应用化学 ›› 2018, Vol. 35 ›› Issue (3): 317-327.DOI: 10.11944/j.issn.1000-0518.2018.03.170379

• 综合评述 • 上一篇    下一篇

MXenes及MXenes复合材料的制备及其在能量存储与转换中的应用

武卫明ab,张长松a,侯绍刚a,杨树斌b*()   

  1. a安阳工学院化学与环境工程学院 河南 安阳 455000
    b北京航空航天大学材料工程学院 空天先进材料与服役教育部重点实验室 北京 100191
  • 接受日期:2017-12-13 出版日期:2018-03-05 发布日期:2018-02-12
  • 通讯作者: 杨树斌
  • 基金资助:
    国家自然科学基金(U1504218,51572007)安阳工学院校博士科研启动基金(BSJ2016006)资助

Synthesis of MXenes and MXenes-containing Composites for Energy Storage and Conversions

WU Weimingab,ZHANG Changsonga,HOU Shaoganga,YANG Shubinb*()   

  1. aSchool of Chemical and Environmental Engineering,Anyang Institute of Technology,Anyang,He'nan 455000,China
    bKey Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education,School of Materials Science and Engineering,Beihang University,Beijing 100191,China
  • Accepted:2017-12-13 Published:2018-03-05 Online:2018-02-12
  • Contact: YANG Shubin
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.U1504218, No.51572007), the Ph.D Initial Scientific Research Fund of Anyang Institute of Technology(No.BSJ2016006).

摘要:

综述了新型过渡金属碳化物和/或氮化物(MXenes)二维纳米材料的合成及其在电化学能源存储与转换中应用的研究进展,这些应用可以分为如下三类:二次电池、超级电容器以及电化学催化。 由于具有二维结构、金属导电性、亲水性表面以及其它优点,MXene二维纳米材料在这些应用领域展示了良好的性能,而且还可以通过嵌入、复合、掺杂、组装等方法来进一步提高其电化学性能。 本文为新型MXenes以及相关材料的开发、合成和应用提供了思路,这种新型MXenes 材料可以用于能量存储与转换、电子和催化等领域。

关键词: MXene, 二维结构, 锂离子电池, 超级电容器

Abstract:

This article reviews recent advances on the synthesis of novel two-dimensional(2D) transitional metal carbides and/or nitrides(MXenes), and their applications for electrochemical energy storage and conversions. These applications could be divided into three main categories: rechargeable batteries, supercapacitors, and electro-catalysis. In these applied aspects, 2D MXenes exhibit promising capabilities due to the unique 2D structure, metallic conductivity, hydrophilic surfaces and other merits. Their electrochemical properties could be enhanced further by strategies of intercalating, compositing, doping, assembling and so on. This provides an avenue to exploit, synthesize and apply novel type of MXenes and MXene-based materials for broad fields, such as electrochemical energy storage and conversions, electronics, and catalysts.

Key words: MXene, 2D structure, lithium ion batteries, supercapacitors