中华医学超声杂志

应用化学 ›› 1991, Vol. 0 ›› Issue (6): 14-17.

• 研究论文 • 上一篇    下一篇

四氨基酞菁镍与碘复合物的电导

叶成   

  1. 中国科学院化学研究所, 北京 100080
  • 收稿日期:1990-11-20 修回日期:1991-02-25 出版日期:1991-12-10 发布日期:1991-12-10

THE ELECTRICAL CONDUCTIVITY OF COMPLEXES OF NICKEL TETRAAMINOPHTHALOCYANINE WITH IODINE

Ye Cheng   

  1. Institute of Chemistry, Academia Sinica, Beijing 100080
  • Received:1990-11-20 Revised:1991-02-25 Published:1991-12-10 Online:1991-12-10

PDF

397

被引次数

2

摘要： 报道了用4-硝基邻苯二甲酸制得四硝基酞菁镍再经Na2S还原而得四氨基酞菁镍的合成方法以及产物的表征。四氨基酞菁镍与碘所得到的复合物〔Ni(NH2)4Pc〕Ix的碘含量范围很宽(0.4≤x≤3.77),其电导率为10-2～10-3S/cm,比未掺杂时提高了4～6个量级,而且在空气中很稳定,放置二个月后电导率仍几乎保持不变。

关键词: 四氨基酞菁镍, 碘, 掺杂, 复合物, 电导率

Abstract: In this paper, the synthesis and characterization of nickel tetraaminophthalocyanineNi(NH2)4Pc, and the electrical conductivity of its complexes with iodine are described. Thecomplexes have a wide range of dopant stoichiometries(about 0.4～3.77). The room tempera-ture electrical conductivity of [Ni(NH2)4Pc]Ix compact is 1×10-2 - 1×10-3S/cm, i. e. 4 to 6orders of magnitude higher than that of Ni(NH2)4Pc. The conductivity of the complexesremained almost unchanged after standing in air over two months.

Key words: tetraamino phthalocyanine, iodine, complex, doping, conductrvity

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