应用化学 ›› 1988, Vol. 0 ›› Issue (4): 33-36.

• 研究论文 • 上一篇    下一篇

水合氯化锰与冠醚B15C5配合物的研究

蒋海盈1, 吕余刚2, 郭九如3   

  1. 1. 渭南师专 陕西;
    2. 西北大学 西安;
    3. 西安交通大学
  • 收稿日期:1987-03-23 修回日期:1988-01-29 出版日期:1988-08-10 发布日期:1988-08-10

STUDY ON THE COMPLEX OF TETRAHYDRATED MANGANOUS CHLORIDE WITH BENZO-15-CROWN-5 ETHER

Jiang Haiying1, L? Yugang2, Guo Jiuru 3   

  1. 1. Weinan Teachers' College;
    2. Northwest University;
    3. Xi'an Jiaotong University
  • Received:1987-03-23 Revised:1988-01-29 Published:1988-08-10 Online:1988-08-10

摘要: 水合氯化锰和冠醚B15C5可在丙酮和无水乙醇中生成一种淡粉红色固态配合物:3MnCl2·2815C5·4H2O。本文通过元素分析、紫外分光光度分析、气相色谱、紫外光谱、X-射线衍射、差热与热重分析等研究了配合物的组成和性质,测定了它在一些有机溶剂中的溶解度。

关键词: 氯化锰冠醚, 配合物, 性质

Abstract: A solid complex of manganous chloride with benzo-15-crown-5 ether was prepared from absolute alcohol and acetone in a wide range of mole ratio of salt to crown ether. The unique stoichiometric complex formed has been characterized as 3MnCl2·2B15C5·4H2O by elemental analysis, gas chromatography,IR-spectra, UV-spectra, x-ray diffraction, thermo gravimetric and differential thermal analysis.Its solubilities in some organic solvents are reported in the paper.

Key words: Manganous chloride, Crown ether, Complex Prcperty