应用化学 ›› 1995, Vol. 0 ›› Issue (2): 16-19.

• 研究论文 • 上一篇    下一篇

钯(Ⅱ)混配物分子内的芳环堆积作用

孙洪良1, 龚钰秋2   

  1. 1. 杭州商学院食品系, 杭州;
    2. 杭州大学化学系, 杭州 310028
  • 收稿日期:1994-09-27 修回日期:1994-12-07 出版日期:1995-04-10 发布日期:1995-04-10
  • 基金资助:
    国家自然科学基金资助课题

Stacking Interaction of Aromatic Rings in Pd(Ⅱ)Mixed-Ligand Complexes

Sun Hongliang1, Gong Yuqiu2   

  1. 1. Department of Food, Hangzhou Institute of Commerce, Hangzhou;
    2. Department of Chemistry, Hangzhou University, Hangzhou 310028
  • Received:1994-09-27 Revised:1994-12-07 Published:1995-04-10 Online:1995-04-10

摘要: 1H NMR法研究了钯(Ⅱ)混配物分子内芳环配体间的堆积作用,结果表明堆积度和参与堆积的芳环大小一致.

关键词: 钯, 混配物, 邻菲咯啉, 联吡啶, 色氨酸, 三磷酸腺苷, 堆积作用

Abstract: The stacking interaction of aromatic rings in the mixed ligand complexes Pd(A)(ATP)n-(A=1,10-phenanthroline,2,2′-bipyridyl,and typtophane,n=2,3)has beenstudied by1H NMR. The results showed that the stacking degree was in accordance with the size of the aromatic rings.

Key words: palladium, mixed complex, phenanthroline, bipyridyl, typtophane, ATP, stacking interaction