中华医学超声杂志

应用化学 ›› 1990, Vol. 0 ›› Issue (2): 83-85.

• 研究简报 • 上一篇    下一篇

固体超酸POSA催化醇脱水制烯

傅相锴, 普万里, 夏学清, 陈志华   

  1. 西南师范大学化学系 重庆 630715
  • 收稿日期:1989-07-07 修回日期:1989-09-26 出版日期:1990-04-10 发布日期:1990-04-10
  • 基金资助:
    国家自然科学基金

PREPARATION OF ALKENES FROM ALCOHOLS WITH SOLID SUPER ACID POSA AS CATALYST

Fu Xiangkai, Pu Wanli, Xia Xueqing, Cheng Zhihua   

  1. Department of Chemistry, Southwest-China Teachers University, Chongqing 630715
  • Received:1989-07-07 Revised:1989-09-26 Published:1990-04-10 Online:1990-04-10

PDF

443

被引次数

4 | 1

摘要： 固体超酸由于其优良的催化性能,近年来倍受重视[1,2]。其中以全氟骨架的磺酸树脂Nafion H应用最广。POSA(全氟辛基磺酸,C8F17SO3H)也是一种化学性质稳定、易回收的固体超酸,具有与Nafion H相似的氟碳链磺酸结构。

关键词: 醇, 脱水反应, 烯烃, 超酸, 全氟辛基磺酸

Abstract: Various tipe of alkenes can be simply prepared in high yield from primary, secondaryand tertiary alcohols, using solid superacid POSA(C8F17SO3H, perfluorooctanesulfonicacid)as a catalyst. The catalyst can be reused many times without any loss of its activity.

Key words: alcohol, dehydration, alkene, superacid, perfluorooctanesulfonic acid

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