铁催化的交叉偶联反应研究进展

doi:10.11944/j.issn.1000-0518.2016.03.150202

摘要/Abstract

摘要：

过渡金属催化的交叉偶联反应具有反应条件温和、操作简单、底物范围广等特点而备受关注,其中,铁在地球上存储丰富、廉价、无毒、对环境友好,商品化的铁盐和含铁化合物种类繁多,是一种可供选择的、绿色的、较为理想的催化剂。近年来铁作为催化剂应用于交叉偶联反应的相关报道逐渐增多,本文根据铁催化剂的不同种类,综述了近年来铁盐催化交叉偶联反应的研究进展,期望为相关的研究工作提供参考。

关键词: 铁催化剂, 交叉偶联反应, 有机合成, 进展

Abstract:

Transition metal-catalyzed cross-coupling reaction which has advantages of simple operation, mild reaction conditions, and broad scope of substrates is one of the most efficient methods for the construction of carbon-carbon bonds. Iron is one of the potential green catalysts as it is one of the most abundant, inexpensive metals on earth, and environmentally friendly. Iron salts and iron-containing compounds are widely commercially available. Recently, more and more studies report the use of iron as catalyst in cross-coupling reactions. This paper reviews the recent advances in iron-catalyzed cross-coupling reactions based on different raw materials and we hope to provide some inspiration for relative research.

Key words: iron catalysts, cross-coupling reaction, organic synthesis, progress

周文俊,邓家英. 铁催化的交叉偶联反应研究进展[J]. 应用化学, 2016, 33(3): 245-266.

ZHOU Wenjun,DENG Jiaying. Research Progress of Iron-catalyzed Cross-coupling Reactions[J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 245-266.

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