱ)