中华医学超声杂志

应用化学 ›› 1992, Vol. 0 ›› Issue (3): 70-71.

• 研究简报 • 上一篇    下一篇

两亲性卟啉的合成及其L-B膜

文珂, 曹锡章   

  1. 吉林大学化学系, 长春 130023
  • 收稿日期:1991-05-05 修回日期:1991-08-20 出版日期:1992-06-10 发布日期:1992-06-10

SYNTHESES OF AMPHIPHILIC PORPHYRINS AND THEIR LANGMUIR-BLODGETT FILMS

Wen Ke, Cao Xizhang   

  1. Department of Chemistry, JiIin Unversity, Changchun 130023
  • Received:1991-05-05 Revised:1991-08-20 Published:1992-06-10 Online:1992-06-10

PDF

393

被引次数

1

摘要： 早期L-B膜的研制主要着眼于长碳链脂肪酸及其衍生物。近来,由于对膜性能的特殊要求,人们把注意力转向丁二炔[1]、酞菁[2-4]和卟啉[5-7]衍生物。本文用四-(N,N-二甲基氨基苯基)卟啉(TDMAPP)与溴代十六烷反应得到两亲性的含有4个长碳链的澳化四-(4-N,N-二甲基十六烷基氨基苯基)叶琳(TDMHAPPBr),测定了所得L-B膜的电子吸收光谱和固体电子反射光谱。

关键词: 长链卟啉衍生物, 合成, L-B膜

Abstract: Tetra-(N,N-dimethylaminophenyl)porphyrin(TDMAPP) reacts with n-C16H33Br to give quaternary bromides of the amphiphilie porphyrin containing four long aliphatic chains. Its Cu, Zn and Co complexes have been prepared. These porphyrins are capable of forming Langmuir-Blodgett films. The UV-Visible spectra of the L-B films as well as of the solid compounds indicate that the interations between molecules in two cases are different.

Key words: long chain porphyrin derivative, synthesis, L-B film

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