应用化学 ›› 1996, Vol. 0 ›› Issue (1): 74-76.

• 研究简报 • 上一篇    下一篇

丙烯酸丁酯-苯乙烯-丙烯腈共聚物的结构与力学性能

张会轩1, 韩业1, 张会良1, 冯之榴2   

  1. 1. 吉林工学院化工系 长春 130012;
    2. 中国科学院长春应用化学研究所 长春
  • 收稿日期:1995-03-28 修回日期:1995-09-08 出版日期:1996-02-10 发布日期:1996-02-10
  • 基金资助:
    国家教委资助年轻教师基金;自然科学基金

Structure and Mechanical Properties of Polybutylacrylate/Styrene/Acrylonitrile Copolymer

Zhang Huixuan1, Han Ye1, Zhang Huiliang1, Feng Zhiliu2   

  1. 1. Jilin Institute of Technology, Changchun 130012;
    2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun
  • Received:1995-03-28 Revised:1995-09-08 Published:1996-02-10 Online:1996-02-10

摘要: 丙烯酸丁酯-苯乙烯-丙烯腈共聚物(ASA)是两相结构,聚丙烯酸丁酯(PnBA)以弹性体粒子的形式分散在刚性的苯乙烯一丙烯睛共聚物((SAN)基体中.PnBA链不含双键,耐侯性优越,可用作户外结构材料.

关键词: ASA, 乳液聚合, 粒子, 力学性能

Abstract: Poly(n-butyl acrylate)/styrene/acrylonitrile copolymer(ASA) was synthesized,and its structure-property relationship was studied.It was found that the rubber particle size can be controlled by using the seed emulsion polymerization technique.The impact strength of the ASA depends on its composition and rubber particle size.The optimum particle size is 0.135μm,and the optimum composition of the matrix is 28/72(AN/St).

Key words: poly(n-butyl acrglate)/styrene/acrylonitrile, emulsion polymerization, particle, mechanical property