Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater

doi:10.19894/j.issn.1000-0518.220335

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (5): 681-696.DOI: 10.19894/j.issn.1000-0518.220335

• Review • Previous Articles Next Articles

Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater

Xue-Bo LEI¹, Hui-Jing LIU¹(), He-Yu DING¹, Guo-Dong SHEN¹, Run-Jun SUN¹^,²

^1.School of Textile Science and Engineering，Xi′an Polytechnic University，Xi′an 710048，China
^2.State Key Laboratory of Intelligent Textile Material and Products，Xi′an Polytechnic University，Xi′an 710048，China

Received:2022-10-13 Accepted:2023-03-09 Published:2023-05-01 Online:2023-05-26
Contact: Hui-Jing LIU
About author:liuhuijing@xpu.edu.cn
Supported by:
the National Natural Science Foundation of China(21802106);the China Postdoctoral Science Foundation(2019M653860XB);the Natural Science Basic Research Program of Shaanxi(2021JQ-681)

Abstract

Abstract:

Dye-containing wastewater， largely discharged from the textile or printing industries， is one of the well-known sources of water pollution， posing great threats to both human health and the living environment. Although several water treatment technologies including physisorption， chemical oxidation， and biodegradation have been developed， most of them are costly and may produce some by-products with unknown toxicities. Therefore， it is highly desirable to develop economic and effective treatment technologies to reduce water resource consumption and protect the environment. Photocatalysis is a method in that highly reactive transitory species such as superoxide or hydroxyl radicals can be generated by reacting oxygen or water with photocatalysts upon irradiation of light， then degrading the organic dyes. Because the whole photocatalysis process has no chemical input and no secondary pollutants， it is considered to be an environmentally friendly， energy-efficient， and sustainable technique. In this paper， we have reviewed different kinds of photocatalyst systems developed in recent ten years for the degradation of organic pollutes， which cover inorganic semiconductors， metal-organic frameworks， organic small molecules， and conjugated porous polymers. Based on the large surface area and high photocatalytic activity， the conjugated porous polymers can simultaneously adsorb and photodegrade organic dyes under visible light， exhibiting stronger developmental potential compared with other photocatalytic materials.

Key words: Printing and dyeing wastewater, Photocatalysis, Inorganic semiconductor materials, Metal-organic frameworks, Porous conjugated polymers

CLC Number:

O643

Xue-Bo LEI, Hui-Jing LIU, He-Yu DING, Guo-Dong SHEN, Run-Jun SUN. Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater[J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 681-696.

