Preparation of (BiO)2CO3-Bi-TiO2 Composite Nanofibers and Its Photocatalytic Degradation of Antibiotics

doi:10.19894/j.issn.1000-0518.200203

Chinese Journal of Applied Chemistry ›› 2021, Vol. 38 ›› Issue (1): 99-106.DOI: 10.19894/j.issn.1000-0518.200203

• Full Papers • Previous Articles Next Articles

Preparation of (BiO)₂CO₃-Bi-TiO₂ Composite Nanofibers and Its Photocatalytic Degradation of Antibiotics

ZHANG Chun-Hua, ZHAO Xiao-Bo^*, LI Yue-Jun, SUN Da-Wei

College of Chemistry,Baicheng Normal University,Baicheng 137000,China

Received:2020-07-06 Revised:2020-08-21 Published:2021-01-01 Online:2021-02-01
Supported by:
National Natural Science Foundation of China(No.21573003) and Jilin Province Education Department “13th Five-Year Plan” Science and Technology Research Project(No.201638)

Abstract

Abstract: The heterojunction type Bi-TiO₂, (BiO)₂CO₃-TiO₂ and (BiO)₂CO₃-Bi-TiO₂ composite nanofibers were synthesized via a facile one-step solvothermal method, using electrospun TiO₂ nanofibers as the substrate and glucose as reducing agent,in acidic or alkaline environments. The obtained materials were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) and photoluminescence (PL) spectroscopy. The photocatalytic activities of the samples were evaluated by photodegradation of lomefloxacin, ciprofloxacin and norfloxacin as the target pollutants, under simulated sunlight irradiation, and the degradation reaction mechanism was explored. The results show that (BiO)₂CO₃-Bi-TiO₂ photocatalyst exhibits the highest photocatalytic activity, with the degradation rate of norfloxacin, lomefloxacin and ciprofloxacin of 93.2%, 97.5% and 100%, respectively, under simulated sunlight irradiation for 60 min.

Key words: Composite nanofibers, Plasma resonance effect, Antibiotic drugs, Photocatalysis

CLC Number:

O643

ZHANG Chun-Hua, ZHAO Xiao-Bo, LI Yue-Jun, SUN Da-Wei. Preparation of (BiO)₂CO₃-Bi-TiO₂ Composite Nanofibers and Its Photocatalytic Degradation of Antibiotics[J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 99-106.

