Application of High-Precision X-Ray Fluorescence Spectroscopy in the Determination of Cu Ions in Copper Containing Sludge

doi:10.19894/j.issn.1000-0518.240070

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (9): 1307-1314.DOI: 10.19894/j.issn.1000-0518.240070

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Application of High-Precision X-Ray Fluorescence Spectroscopy in the Determination of Cu Ions in Copper Containing Sludge

Ying WANG¹^,²(), Rui-Ping WU¹

^1.Department of Chemical and Material Engineering，Lyuliang University，Lvliang 033000，China
^2.Institute of New Carbon-based Materials and Zero-carbon and Negative-carbon Technology，Lyuliang University，Lvliang 033000，China

Received:2024-03-06 Accepted:2024-08-06 Published:2024-09-01 Online:2024-10-09
Contact: Ying WANG
About author:wyymtd@163.com
Supported by:
Research Program for Key Issues in Air Pollution Control in Lvliang City(LLXYHX202309-13)

Abstract

Abstract:

Measuring the mass concentration and distribution of copper ions in copper containing sludge is a necessary step for recovering copper ions. Therefore， it is very important to study the application of high-precision X-ray fluorescence spectroscopy in the determination of Cu ions in copper containing sludge. Due to the interference caused by the overlapping wavelength of X-rays generated by other elements and copper during the measurement process， the final Cu ion measurement results are biased. Therefore， high-precision X-ray fluorescence spectroscopy was used to study the determination of Cu ions in copper containing sludge in the Shandonggou copper mine area in Zhongtiao， Shanxi， in order to solve the problem of measurement result deviation caused by interferen PHA range of 100~300， use high-precision X-ray fluorescence spectroscopy to determine the mass concentration of Cu ions in the molten sheet and correct it. The results showed that based on X-ray fluorescence spectroscopy， the range of Cu ion mass concentration in 36 sampling point samples was measured， from the lowest 8.78 mg/kg to the highest 334.98 mg/kg. Through the drawn Cu ion mass concentration distribution characteristic map， it was found that the Cu ion mass concentration was highest in the southeast and gradually decreased towards the northwest， indicating a wide variation in Cu ion mass concentration in copper containing sludge.

Key words: High-precision X-ray fluorescence spectroscopy, Copper containing sludge, Cu ion determination

CLC Number:

O657

Ying WANG, Rui-Ping WU. Application of High-Precision X-Ray Fluorescence Spectroscopy in the Determination of Cu Ions in Copper Containing Sludge[J]. Chinese Journal of Applied Chemistry, 2024, 41(9): 1307-1314.

Figures/Tables 5

References 21

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Num	Concentration of Cu²⁺ Actual sample/（mg·kg^-1）	Result/（mg·kg^-1） ^a	Result/（mg·kg^-1） ^b	Result/（mg·kg^-1） ^c
1	9.73	9.68	9.62	9.63
2	11.74	11.74	11.52	11.51
3	16.18	16.10	16.04	16.05
4	28.51	28.51	28.40	28.38
5	10.26	10.20	10.15	10.16

Num	Concentration of Cu²⁺ Actual sample/（mg·kg^-1）	Result/（mg·kg^-1） ^a	Result/（mg·kg^-1） ^b	Result/（mg·kg^-1） ^c
1	9.73	9.68	9.62	9.63
2	11.74	11.74	11.52	11.51
3	16.18	16.10	16.04	16.05
4	28.51	28.51	28.40	28.38
5	10.26	10.20	10.15	10.16

Copper containing sludge samples	C（Cu²⁺）/（mg·kg^-1）	Copper containing sludge samples	C（Cu²⁺）/（mg·kg^-1）
1	10.65	19	287.65
2	12.92	20	308.46
3	36.98	21	126.48
4	8.78	22	343.63
5	10.47	23	458.62
6	38.63	24	441.84
7	35.87	25	324.69
8	16.33	26	307.98
9	27.85	27	423.67
10	52.64	28	380.14
11	68.55	29	517.64
12	236.24	30	482.17
13	87.12	31	316.32
14	98.62	32	324.88
15	105.66	33	428.32
16	174.12	34	472.33
17	304.63	35	456.21
18	334.98	36	520.18

Copper containing sludge samples	C（Cu²⁺）/（mg·kg^-1）	Copper containing sludge samples	C（Cu²⁺）/（mg·kg^-1）
1	10.65	19	287.65
2	12.92	20	308.46
3	36.98	21	126.48
4	8.78	22	343.63
5	10.47	23	458.62
6	38.63	24	441.84
7	35.87	25	324.69
8	16.33	26	307.98
9	27.85	27	423.67
10	52.64	28	380.14
11	68.55	29	517.64
12	236.24	30	482.17
13	87.12	31	316.32
14	98.62	32	324.88
15	105.66	33	428.32
16	174.12	34	472.33
17	304.63	35	456.21
18	334.98	36	520.18

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Application of High-Precision X-Ray Fluorescence Spectroscopy in the Determination of Cu Ions in Copper Containing Sludge

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