Figures/Tables 17

References 88

1	LIU H， YANG S， NI Y. Comparison of dye behavior from aspen HYP： dyes added in the HYP manufacturing process versus dyes added at the papermaking wet end［J］. J Wood Chem Technol， 2010， 30（2）： 118-128.
2	FENG Q Y， GAO B Y， YUE Q Y， et al. Flocculation performance of papermaking sludge-based flocculants in different dye wastewater treatment： comparison with commercial lignin and coagulants［J］. Chemosphere， 2021， 262： 128416.
3	LI Q， DONG K， TU Y， et al. Current situation and problems of MBR treatment process in dye wastewater［C］. IOP Conf Ser： Earth Environ Sci， 2019， 358： 022043.
4	BELDEAN-GALEA M S， COPACIU F M， COMAN M V. Chromatographic analysis of textile dyes［J］. J AOAC Int， 2018， 101（5）： 1353-1370.
5	UDDIN F. Environmental hazard in textile dyeing wastewater from local textile industry［J］. Cellulose， 2021， 28（17）： 10715-10739.
6	MOYO S， MAKHANYA B P， ZWANE P E. Use of bacterial isolates in the treatment of textile dye wastewater： a review［J］. Heliyon， 2022， 8（6）： e09632.
7	RAMAN C D， KANMANI S. Textile dye degradation using nano zero valent iron： a review［J］. J Environ Manage， 2016， 177： 341-355.
8	LEE M， NAM K T， KIM J， et al. Evaluation of ocular irritancy of coal-tar dyes used in cosmetics employing reconstructed human cornea-like epithelium and short time exposure tests［J］. Food Chem Toxicol，2017， 108： 236-243.
9	WARGALA E， SLAWSKA M， ZALEWSKA A， et al. Health effects of dyes， minerals， and vitamins used in cosmetics［J］. Women， 2021， 1： 223-237.
10	PASDARAN A， AZARPIRA N， HEIDARI R， et al. Effects of some cosmetic dyes and pigments on the proliferation of human foreskin fibroblasts and cellular oxidative stress； potential cytotoxicity of chlorophyllin and indigo carmine on fibroblasts［J］. J Cosmet Dermatol， 2022， 21（9）： 3979-3985.
11	TU Y M， SHAO G Y， ZHANG W J， et al.The degradation of printing and dyeing wastewater by manganese-based catalysts［J］. Sci Total Environ， 2022， 828： 154390.
12	LIU Z C， KHAN T A， ISLAM M A， et al. A review on the treatment of dyes in printing and dyeing wastewater by plant biomass carbon［J］. Bioresour Technol，2022， 354： 127168.
13	DANG G H， TRAN Y B N， PHAM T V， et al. A cerium-containing metal-organic framework： synthesis and heterogeneous catalytic activity toward Fenton-like reactions［J］. ChemPlusChem，2019， 84（8）： 1046-1051.
14	ZHANG X， WANG J， DONG X X， et al. Functionalized metal-organic frameworks for photocatalytic degradation of organic pollutants in environment［J］. Chemosphere， 2020， 242： 125144.
15	ZHAO T C， LIU R， LU J P， et al. Photocatalytic degradation of methylene blue solution by diphenylanthrazoline compounds［J］. J Phys Org Chem， 2017， 30（12）： e3712.
16	ROY A， PRADHAN M， RAY C， et al. Facile synthesis of pyridine intercalated ultra-long V₂O₅ nanowire from commercial V₂O₅： catalytic applications in selective dye degradation［J］. CrystEngComm， 2014， 16（33）： 7738-7744.
17	WU W B， MAO D， XU S D， et al. Polymerization-enhanced photosensitization［J］. Chem，2018， 4（8）： 1937-1951.
18	ZHANG S T， WANG Z M， YAO L Z， et al. Preparation of perylene diimide modified AgCl photocatalyst and its photocatalytic performance for degrading various organic pollutants under visible light［J］. Colloids Surfaces A， 2022， 652： 129902.
19	QU X， LIN J B， QIANG W， et al.Self-doped defect-mediated TiO₂ with disordered surface for high-efficiency photodegradation of various pollutants［J］. Chemosphere， 2022， 308： 136239.
20	ELUMALAI N， PRABHU S， SELVARAJ M， et al. Enhanced photocatalytic activity of ZnO hexagonal tube/r-GO composite on degradation of organic aqueous pollutant and study of charge transport properties［J］. Chemosphere， 2022， 291： 132782.
21	DAI C H， LIU B. Conjugated polymers for visible-light-driven photocatalysis［J］. Energy Environ Sci， 2020， 13（1）： 24-52.
22	XU X Y， ZHOU X S， ZHANG L L， et al. Photoredox degradation of different water pollutants （MO， RhB， MB， and Cr（Ⅵ）） using Fe-N-S-tri-doped TiO₂ nanophotocatalyst prepared by novel chemical method［J］. Mater Res Bull， 2015， 70： 106-113.
23	MIA M S， YAO P， ZHU X W， et al. Degradation of textile dyes from aqueous solution using tea-polyphenol/Fe loaded waste silk fabrics as Fenton-like catalysts［J］. RSC Adv， 2021， 11（14）： 8290-8305.