References

[1] BURCH T R, SADOWSKY M J, LAPARA T M. Fate of antibiotic resistance genes and class 1 integrons in soil microcosms following the application of treated residual municipal wastewater solids[J]. Environ Sci Technol, 2014, 48:5620-5627.
[2] CHRISTGEN B, YANG Y, AHAMMAD S Z, et al. Metagenomics shows that low-energy anaerobic-aerobic treatment reactors reduce antibiotic resistance gene levels from domestic wastewater[J]. Environ Sci Technol, 2015, 49(4):2577-2584.
[3] 霍朝晖, 杨晓珊, 陈晓丽, 等. 纳米银/二维石墨相氮化碳/还原氧化石墨烯复合材料的制备及其光催化降解抗生素[J]. 应用化学, 2020, 27(4):471-480.
HUO Z H,YANG X S,CHEN X L, et al. Preparation of Ag/two-dimensional graphitic carbon nitride/reduced graphene oxide composite and its photocatalytic degradation of antibiotics[J]. Chinese J Appl Chem, 2020, 27(4):471-480.
[4] LI D, ZENG S Y, HE M, et al. Water disinfection byproducts induce antibiotics resistance-role of environmental pollutants in resistance phenomena[J]. Environ Sci Technol, 2016, 50(6):3193-3201.
[5] LI S, HU J Y. Photolytic and photocatalytic degradation of tetracycline; effect of humic acid on degradation kinetics and mechanisms[J]. J Hazard Mater, 2016, 318(15):134-144.
[6] YAN W, YAN L, JING C Y. Impact of doped metals on urea-derived g-C₃N₄ for photocatalytic degradation of antibiotics:structure, photoactivity and degradation mechanisms[J]. Appl Catal B:Environ, 2019, 244(5):475-485.
[7] IAKOVIDES I C,MICHAEL-KORDATOU I,MOREIRA N F F, et al. Continuous ozonation of urban wastewater:removal of antibiotics, antibiotic-resistant Escherichia coli and antibiotic resistance genes and phytotoxicity[J]. Water Res, 2019, 159:333-347.
[8] AHMAD H,KAMARUDIN S K,MINGGU L J, et al. Hydrogen from photo-catalytic water splitting process:a review[J]. Renew Sustainable Energy Rev, 2015, 43:599-610.
[9] HE W J,SUN Y J,JIANG G M, et al. Defective Bi₄MoO₉/Bi metal Core/Shell heterostructure:enhanced visible light photocatalysis and reaction mechanism[J]. Appl Catal B:Environ,2018,239:619-627.
[10] DONG F, ZHAO Z W, SUN Y J, et al. An advanced semimetal-organic Bi spheres g-C₃N₄ nanohybrid with SPR-enhanced visible-light photocatalytic performance for NO purification[J]. Environ Sci Technol, 2015, 49(20):12432-12440.
[11] QU L L, LUO Z J, TANG C. One step synthesis of Bi@Bi₂O₃@carboxylate-rich carbon spheres with enhanced photocatalytic performance[J]. Mater Res Bull, 2013, 48(11):4601- 4605.
[12] ZHANG Y F, ZHU G Q, HOJAMBERDIEV M, et al. Synergistic effect of oxygen vacancy and nitrogen doping on enhancing the photocatalytic activity of Bi₂O₂CO₃ nanosheets with exposed {001} facets for the degradation of organic pollutants[J]. Appl Surf Sci, 2016, 371:231-241.
[13] LIU Y Y, WANG Z Y, HUANG B B, et al. Preparation, electronic structure, and photocatalytic properties of Bi₂O₂CO₃ nanosheet[J]. Appl Surf Sci, 2010, 257(1):172-175.
[14] CEN W L, XIONG T, TANG C Y, et al. Effects of morphology and crystallinity on the photocatalytic activity of (BiO)₂CO₃ nano/Microstructures[J]. Ind Eng Chem Res, 2014, 53(39):15002-15011.
[15] AI Z H, HO W K, LEE S C, et al. Efficient photocatalytic removal of NO in indoor air with hierarchical bismuth oxybromide nanoplate microspheres under visible light[J]. Environ Sci Technol, 2009, 43(11):4143-4150.
[16] NYHOLM R, BERNDTSSON A, MARTENSSON N. Core level binding energies for the elements Hf to Bi (Z=72-83)[J]. J Phys C:Solid St Phys, 1980, 13:L1091-L1096.
[17] LI Y Y, DANG L Y, HAN L F, et al. Iodine-sensitized Bi₄Ti₃O₁₂/TiO₂ photocatalyst with enhanced photocatalytic activity on degradation of phenol[J]. J Mol Catal A:Chem, 2013, 379(15):146-151.
[18] ZHOU Y G, ZHANG Y F, LIN M S, et al. Monolayered Bi₂WO₆ nanosheets mimicking heterojunction interface with open surfaces for photocatalysis[J]. Nat Commun, 2015, 6:8340-8347.
[19] DONG F, LI Q Y, SUN Y J, et al. Noble metal-like behavior of plasmonic Bi particles as a cocatalyst deposited on (BiO)₂CO₃ microspheres for efficient visible light photocatalysis[J]. ACS Catal, 2014, 4:4341-4350.
[20] MCMAHON J M,SCHATZ G C, GRAY S K. Plasmonics in the ultraviolet with the poor metals Al, Ga, In, Sn, Tl, Pb, and Bi[J]. Phys Chem Chem Phys, 2013, 15:5415-5423.
[21] WANG Z, JIANG C L, HUANG R, et al. Investigation of optical and photocatalytic properties of bismuth nanospheres prepared by a facilethermolysis method[J]. J Phys Chem C, 2014, 118(2):1155-1160.

Preparation of (BiO)₂CO₃-Bi-TiO₂ Composite Nanofibers and Its Photocatalytic Degradation of Antibiotics

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Xue-Bo LEI, Hui-Jing LIU, He-Yu DING, Guo-Dong SHEN, Run-Jun SUN. Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 681-696.
[2]	Lin-Jie SHANG, Jiang LIU, Ya-Qian LAN. Covalent Organic Framework Materials for Photo/ Electrocatalytic Carbon Dioxide Reduction [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 559-584.
[3]	Jia-He WANG, Da-Yong LIU, Wei LIU, Lin WANG, Biao DONG. Research Progress on Photocatalytic Antibacterial Application of TiO₂ Nano Materials [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 629-646.
[4]	Hui LU, Jiang LI, Li-Hua WANG, Ying ZHU, Jing CHEN. Researsh Progress of Photocatalytic Applications of Atomically Precise Coinage Metal Nanoclusters [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1652-1664.
[5]	Xiang-Zhi YE, Yun-Shui DENG, Yuan LIU, Yong-Liu ZHOU, Jian-Xiong HE, Chun-Rong XIONG. Glass Sphere Supported Amorphous Organotitanium Polymer to Improve the Turnover Frequency in Photocatalytic Reduction of CO₂ [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1554-1563.
[6]	Ying-Zi LI, Ting LIU, Si-Qi WU, Xuan FANG, Jing GAO, Shi TANG. Metallaphotoredox⁃Catalyzed O⁃Arylation of Serine [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1610-1616.
[7]	YANG Yu-Ping, XU Shao-Hong, MA Guo-Yang, JIAO Li-Ming, SUN Li-Ping, XIA Ran. Synthesis of 5-Deuterated Ribavirin Derivative [J]. Chinese Journal of Applied Chemistry, 2021, 38(8): 911-916.
[8]	TANG Fei, DU Duo-Qin, TAN Yun-Fei, QIN Li-Xiao. Preparation and Characterization of MoO_3-x Hexagonal Microrods as High-Efficiency Photocatalysts [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 92-98.
[9]	HUANG Jieying, LIU Jianjun, ZUO Shengli, HAN Wenjing, YU Yingchun. Preparation of Ag₃PO₄ Quantum Dots/g-C₃N₄ Nanosheet Composite Photocatalysts and Its Activity for Selective Oxidation of Benzyl Alcohol [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1030-1037.
[10]	WANG Yuting,YANG Tianyi,ZHANG Yinghui. Application of Porphyrin-Based Framework Materials on Photocatalysis [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 611-619.
[11]	FAN Zhe,ZHANG Shengsheng,TANG Jiahao,FAN Ping. Structure, Preparation and Application of Graded Nanomaterials [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 489-501.
[12]	GUO Hongxia, CUI Jifang, LIU Li. Research Progress in Photocatalytic Reduction of CO₂ Enhanced by Oxygen Vacancy [J]. Chinese Journal of Applied Chemistry, 2020, 37(3): 256-263.
[13]	LIU Bing, GONG Huili, LIU Rui, HU Changwen. One-Step Synthesis of TiO₂-Au Composite and Its Performance for Photocatalytic Hydrogen Evolution [J]. Chinese Journal of Applied Chemistry, 2019, 36(9): 1076-1084.
[14]	LIU Bing, GONG Huili, LIU Rui, HU Changwen. Synthesis of TiO₂ Coated Gold Nanorod with Core-Shell Structure and Its Photocatalytic Hydrogen Evolution [J]. Chinese Journal of Applied Chemistry, 2019, 36(8): 939-948.
[15]	MAO Xiaoming, TANG Xin, LI Min, LI Hui, LIANG Yaqin, LI Yan. Preparation and Photocatalytic Activity of BiOCl/Montmorillonite Composite Photocatalyst [J]. Chinese Journal of Applied Chemistry, 2019, 36(4): 474-481.