应用化学 ›› 1996, Vol. 0 ›› Issue (1): 77-79.

• 研究简报 • 上一篇    下一篇

萘氧基萘并萘醌的合成和光致变色性质

方政1, 杨志范1, 王淑芝1, 徐素贤2, 方天如2, 王佛松2   

  1. 1. 吉林工学院化工系 长春;
    2. 中国科学院长春应用化学研究所 长春 130022
  • 收稿日期:1995-05-26 修回日期:1995-09-08 出版日期:1996-02-10 发布日期:1996-02-10
  • 基金资助:
    中国科学院“八五”重大基础性研究;国家自然科学基金;国家应用光学重点实验室资助

Synthesis and Photochromism of Naphthyloxynaphthacenequinone

Fang Zheng1, Yang Zhifan1, Wang Shuzhi1, Xu Suxian2, Fang Tianru2, Wang Fusong2   

  1. Department of Chemical Engineering, Jilin College of Technology, Changchun)Xu Suxian;Fang Tianru;Wang Fusong(Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1995-05-26 Revised:1995-09-08 Published:1996-02-10 Online:1996-02-10

摘要: 苯氧基萘并萘醌类光致变色材料具有耐疲劳,室温下几乎无热消失反应,以及在紫外光辐照下所形成的信息可通过在氨气氛中处理固定化等特点.

关键词: 萘氧基萘并萘醌, 合成, 光致变色

Abstract: Naphthyloxy-5,12-naphthacenequinone(1) was synthesized by reacting 6-chloro-5,12-naphthacenequinone with 1-naphthol in dry DMF in the presence of potassium carbonate.Its characterization results of 1H NMR and IR were presented.Like phenoxynaphthacenequinones,1 showed normal photochromism in a DMSO solution,exhibiting a characteristic double peak at 454 and 483 nm with isosbestic points at 405,362,342 and 278nm during irradiation with 365 nm UV light.

Key words: naphthyloxynaphthacenequinone, synthesis, photochromism