24	RANI B， PUNNIYAKOTI S， SAHU N K. Polyol asserted hydrothermal synthesis of SnO₂ nanoparticles for the fast adsorption and photocatalytic degradation of methylene blue cationic dye［J］. New J Chem， 2018， 42（2）： 943-954.
25	ROUTOULA E， PATWARDHAN S V. Degradation of anthraquinone dyes from effluents： a review focusing on enzymatic dye degradation with industrial potential［J］. Environ Sci Technol， 2020， 54（2）： 647-664.
26	ZHANG S， LI B F， WANG X X， et al. Recent developments of two-dimensional graphene-based composites in visible-light photocatalysis for eliminating persistent organic pollutants from wastewater［J］. Chem Eng J， 2020， 390： 124642.
27	KHASAWNEH O F S， PALANIANDY P. Removal of organic pollutants from water by Fe₂O₃/TiO₂ based photocatalytic degradation： a review［J］. Environ Technol Innovation， 2021， 21： 101230.
28	GAO Z W， PAN C Q， CHOI C H， et al. Continuous-flow photocatalytic microfluidic-reactor for the treatment of aqueous contaminants， simplicity， and complexity： a mini-review［J］. Symmetry， 2021， 13（8）： 1325.
29	JUN L Y， YON L S， MUBARAK N M， et al. An overview of immobilized enzyme technologies for dye and phenolic removal from wastewater［J］. J Environ Chem Eng， 2019， 7（2）： 102961.
30	LI Q， FAN Z L， XUE D X， et al. A multi-dye@MOF composite boosts highly efficient photodegradation of an ultra-stubborn dye reactive blue 21 under visible-light irradiation［J］. J Mater Chem A， 2018， 6（5）： 2148-2156.
31	LI J S， WEN X H， ZHANG Q J， et al. Adsorption and visible-light photodegradation of organic dyes with TiO₂/conjugated microporous polymer composites［J］. RSC Adv， 2018， 8（60）： 34560-34565.
32	SHARMA A， DUTTA R K. Studies on the drastic improvement of photocatalytic degradation of acid orange-74 dye by TPPO capped CuO nanoparticles in tandem with suitable electron capturing agents［J］. RSC Adv， 2015， 5（54）： 43815-43823.
33	LESHUK T， HOLMES A B， RANATUNGA D， et al. Magnetic flocculation for nanoparticle separation and catalyst recycling［J］. Environ Sci： Nano， 2018， 5（2）： 509-519.
34	LI S X， HU T Y， XU Y Z， et al. A review on flocculation as an efficient method to harvest energy microalgae： mechanisms， performances， influencing factors and perspectives［J］. Renewable Sustainable Energy Rev， 2020， 131： 110005.
35	SUN Y J， LI D， LU X， et al. Flocculation of combined contaminants of dye and heavy metal by nano-chitosan flocculants［J］. J Environ Manage， 2021， 299： 113589.
36	SHI Y Q， YANG Z L， XING L， et al. Recent advances in the biodegradation of azo dyes［J］. World J Microbiol Biotechnol， 2021， 37（8）： 137.
37	DAYI B， ONAC C， KAYA A， et al. New type biomembrane： transport and biodegradation of reactive textile dye［J］. ACS Omega， 2020， 5（17）： 9813-9819.
38	NGUYEN T A， FU C C， JUANG R S. Biosorption and biodegradation of a sulfur dye in high-strength dyeing wastewater by acidithiobacillus thiooxidans［J］. J Environ Manage， 2016， 182： 265-271.
39	FAN J X， CHEN D Y， LI N J， et al. Adsorption and biodegradation of dye in wastewater with Fe₃O₄@MIL-100 （Fe） core-shell bio-nanocomposites［J］. Chemosphere， 2018， 191： 315-323.
40	SUN K， WANG L F， WU C Z， et al. Fabrication of α-Fe₂O₃@rGO/PAN nanofiber composite membrane for photocatalytic degradation of organic dyes［J］. Adv Mater Interfaces， 2017， 4（24）： 1700845.
41	SUBAIHI A， NAGLAH A M. Facile synthesis and characterization of Fe₂O₃nanoparticles using L-lysine and L-serine for efficient photocatalytic degradation of methylene blue dye［J］. Arabian J Chem， 2022， 15： 103613.
42	HITAM C N C， JALIL A A. A review on exploration of Fe₂O₃ photocatalyst towards degradation of dyes and organic contaminants［J］. J Environ Manage， 2020， 258： 110050.
43	LI D W， YU S Y， GENG H J， et al. The （002） exposing facets of WO₃ boosting photocatalytic degradation of nitrobenzene［J］. Appl Surf Sci， 2023， 607： 154996.
44	SHANG Y R， CUI Y P， SHI R X， et al. Depositing Ag₃PO₄ on WO₃ hollow microspheres at room temperature for rapid photocatalytic degradation of rhodamine B［J］. Prog Nat Sci， 2022， 32（3）： 282-288.
45	GAO H G， ZHU L J， PENG X， et al. Fe-doped WO₃ nanoplates with excellent bifunctional performances： gas sensing and visible light photocatalytic degradation［J］. Appl Surf Sci， 2022， 592： 153310.
46	NIE J， LI C Y， JIN Z Y， et al. Fabrication of MCC/Cu₂O/GO composite foam with high photocatalytic degradation ability toward methylene blue［J］. Carbohydr Polym， 2019， 223： 115101.
