Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater

doi:10.19894/j.issn.1000-0518.220335

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (5): 681-696.DOI: 10.19894/j.issn.1000-0518.220335

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Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater

Xue-Bo LEI¹, Hui-Jing LIU¹(), He-Yu DING¹, Guo-Dong SHEN¹, Run-Jun SUN¹^,²

^1.School of Textile Science and Engineering，Xi′an Polytechnic University，Xi′an 710048，China
^2.State Key Laboratory of Intelligent Textile Material and Products，Xi′an Polytechnic University，Xi′an 710048，China

Received:2022-10-13 Accepted:2023-03-09 Published:2023-05-01 Online:2023-05-26
Contact: Hui-Jing LIU
About author:liuhuijing@xpu.edu.cn
Supported by:
the National Natural Science Foundation of China(21802106);the China Postdoctoral Science Foundation(2019M653860XB);the Natural Science Basic Research Program of Shaanxi(2021JQ-681)

Abstract

Abstract:

Dye-containing wastewater， largely discharged from the textile or printing industries， is one of the well-known sources of water pollution， posing great threats to both human health and the living environment. Although several water treatment technologies including physisorption， chemical oxidation， and biodegradation have been developed， most of them are costly and may produce some by-products with unknown toxicities. Therefore， it is highly desirable to develop economic and effective treatment technologies to reduce water resource consumption and protect the environment. Photocatalysis is a method in that highly reactive transitory species such as superoxide or hydroxyl radicals can be generated by reacting oxygen or water with photocatalysts upon irradiation of light， then degrading the organic dyes. Because the whole photocatalysis process has no chemical input and no secondary pollutants， it is considered to be an environmentally friendly， energy-efficient， and sustainable technique. In this paper， we have reviewed different kinds of photocatalyst systems developed in recent ten years for the degradation of organic pollutes， which cover inorganic semiconductors， metal-organic frameworks， organic small molecules， and conjugated porous polymers. Based on the large surface area and high photocatalytic activity， the conjugated porous polymers can simultaneously adsorb and photodegrade organic dyes under visible light， exhibiting stronger developmental potential compared with other photocatalytic materials.

Key words: Printing and dyeing wastewater, Photocatalysis, Inorganic semiconductor materials, Metal-organic frameworks, Porous conjugated polymers

CLC Number:

O643

Xue-Bo LEI, Hui-Jing LIU, He-Yu DING, Guo-Dong SHEN, Run-Jun SUN. Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater[J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 681-696.

Figures/Tables 17

References 88

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Catalysts	Light/nm	Mass/mg	Substrates	Concentration	Time/min	Efficiency/%	Ref.
V₂O₅ NWs	-	2.5	RhB	20 mL（23 mg/L）	70	95	［16］
Sn-TEG	254	20	MB	50 mL（10 mg/L）	15	96.6	［24］
Ag@Zn₂TiO₄	200～700	0.4	RhB	40 mL（5 mg/L）	90	97	［60］
CZTS	400～700	25	RhB	50 mL（194 mg/L）	4	100	［61］
Se_2.6%-ZnS	200～700	40	Trypan blue	50 mL（15 mg/L）	180	99	［62］
CST-T	365	100	RhB	50 mL（100 mg/L）	200	75	［63］
Bi₄Ti₃O₁₂/BiOBr	400～700	20	Acid blue 83	100 mL（5 mg/L）	180	100	［64］
0.9BiOBr/0.1Ba_0.8Sr_0.2TiO₃	200～400	20	Direct blue 5B	200 mL（20 mg/L）	180	98	［65］

Catalysts	Light/nm	Mass/mg	Substrates	Concentration	Time/min	Efficiency/%	Ref.
V₂O₅ NWs	-	2.5	RhB	20 mL（23 mg/L）	70	95	［16］
Sn-TEG	254	20	MB	50 mL（10 mg/L）	15	96.6	［24］
Ag@Zn₂TiO₄	200～700	0.4	RhB	40 mL（5 mg/L）	90	97	［60］
CZTS	400～700	25	RhB	50 mL（194 mg/L）	4	100	［61］
Se_2.6%-ZnS	200～700	40	Trypan blue	50 mL（15 mg/L）	180	99	［62］
CST-T	365	100	RhB	50 mL（100 mg/L）	200	75	［63］
Bi₄Ti₃O₁₂/BiOBr	400～700	20	Acid blue 83	100 mL（5 mg/L）	180	100	［64］
0.9BiOBr/0.1Ba_0.8Sr_0.2TiO₃	200～400	20	Direct blue 5B	200 mL（20 mg/L）	180	98	［65］

Catalysts	Wave length/nm	Mass/mg	Substrates	Concentration	Time	Efficiency/%	Ref.
Ce-MOF-589	-	1	MB	40 mg/L（1 mL）	15 min	96	［13］
^PTBMOF	200~800	20	Tartrazine	23 mg/L	24 h	98.9	［66］
CuTz-1	200~800	12	RhB	12 mg/L（20 mL）	22 min	100	［68］
BMOF	200~800	10	MB	3.7 mg/L	90 min	57	［69］

Catalysts	Wave length/nm	Mass/mg	Substrates	Concentration	Time	Efficiency/%	Ref.
Ce-MOF-589	-	1	MB	40 mg/L（1 mL）	15 min	96	［13］
^PTBMOF	200~800	20	Tartrazine	23 mg/L	24 h	98.9	［66］
CuTz-1	200~800	12	RhB	12 mg/L（20 mL）	22 min	100	［68］
BMOF	200~800	10	MB	3.7 mg/L	90 min	57	［69］

Catalysts	Light	Mass/mg	Substrate	Concentration	Time	Efficiency/%	Ref.
TM-2-d	High pressure mercury lamp（500 W）	1 000	MB	300 mg/L（2 000 mL）	12 h	100	［15］
ANP	300～700 nm	50	MB	37 mg/L（20 mL）	200 min	97	［74］
PCBM	300～700 nm	1.2	RhB	6.7 mg/mL（3mL）	30 min	90	［75］

Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater

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Catalysts	Wavelength	Mass/mg	Substrates	Concentration	Time	Efficiency/%	Ref.
10%TrCMP/TiO₂	300～700 nm	26.25	MB	8.1 mg/L（35 mL）	20 min	92.5	［31］
Nano PDPB	λ＞450 nm	3.5	MO	3.27 mg/L（3.5 mL）	240 min	75	［78］
P-FL-BT-3	300～700 nm	1	RhB	10 mg/mL（10 mL）	70 min	90	［79］
POPs-2	λ＞420 nm	10	CR	10 mg/L（10 mL）	90 min	85	［80］
PTEB	λ＞420 nm	0.3	RhB	20 mg/L	50 min	100	［81］
Py-BF-CMP	λ＞450 nm	4	RhB	25 mg/L（20 mL）	30 min	81	［82］
TZCP-3	λ＞420 nm	5	RhB	10 mg/L（100 mL）	30 min	100	［83］
TA-BGY	200～1300 nm	20	MB	30 mg/L（20 mL）	8 h	80	［84］
TpSD	300～700 nm	3	Rh6G	10 mg/L（30 mL）	60 min	99.2	［85］
sp²c-CTP-4	300～700 nm	3	MB	40 mg/L（5 mL）	90 min	98	［86］
network-3	300～700 nm	14.2	MB	4 mg/L	90 min	95	［87］
CTF-NWU-1	λ＞420 nm	10	RhB	20 mg/L（50 mL）	30 min	99	［88］

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