碱和盐对十二烷基硫酸钠/正戊醇-环己烷-水拟三元体系相图影响

doi:10.11944/j.issn.1000-0518.2017.07.160445

摘要/Abstract

摘要：

拟三元相图的研究可为获得制备纳米材料的微乳液提供理论依据。本文首先通过实验绘制了45 ℃下十二烷基硫酸钠(SDS)/正戊醇-环己烷-水溶液体系的拟三元相图,并用电导法进行了验证,说明电导的测定结果与相图吻合的很好。其次,绘制了45 ℃及65 ℃下,SDS/正戊醇-环己烷-水、SDS/正戊醇-环己烷-硝酸锌水溶液和SDS/正戊醇-环己烷-氢氧化钠水溶液体系的拟三元相图并对6个相图进行了比较,研究了碱(NaOH)和盐(Zn(NO₃)₂)对SDS/正戊醇-环己烷-水拟三元体系相图影响。结果表明,硝酸锌及碱的加入使SDS/正戊醇-环己烷-水拟三元相图水包油(O/W)和油包水(W/O)区域明显的缩小。 45 ℃时,SDS/正戊醇-环己烷-氢氧化钠水溶液体系的拟三元相图中的O/W区域甚至消失;65 ℃时, O/W和W/O区域均存在,且3个相图的W/O和O/W区域有重叠区。在此基础上,确定了制备纳米ZnO的微乳液的条件,即SDS/正戊醇-环己烷-硝酸锌水溶液和SDS/正戊醇-环己烷-氢氧化钠水溶液体系的拟三元相图中W/O区域的重叠区(各相图中的Ⅱ区)。制备的纳米氧化锌为多晶结构,平均粒径为80 nm。

关键词: 拟三元相图, 纳米粒子, 油包水微乳液, 碱, 盐

Abstract:

An important application of psudo ternary phase diagrams is to obtain microemulsion for nano material preparation. Therefore, psudo ternary phase diagrams of sodium dodecyl sulfate(SDS)/n-C₅H₁₁OH-cyclohexane-water at 45 ℃ and its conductivity were studied. Pseudo ternary phase diagrams agree well with conductivity measurement. Then psudo ternary phase diagrams of SDS/n-C₅H₁₁OH-cyclohexane-water, SDS/n-C₅H₁₁OH-cyclohexane-Zn(NO₃)₂, SDS/n-C₅H₁₁OH-cyclohexane-NaOH at 45 ℃ and 65 ℃ were measured and compared. The influence of alkali NaOH and salt Zn(NO₃)₂ on peudo ternary phase diagrams was discussed. The result shows that oil-in-water(O/W) and water-in-oil(W/O) microemulsion areas are smaller after (Zn(NO₃)₂) or (NaOH) was added into SDS/n-C₅H₁₁OH-cyclohexane-water system. The O/W microemulsion areas disappeared in SDS/n-C₅H₁₁OH-cyclohexane-NaOH peudo ternary phase diagrams at 45 ℃. There are still 5 areas in psudo ternary phase diagrams and smaller O/W and W/O microemulsion areas after NaOH or Zn(NO₃)₂ was added in SDS/cyclohexane-water system at 65 ℃. These study results were applied in the preparation nano ZnO particle in microemulsion system. Tansimission electron microscopy and X-ray diffraction studies show that the sample preparaed by the guidance of psudo ternary phase diagrams is nano ZnO particle.

Key words: peudo ternary phase diagrams, nanoparticle, water-in-oil microemulsion, alkali, salt

朱艳, 原光, 原帅, 陈少杰, 姚卫琴, 田龙昭, 秦帆, 刘林梅. 碱和盐对十二烷基硫酸钠/正戊醇-环己烷-水拟三元体系相图影响[J]. 应用化学, 2017, 34(7): 833-838.

ZHU Yan, YUAN Guang, YUAN Shuai, CHEN Shaojie, YAO Weiqin, TIAN Longzhao, QIN Fan, LIU Linmei. Influence of Alkali and Salt on Phase Diagram of Sodium Dodecyl Sulfate/n-Pentanol- Cyclohexane-Water Pseudo Ternary Systems[J]. Chinese Journal of Applied Chemistry, 2017, 34(7): 833-838.

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