47	ZHAO Q， WANG K， WANG J L， et al. Cu₂O nanoparticle hyper-cross-linked polymer composites for the visible-light photocatalytic degradation of methyl orange［J］. ACS Appl Nano Mater， 2019， 2（5）： 2706.
48	ZHANGA J F， ZHANG Z Q， ZHU W H， et al. Boosted photocatalytic degradation of rhodamine B pollutants with Z-scheme CdS/AgBr-rGO nanocomposite［J］. Appl Surf Sci， 2020， 502： 144275.
49	HU L X， DENG G H， LU W C， et al. Deposition of CdS nanoparticles on MIL-53（Fe） metal-organic framework with enhanced photocatalytic degradation of RhB under visible light irradiation［J］. Appl Surf Sci， 2017， 410： 401-413.
50	BAKHTKHOSH P， MEHRIZAD A. Sonochemical synthesis of Sm-doped ZnS nanoparticles for photocatalytic degradation of direct blue 14： experimental design by response surface methodology and development of a kinetics model［J］. J Mol Liq， 2017， 240： 65-73.
51	WU M H， LI L， LIU N， et al. Molybdenum disulfide （MoS₂） as a co-catalyst for photocatalytic degradation of organic contaminants： a review［J］. Process Saf Environ Prot， 2018， 118： 40-58.
52	ZHOU H， QU W J， WU M， et al. Synthesis of novel BiOBr/Bio-veins composite for photocatalytic degradation of pollutants under visible-light［J］. Surf Interfaces， 2022， 28： 101668.
53	QU J N， SUN X Y， YANG C L， et al. Novel p-n type polyimide aerogels/BiOBr heterojunction for visible light activated high efficient photocatalytic degradation of organic contaminants［J］. J Alloys Compd， 2022， 900： 163469.
54	ALANSI A M， AL-QUNAIBIT M， ALADE I O， et al. Visible-light responsive BiOBr nanoparticles loaded on reduced graphene oxide for photocatalytic degradation of dye［J］. J Mol Liq， 2018， 253： 297-304.
55	NATH I， CHAKRABORTY J， VERPOORT F. Degradation of environmental contaminants by topical heterogeneous photocatalysts［M］. Amsterdam： Elsevier Biomedical Press， 2020： 151-182.
56	WU M， ZHANG J， LIU C X， et al. Rational design and fabrication of noble-metal-free NixP cocatalyst embedded 3D n-TiO₂/g-C₃N₄ heterojunctions with enhanced photocatalytic hydrogen evolution［J］. ChemCatChem， 2018， 10（14）： 3069-3077.
57	YUAN Y J， LU H W， YU Z T， et al. Noble-metal-free molybdenum disulfide cocatalyst for photocatalytic hydrogen production［J］. ChemSusChem， 2015， 8（24）： 4113-4127.
58	SHEN H D， PEPPEL T， STRUNK J， et al. Photocatalytic reduction of CO₂ by metal-free-based materials： recent advances and future perspective［J］. Sol RRL， 2020， 4（8）： 1900546.
59	RAN J R， GUO W W， WANG H L， et al. Metal-free 2D/2D phosphorene/g-C₃N₄ van der waals heterojunction for highly enhanced visible-light photocatalytic H₂ production［J］. Adv Mater， 2018， 30（25）： 1800128.
60	NIKAM L， PANMAND R， KADAM S， et al. Enhanced hydrogen production under visible light source and dye degradation under natural sunlight using nanostructured doped zinc orthotitanates［J］. New J Chem， 2015， 39（5）： 3821-3834.
61	KUSH P， DEORI K， KUMAR A， et al. Efficient hydrogen/oxygen evolution and photocatalytic dye degradation and reduction of aqueous Cr（VI） by surfactant free hydrophilic Cu₂ZnSnS₄ nanoparticles［J］. J Mater Chem A， 2015， 3（15）： 8098-8106.
62	TALUKDAR S， DUTTA R K. A mechanistic approach for superoxide radicals and singlet oxygen mediated enhanced photocatalytic dye degradation by selenium doped ZnS nanoparticles［J］. RSC Adv， 2016， 6（2）： 928-936.
63	KSHIRSAGAR A S， KHANNA P K. CuSbSe₂/TiO₂： novel type-II heterojunction nano-photocatalyst［J］. Mater Chem Front， 2019， 3（3）： 437-449.
64	SHEN G D， PU Y P， SUN R J， et al. Enhanced visible light photocatalytic performance of a novel heterostructured Bi₄Ti₃O₁₂/BiOBr photocatalyst［J］. New J Chem， 2019， 43（33）： 12932-12940.
65	SHEN G D， PU Y P， CUI Y F， et al. Effect of ferroelectric Ba_0.8Sr_0.2TiO₃on the charge carrier separation of BiOBr at different temperature［J］. Appl Surf Sci， 2021， 550： 149366.
66	AU V K M， KWAN S Y， LAI M N， et al. Dual-functional mesoporous copper（Ⅱ） metal-organic frameworks for the remediation of organic dyes［J］. Chem Eur J， 2021， 27（35）： 9174-9179.
67	XAMENA F X L， CORMA A， GARCIA H. Applications for metal-organic frameworks （MOFs） as quantum dot semiconductors［J］. J Phys Chem C， 2007， 111（1）： 80-85.
68	LIU C X， ZHANG W H， WANG N， et al. Highly efficient photocatalytic degradation of dyes by a copper triazolate metal-organic framework［J］. Chem Eur J， 2018， 24（63）： 16804-16813.
