应用化学 ›› 2011, Vol. 28 ›› Issue (08): 855-863.DOI: 10.3724/SP.J.1095.2011.00544

• 综合评述 • 上一篇    下一篇

磺酸盐型Gemini表面活性剂合成研究进展

周明1,2*,赵金洲3,4,刘建勋5,杨燕1   

  1. (1.西南石油大学材料学院 成都  615000;2.塔里木油田公司博士后流动站 库尔勒 841000;
    3.西南石油大学石油工程学院 成都;4.油气藏地质及开发国家重点实验室 西南石油大学 成都;
    5.塔里木油田公司 库尔勒)
  • 收稿日期:2010-09-15 修回日期:2010-10-27 出版日期:2011-08-10 发布日期:2011-08-10
  • 通讯作者: 周明,副教授; Tel:0996-2175447; Fax:028-83037406; E-mail:mr.zhouming@163.com; 研究方向:油田化学及三次采油
  • 基金资助:
    国家自然科学基金(51074133)和中国国博士后科学基金(20090450173)资助项目

Progress in the Synthesis of Sulfonate Gemini Surfactants

ZHOU Ming1,2*, ZHAO Jinzhou3,4, LIU Jianxun5, YANG Yan1   

  1. (1.College of Material Science and Engneering,Southwest Petroleum University,Chengdu 610500;
    2.Tarim Oilfield Postdoctoral Scientific Research Workstation,CNPC,Korla 841000;
    3.College of Petroleum Engineering,Southwest Petroleum University,Chengdu;
    4.State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Engineering & Southwest Petroleum University,Chengdu;
    5.Tarim Oilfield,CNPC,Korla)
  • Received:2010-09-15 Revised:2010-10-27 Published:2011-08-10 Online:2011-08-10

摘要:

磺酸盐型Gimini表面活性剂是一类新型的阴离子表面活性剂,它由联结基团通过化学键将2个或多个单体磺酸盐型表面活性剂连接在一起,由此产生高表界面活性,低临界胶束浓度值,增强了洗涤能力,与传统的阴离子表面活性剂有较好的复配性,奇异的流变特性和良好的抗盐性等一系列的性质,从而具有广泛的应用前景。 本文以原料来源不同分类,综述了一系列磺酸盐型Gemini表面活性剂的合成方法,展望了合成磺酸盐型Gemini表面活性剂的研究方向。

关键词: 磺酸盐, Gemini表面活性剂, 合成, 进展

Abstract:

As one of the new anionic surfactants, sulfonated Gemini surfactants are formed by combining two or more sulfonated surfactants monomer via space groups through covalent bonds. They show potential applications in industry due to their improved properties such as higher surface activity, less critical micelle concentration(cmc), better washing ability, excellent blending performance with conventional anionic surfactants, unique rheologic behavior, good anti-salinity and so on. In this paper, the synthetic methods of a series of sulfonated Gemini surfactants are briefly reviewed according to the origin of the raw materials and the research direction on the synthesis of sulfonated Gemini surfactants is speculated.

Key words: sulfonate, Gemini surfactants, synthesis, progress

中图分类号: