中华医学超声杂志

应用化学 ›› 1988, Vol. 0 ›› Issue (3): 73-76.

• 研究简报 • 上一篇    下一篇

1,10-菲啰啉-1-氧化物合铈(Ⅳ)配合物的合成

袁景利, 赵国良, 王桂兰, 袁万钟, 王颖   

  1. 大连理工大学化学系
  • 收稿日期:1987-06-15 修回日期:1987-11-16 出版日期:1988-06-10 发布日期:1988-06-10

SYNTHESIS OF CERIUM(IV)COMPLEXES WITH 1,1O-PHENANTHROLINE-1-OXIDE

Yuan Jingli, Zhao Guoliang, Wang Guilan, Yuan Wanzhong, Wang Ying   

  1. Department of Chemistry, Dalian Institute of Technology
  • Received:1987-06-15 Revised:1987-11-16 Published:1988-06-10 Online:1988-06-10

PDF

417

被引次数

12

摘要： 关于稀土与芳乔胺氮氧化物配合物的研究已有大量工作发表,1,10-菲啰啉-1-氧化物(以下简写为O-phenNO)作为一双齿螯合配体能与许多过渡元素形成稳定的配合物,但与稀土化合物仅有其与三价稀土硝酸盐形成配合物的报道.

关键词: 铈, 1,10-菲啰啉-1-氧化物, 配合物

Abstract: Two solid complexes of cerium(Ⅳ) salts with 1,10-Phenanthrolinc-1-oxide(o-phcnNO) were preparcd and characterized, having the composition of Ce(po-henNO) (NO3)3(OH). H2O and Ce(o-PhenNO)4(NO3)(ClO4)3·H2O. IR spectra indicate that the characteristic frequencies assignable to stretching vibration of Ce-O(o-phenNO)bond in these complexes appear in the region of 385-390cm-1Vci-(NO-phenNO) in the region of 255-260cm-1, VN→o and ON-→o of free ligand shift to lower wave numbers upon complexation, The molar conductance and IR spectra data show that NO3-and CIO4- are not coordinated in Ce(oPhenNO)4 (NO3)(CIO4)3·H2O, and all NO3- are coordinated in Ce(c-PhenNO)(NO3)3 (OH), H2O, The UV spectrum of Ce(o-PhenNO)4(NO3)(CIO4)3. H2O is similar to that of the free ligand. The complexes are less soluble in some organic solvents than the ligand.

Key words: Cerium, 1,10-phenanthroline-l-oxide, Complex

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