69	TIWARI A， SAGARA P S， VARMA V， et al. Bimetallic metal organic frameworks as magnetically separable heterogeneous catalyst for efficient organic transformation and photocatalytic dye degradation［J］. ChemPlusChem， 2019， 84（1）： 136.
70	DAI D L， QIU J H， ZHANG L， et al. Amino-functionalized Ti-metal-organic framework decorated BiOI sphere for simultaneous elimination of Cr（VI） and tetracycline［J］. J Colloid Interface Sci， 2022， 607： 933-941.
71	LIN H D， JIE B R， YE J Y， et al. Recent advance of macroscopic metal-organic frameworks for water treatment： a review［J］. Surf Interfaces， 2023， 36： 102564.
72	WU M， ZHANG J， LIU C X， et al. Rational design and fabrication of noble-metal-free NixP cocatalyst embedded 3D N-TiO₂/g-C₃N₄heterojunctions with enhanced photocatalytic hydrogen evolution［J］. ChemCatChem， 2018， 10（14）： 3069-3077.
73	LI X B， XIONG J， GAO X M， et al. Recent advances in 3D g-C₃N₄ composite photocatalysts for photocatalytic water splitting， degradation of pollutants and CO₂ reduction［J］. J Alloys Compd， 2019， 802： 196-209.
74	NATH K， CHANDRA M， PRADHAN D， et al. Supramolecular organic photocatalyst containing a cubanelike water cluster and donor-acceptor stacks： hydrogen evolution and dye degradation under visible light［J］. ACS Appl Mater Interfaces， 2018， 10（35）： 29417-29424.
75	PORNRUNGROJ C， ONODERA T， OIKAWA H. PCBM nanoparticles as visible-light-driven photocatalysts for photocatalytic decomposition of organic dyes［J］. MRS Commun， 2019， 9（1）： 321-326.
76	MOHAMED M G， ELSAYED M H， ELEWA A M， et al. Pyrene-containing conjugated organic microporous polymers for photocatalytic hydrogen evolution from water［J］. Catal Sci Technol， 2021， 11（6）： 2229-2241.
77	ZHANG Z W， JIA J， ZHI Y F， et al. Porous organic polymers for light-driven organic transformations［J］. Chem Soc Rev， 2022， 51（7）： 2444-2490.
78	GHOSH S， KOUAMÉ N A， RAMOS L， et al. Conducting polymer nanostructures for photocatalysis under visible light［J］. Nat Mater， 2015， 14（5）： 505-511.
79	GHASIMI S， PRESCHER S， WANG Z J， et al. Heterophase photocatalysts from water-soluble conjugated polyelectrolytes： an example of self-initiation under visible light［J］. Angew Chem Int Ed， 2015， 54（48）： 14549-14553.
80	NATHA I， CHAKRABORTYA J， HEYNDERICKXC P M， et al. Engineered synthesis of hierarchical porous organic polymers for visible light and natural sunlight induced rapid degradation of azo， thiazine and fluorescein based dyes in a unique mechanistic pathway［J］. Appl Catal B， 2018， 227： 102-113.
81	WANG J H， YANG H S， JIANG L， et al. Highly efficient removal of organic pollutants by ultrahigh-surface-area-ethynylbenzene-based conjugated microporous polymers via adsorption-photocatalysis synergy［J］. Catal Sci Technol， 2018， 8（19）： 5024-5033.
82	WANG B， XIE Z， LI Y S， et al. Dual-functional conjugated nanoporous polymers for efficient organic pollutants treatment in water： a synergistic strategy of adsorption and photocatalysis［J］. Macromolecules， 2018， 51（9）： 3443-3449.
83	HUANG Q， GUO L P， WANG N， et al. Layered thiazolo［5，4-d］ thiazole-linked conjugated microporous polymers with heteroatom adoption for efficient photocatalysis application［J］. ACS Appl Mater Interfaces， 2019， 11（17）： 15861-15868.
84	CHEN T， LI W Q， CHEN X J， et al. A triazine-based analogue of graphyne： scalable synthesis and applications in photocatalytic dye degradation and bacterial inactivation［J］. Chem Eur J， 2020， 26（10）： 2269-2275.
85	CAO Y P， LIU W， QIAN J， et al. Porous organic polymers containing a sulfur skeleton for visible light degradation of organic dyes［J］. Chem Asian J， 2019， 14（16）： 2883-2888.
86	XU C， XIE Q J， ZHANG W J， et al. A vinylene-bridged conjugated covalent triazine polymer as a visible-light-active photocatalyst for degradation of methylene blue［J］. Macromol Rapid Commun， 2020， 41（7）： 2000006.
87	CHAE J A， JEONG S， KIM H J， et al. Fibrous mesoporous polymer monoliths： macromolecular design and enhanced photocatalytic degradation of aromatic dyes［J］. Polym Chem， 2021， 12（16）： 2464-2470.
88	WANG H， GUAN L J， LIU J W， et al. A thiazolo［5，4-d］thiazole functionalized covalent triazine framework showing superior photocatalytic activity for hydrogen production and dye degradation［J］. J Mater Chem A， 2022， 10（30）： 16328-16336.

