中华医学超声杂志

应用化学 ›› 2010, Vol. 27 ›› Issue (07): 801-805.DOI: 10.3724/SP.J.1095.2010.90669

• 研究论文 • 上一篇    下一篇

离子液体中氧化锰八面体分子筛催化醇的氧化

刘霖1*,马娟娟1,2,付廷明2,李善忠1,2,童志伟1,魏运洋2   

  1. (1.淮海工学院化工学院 连云港 222005；2.南京理工大学化工学院 南京)
  • 收稿日期:2009-10-15 修回日期:2010-01-03 出版日期:2010-07-10 发布日期:2010-07-10
  • 通讯作者: 刘霖，男，博士，讲师; E-mail:spliulin@gmail.com; 研究方向：绿色有机合成，功能材料
  • 基金资助:
    国家自然科学基金资助项目(50873042),淮海工学院自然科学研究项目(Z2009015,Z2009021)

Selective Aerobic Oxidation of Alcohols Catalyzed by Octahedral Molecular Sieves in Ionic Liquids

LIU Lin1*, MA Juan-Juan1,2, FU Ting-Ming2, LI Shan-Zhong1,2, TONG Zhi-Wei1, WEI Yun-Yang2   

  1. (1.School of Chemical Engineering,Huaihai Institute of Technology,Lianyungang, 222005;
    2.School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing)
  • Received:2009-10-15 Revised:2010-01-03 Published:2010-07-10 Online:2010-07-10

PDF

1136

被引次数

3 | 2

摘要：

按文献方法制备了3种八面体MnO6分子筛催化剂K-OMS-2、H-K-OMS-2和Cu-OMS-2，用SEM和XRD测试技术表征了它们的结构和组成。 考察了这3种催化剂对用氧气选择性氧化醇为相应的醛或酮的催化作用，研究了采用不同OMS-2在离子液体[bmim]PF6中反应时间和反应温度对催化反应的影响。 其中H-K-OMS-2对苄醇和烯丙醇氧化的转化率和选择性均超过90%。 催化剂和离子液体可分别用萃取法和减压蒸馏法从反应体系中回收，其中减压蒸馏法回收循环使用效果较好。

关键词: 氧化锰, 八面体分子筛, 醇, 氧化, 离子液体

Abstract:

Three manganese oxide octahedral molecular sieves(OMS2), K-OMS2, H-K-OMS-2 and Cu-OMS-2, were synthesized according to the literature. The structure and composition of the obtained materials were characterized by SEM and XRD. OMS-2 was applied to the selective oxidation of alcohols to generate corresponding aldehydes or ketones. The effects of reaction time and temperature on the catalytic reactions were investigated in ionic liquid [bmim]PF6 when different OMS-2 materials were used as catalysts. The conversion and selectivity of benzylic or allylic alcohols catalyzed by H-K-OMS-2 both reached over 90%. The solvent and catalyst could be recovered from the reaction system by extraction method and vacuum distillation method respectively. The catalytic system recovered by vacuum distillation method showed better recycling performance.

Key words: manganese oxide, octahedral molecular sieve, alcohol, oxidation, ionic liquid

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