中华医学超声杂志

应用化学 ›› 1992, Vol. 0 ›› Issue (3): 66-69.

• 研究简报 • 上一篇    下一篇

4,4'-二甲氧基查耳酮的合成和晶体结构测定

郑吉民1, 张东1, 申泮文1, 王宏根2, 姚心侃2   

  1. 1. 南开大学化学系, 天津 300071;
    2. 南开大学测试中心, 天津
  • 收稿日期:1991-04-04 修回日期:1991-08-20 出版日期:1992-06-10 发布日期:1992-06-10

CRYSTAL STRUCTURE OF 4,4'-DIMETHOXY CHALCONE

Zheng Jimin1, Zhang Dong1, Sheng Panwen1, Wang Honggen2, Yao Xinkan2   

  1. 1. Department of Chemistry, Nankai University, Tianjin 300071;
    2. The Central Laboratory, Nankai University, Tianjin
  • Received:1991-04-04 Revised:1991-08-20 Published:1992-06-10 Online:1992-06-10

PDF

418

被引次数

1

摘要： 非线性光学晶体材料可用于制作光参量振荡器,升频或降频转换器,从而得到不同波长的激光,扩大了激光的用途,具有重要的理论和实用意义。有机非线性晶体材料以其具有非线性系数大,抗光损伤阈值高等特性更受到人们的青睐,是很有希望的一类倍频材料,各国正在积极研究[1-4]本文报道具有非线性光学特性的4,4'-二甲氧基查耳酮(简称4,4'-DMCh)的合成与分子和晶体结构。

关键词: 4,4'-二甲氧基查耳酮, 晶体结构, 非线性, 光学材料

Abstract: The molecular structure of 4,4'-dimethoxy chalcone single crystal has been determined by X-ray diffraction method. The crystals are orthorhombie with space group P212121 and a=5.268(3), b=30.639(8), c=8.652(4)Å, Z=4, V=1396.56Å3 and Dx=1.276g/cm3.The structure was solved by direct mothods and refined by full metrix least squares method to the final R=0.082 for 991 reflections having I≥3σ(I). Being irradiated by 1064nm Nd3+:YIG laser beam 4,4'-dimethoxy chalcone crystal produces a light of 532nm wavelength.

Key words: dimethoxy chalcone, crystal structure, non-linear optical meterial

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