Catalysts	Light/nm	Mass/mg	Substrates	Concentration	Time/min	Efficiency/%	Ref.
V₂O₅ NWs	-	2.5	RhB	20 mL（23 mg/L）	70	95	［16］
Sn-TEG	254	20	MB	50 mL（10 mg/L）	15	96.6	［24］
Ag@Zn₂TiO₄	200～700	0.4	RhB	40 mL（5 mg/L）	90	97	［60］
CZTS	400～700	25	RhB	50 mL（194 mg/L）	4	100	［61］
Se_2.6%-ZnS	200～700	40	Trypan blue	50 mL（15 mg/L）	180	99	［62］
CST-T	365	100	RhB	50 mL（100 mg/L）	200	75	［63］
Bi₄Ti₃O₁₂/BiOBr	400～700	20	Acid blue 83	100 mL（5 mg/L）	180	100	［64］
0.9BiOBr/0.1Ba_0.8Sr_0.2TiO₃	200～400	20	Direct blue 5B	200 mL（20 mg/L）	180	98	［65］

Catalysts	Light/nm	Mass/mg	Substrates	Concentration	Time/min	Efficiency/%	Ref.
V₂O₅ NWs	-	2.5	RhB	20 mL（23 mg/L）	70	95	［16］
Sn-TEG	254	20	MB	50 mL（10 mg/L）	15	96.6	［24］
Ag@Zn₂TiO₄	200～700	0.4	RhB	40 mL（5 mg/L）	90	97	［60］
CZTS	400～700	25	RhB	50 mL（194 mg/L）	4	100	［61］
Se_2.6%-ZnS	200～700	40	Trypan blue	50 mL（15 mg/L）	180	99	［62］
CST-T	365	100	RhB	50 mL（100 mg/L）	200	75	［63］
Bi₄Ti₃O₁₂/BiOBr	400～700	20	Acid blue 83	100 mL（5 mg/L）	180	100	［64］
0.9BiOBr/0.1Ba_0.8Sr_0.2TiO₃	200～400	20	Direct blue 5B	200 mL（20 mg/L）	180	98	［65］

