应用化学

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梯度共聚物研究进展

郑超,黄海瑛*,何天白*   

  1. (中国科学院长春应用化学研究所高分子物理与化学国家重点实验室 长春 130022)
  • 收稿日期:2014-01-06 修回日期:2014-02-19 出版日期:2014-10-09 发布日期:2014-10-09
  • 通讯作者: 何天白,研究员; Tel:0431-85262123; Fax:0431-85262126; E-mail:tbhe@ciac.ac.cn; 研究方向:高分子的软物质行为
  • 基金资助:
    国家自然科学基金资助项目(21074135,21274148,21104079)

Research Progress in Gradient Copolymers

ZHENG Chao, HUANG Haiying*, HE Tianbai*   

  1. (State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of
    Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China)
  • Received:2014-01-06 Revised:2014-02-19 Published:2014-10-09 Online:2014-10-09
  • Contact: He Tianbai

摘要: 梯度共聚物是一类新型的聚合物,其具有与嵌段共聚物相似的丰富性质,但是合成相对简便,更易于大规模生产进而实现产业化,因此备受关注。 本文从梯度共聚物的定义与结构特点、合成与表征、自组装行为、性质及应用等几个方面综述梯度共聚物当前研究现状,展望其发展方向。

关键词: 梯度共聚物, 嵌段共聚物, 自组装, 共聚合

Abstract: Gradient copolymers are a relatively new kind of polymer, which exhibit various properties similar to block copolymers. Due to the economical large scale synthesis allowed by one-pot preparation, gradient copolymers attract significant attentions. This review summaries the definition and structure of gradient copolymers, and current research on their synthesis, characterization, self-assembly behaviors as well as properties and applications.

Key words: gradient copolymers, block copolymers, self-assembly, copolymerization

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