Preparation and Anti-Ultraviolet Performance of Polydopamine Coated Zn-Ti Layered Double Hydroxide with Application in Sunscreen and Daily Chemical Industry

doi:10.19894/j.issn.1000-0518.240053

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (9): 1297-1306.DOI: 10.19894/j.issn.1000-0518.240053

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Preparation and Anti-Ultraviolet Performance of Polydopamine Coated Zn-Ti Layered Double Hydroxide with Application in Sunscreen and Daily Chemical Industry

Zheng ZHANG, Yang WANG, Ting LI, Wei-Fu DONG()

Key Laboratory of Synthetic and Biological Colloids，Ministry of Education，School of Chemical and Material Engineering，Jiangnan University，Wuxi 214122，China

Received:2024-02-20 Accepted:2024-07-12 Published:2024-09-01 Online:2024-10-09
Contact: Wei-Fu DONG
About author:wfdong@jiangnan.edu.cn
Supported by:
the National Natural Science Foundation of China(52273089)

Abstract

Abstract:

Traditional sunscreens， especially organic ultraviolet （UV） absorbers such as benzophenone， have strong photoactivity and skin permeability， which may cause some human injuries and even cancer. Therefore， it is of great practical significance to develop efficient and safe new sunscreen. With anhydrous zinc acetate （Zn（Ac）₂）， titanium tetrachloride （TiCl₄） and dopamine hydrochloride as raw materials and ethanol/water solution as solvent， polydopamine （PDA） coated Zn-Ti layered double hydroxide （P@ZTL） compounded particles were synthesized through a hydrothermal method. Afterwards， sunscreen samples were prepared with them as the only UV-blocking component. The chemical structure， composition and micro-morphology， along withUV absorbance， free radical scavenging and cytotoxicity performance of P@ZTL were studied. Indispensably， the UV-blocking properties of the sunscreen samples were tested. The results showed that the structure of P@ZTL was 1~5 μm PDA coated ZTL compounded particles， with a specific surface area of 145.916 m²/g. The particles had a typical mesoporous structure with a porosity of 0.154 cm³/g. The compounded particles had great UV absorption and reactive oxygen species （ROS） scavenging abilities， along with no cytotoxicity. The sunscreen with P@ZTL had excellent UV protecting performance， which could preserve fibroblasts from direct UV irradiation. The sun protection index （SPF） values of sunscreen samples added with 10% and 15% P@ZTL reached 47.3±2.3 and 75.1±3.1， respectively， which could fully meet the daily use. Therefore， the synthesized P@ZTL sunscreen has a great application prospect in cosmetics.

Key words: Zn-Ti layered double hydroxide, Polydopamine, UV blocking, Sunscreen, ROS scavenging

CLC Number:

O644.1

Zheng ZHANG, Yang WANG, Ting LI, Wei-Fu DONG. Preparation and Anti-Ultraviolet Performance of Polydopamine Coated Zn-Ti Layered Double Hydroxide with Application in Sunscreen and Daily Chemical Industry[J]. Chinese Journal of Applied Chemistry, 2024, 41(9): 1297-1306.

Figures/Tables 9

Table 1 Formulation of sunscreen

Name	Source	w/%
ZTL or P@ZTL	Synthesized in this work	10 or 15
Water	Prepared in the lab	55 or 50
CARBOMER 940	Lubrizol	0.3
Butanediol	OQ Chemicals GmbH	5
Propanediol	Dow Chemical （SHANGHAI） Co.， Ltd.	5
Xanthan gum	Usolf	0.2
Cetearyl alcohol	Usolf	6
Dimethicone	Usolf	6
Benzoic acid， C_12-15-alkyl esters	Usolf	10
Phenoxyethanol	Shanghai Macklin Biochemical Technology Co.， Ltd	0.5
Arginine	Usolf	2

Fig.1 （A） FT-IR spectra and （B） XRD patterns of ZTL and P@ZTL； The XPS analysis of P@ZTL showing （C） full survey scan，（D） Zn2p，（E） Ti2p and （F） O1s spectra

Fig.2 SEM images of ZTL （A），P@ZTL100 （B），P@ZTL30 （C） and P@ZTL10 （D） samples

Fig.3 The （A） SEM and （B-F） EDS mapping images of P@ZTL

Fig.4 （A） Nitrogen absorption-desorption isotherms and （B） Barret-Joyner-Halenda pore size distributions of ZTL；（C） Nitrogen absorption-desorption isotherms and （D） BJH pore size distributions of P@ZTL

Fig.5 （A） The UV absorbance curves of ZTL and P@ZTL powders；（B） The schematic diagram of NIH3T3 cells exposed to the UV light；（C） FDA/PI double staining of NIH3T3 cells after UV irradiation for 20 min with or without the protection of different sunscreen creams

Table 2 The tested SPF values of some commercial sunscreen （CS） samples and the sunscreen samples with ZTL or P@ZTL

Sunscreen samples	Tested SPF values
10% ZTL	11.6±1.1
15% ZTL	15.1±1.4
10% P@ZTL₃₀	47.3±2.3
15% P@ZTL₃₀	75.1±3.1
ALD （declared SPF 30）	34.8±2.1
YLSE （declared SPF 30+）	36.3±5.0
QMS （declared SPF 50）	55.9±3.8
YZM （declared SPF 50+）	63.7±2.1

Fig.6 Electron paramagnetic resonance spectra of （A） DMPO-·OH and （B） TEMP-1O2 before and after UV radiation for 5 min for ZTL and P@ZTL， respectively

Fig.7 （A） The NIH3T3 fibroblast cell proliferation after cultured with different samples for 24 and 48 h. Data are shown as mean±SD. （n=5）； The FDA/PI double-stained fluorescent images of NIH3T3 cells survival with （B） the blank，（C） ZTL，（D） P@ZTL samples after 48 h

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Preparation and Anti-Ultraviolet Performance of Polydopamine Coated Zn-Ti Layered Double Hydroxide with Application in Sunscreen and Daily Chemical Industry

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