Catalysts	Wave length/nm	Mass/mg	Substrates	Concentration	Time	Efficiency/%	Ref.
Ce-MOF-589	-	1	MB	40 mg/L（1 mL）	15 min	96	［13］
^PTBMOF	200~800	20	Tartrazine	23 mg/L	24 h	98.9	［66］
CuTz-1	200~800	12	RhB	12 mg/L（20 mL）	22 min	100	［68］
BMOF	200~800	10	MB	3.7 mg/L	90 min	57	［69］

Catalysts	Wave length/nm	Mass/mg	Substrates	Concentration	Time	Efficiency/%	Ref.
Ce-MOF-589	-	1	MB	40 mg/L（1 mL）	15 min	96	［13］
^PTBMOF	200~800	20	Tartrazine	23 mg/L	24 h	98.9	［66］
CuTz-1	200~800	12	RhB	12 mg/L（20 mL）	22 min	100	［68］
BMOF	200~800	10	MB	3.7 mg/L	90 min	57	［69］

Catalysts	Light	Mass/mg	Substrate	Concentration	Time	Efficiency/%	Ref.
TM-2-d	High pressure mercury lamp（500 W）	1 000	MB	300 mg/L（2 000 mL）	12 h	100	［15］
ANP	300～700 nm	50	MB	37 mg/L（20 mL）	200 min	97	［74］
PCBM	300～700 nm	1.2	RhB	6.7 mg/mL（3mL）	30 min	90	［75］

Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 17

References 88

Related Articles 15

Recommended Articles

Metrics

Comments

Catalysts	Wavelength	Mass/mg	Substrates	Concentration	Time	Efficiency/%	Ref.
10%TrCMP/TiO₂	300～700 nm	26.25	MB	8.1 mg/L（35 mL）	20 min	92.5	［31］
Nano PDPB	λ＞450 nm	3.5	MO	3.27 mg/L（3.5 mL）	240 min	75	［78］
P-FL-BT-3	300～700 nm	1	RhB	10 mg/mL（10 mL）	70 min	90	［79］
POPs-2	λ＞420 nm	10	CR	10 mg/L（10 mL）	90 min	85	［80］
PTEB	λ＞420 nm	0.3	RhB	20 mg/L	50 min	100	［81］
Py-BF-CMP	λ＞450 nm	4	RhB	25 mg/L（20 mL）	30 min	81	［82］
TZCP-3	λ＞420 nm	5	RhB	10 mg/L（100 mL）	30 min	100	［83］
TA-BGY	200～1300 nm	20	MB	30 mg/L（20 mL）	8 h	80	［84］
TpSD	300～700 nm	3	Rh6G	10 mg/L（30 mL）	60 min	99.2	［85］
sp²c-CTP-4	300～700 nm	3	MB	40 mg/L（5 mL）	90 min	98	［86］
network-3	300～700 nm	14.2	MB	4 mg/L	90 min	95	［87］
CTF-NWU-1	λ＞420 nm	10	RhB	20 mg/L（50 mL）	30 min	99	［88］

[1]	Lin-Jie SHANG, Jiang LIU, Ya-Qian LAN. Covalent Organic Framework Materials for Photo/ Electrocatalytic Carbon Dioxide Reduction [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 559-584.
[2]	Jia-He WANG, Da-Yong LIU, Wei LIU, Lin WANG, Biao DONG. Research Progress on Photocatalytic Antibacterial Application of TiO₂ Nano Materials [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 629-646.
[3]	Hui LU, Jiang LI, Li-Hua WANG, Ying ZHU, Jing CHEN. Researsh Progress of Photocatalytic Applications of Atomically Precise Coinage Metal Nanoclusters [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1652-1664.
[4]	Xiang-Zhi YE, Yun-Shui DENG, Yuan LIU, Yong-Liu ZHOU, Jian-Xiong HE, Chun-Rong XIONG. Glass Sphere Supported Amorphous Organotitanium Polymer to Improve the Turnover Frequency in Photocatalytic Reduction of CO₂ [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1554-1563.
[5]	Ying-Zi LI, Ting LIU, Si-Qi WU, Xuan FANG, Jing GAO, Shi TANG. Metallaphotoredox⁃Catalyzed O⁃Arylation of Serine [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1610-1616.
[6]	YANG Yu-Ping, XU Shao-Hong, MA Guo-Yang, JIAO Li-Ming, SUN Li-Ping, XIA Ran. Synthesis of 5-Deuterated Ribavirin Derivative [J]. Chinese Journal of Applied Chemistry, 2021, 38(8): 911-916.
[7]	ZHANG Ming-Shan, LI Teng-Ya, LEI Yu, WU Yan, HE Shu-Hai. Determination of Two Sulfonamides in Environmental Water Based on Dispersivesolid-Phase Extraction with MIL-101(Cr) Metal-Organic Framework [J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 236-244.
[8]	WU Qiu-Ping, CAI Kun-Ting, WANG Yuan-Kang, SUN Kai, YANG Jin-Bo, HAN Song-Bai, LIU Yun-Tao. Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 0-0.
[9]	WU Qiu-Ping, CAI Kun-Ting, WANG Yuan-Kang, SUN Kai, YANG Jin-Bo, HAN Song-Bai, LIU Yun-Tao. Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1588-1598.
[10]	TANG Fei, DU Duo-Qin, TAN Yun-Fei, QIN Li-Xiao. Preparation and Characterization of MoO_3-x Hexagonal Microrods as High-Efficiency Photocatalysts [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 92-98.
[11]	ZHANG Chun-Hua, ZHAO Xiao-Bo, LI Yue-Jun, SUN Da-Wei. Preparation of (BiO)₂CO₃-Bi-TiO₂ Composite Nanofibers and Its Photocatalytic Degradation of Antibiotics [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 99-106.
[12]	HUANG Jieying, LIU Jianjun, ZUO Shengli, HAN Wenjing, YU Yingchun. Preparation of Ag₃PO₄ Quantum Dots/g-C₃N₄ Nanosheet Composite Photocatalysts and Its Activity for Selective Oxidation of Benzyl Alcohol [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1030-1037.
[13]	WANG Yuting,YANG Tianyi,ZHANG Yinghui. Application of Porphyrin-Based Framework Materials on Photocatalysis [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 611-619.
[14]	FAN Zhe,ZHANG Shengsheng,TANG Jiahao,FAN Ping. Structure, Preparation and Application of Graded Nanomaterials [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 489-501.
[15]	GUO Hongxia, CUI Jifang, LIU Li. Research Progress in Photocatalytic Reduction of CO₂ Enhanced by Oxygen Vacancy [J]. Chinese Journal of Applied Chemistry, 2020, 37(3): 256-263.