Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (9): 1382-1390.DOI: 10.19894/j.issn.1000-0518.210369
• Full Papers • Previous Articles Next Articles
Zhen-Hua YANG, Xuan-Sen SUN, Yue-Xia ZHANG, Yu-Juan CAO, Qi-Qi ZHANG, Qiao-Zhi GUO, Xiao-Peng FAN, Zhong-Ping LI, Chuan DONG()
Received:
2021-07-27
Accepted:
2022-02-23
Published:
2022-09-01
Online:
2022-09-08
Contact:
Chuan DONG
About author:
dc@sxu.edu.cnSupported by:
CLC Number:
Zhen-Hua YANG, Xuan-Sen SUN, Yue-Xia ZHANG, Yu-Juan CAO, Qi-Qi ZHANG, Qiao-Zhi GUO, Xiao-Peng FAN, Zhong-Ping LI, Chuan DONG. Preparation of Nitrogen Sulfur Co⁃doped Carbon Dots with Nitrogen Sulfur and the Application for Detection of Oxytetracycline in Milk[J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1382-1390.
Add to citation manager EndNote|Ris|BibTeX
URL: http://yyhx.ciac.jl.cn/EN/10.19894/j.issn.1000-0518.210369
Fig.3 (A) UV-Vis absorption, fluorescence excitation, and excitation spectra of N,S-CDs aqueous solution;(B) PL spectra of N,S-CDs aqueous solution at different excitation wavelengths
Fig.8 (A) Effect of different antibiotics on fluorescence intensity of N,S-CDs; (B) Effect of different reaction time on fluorescence intensity of oxytetracycline
Fig.9 (A) Fluorescence emission spectra of N,S-CDs with different concentrations of OTC (c(OTC)/(μmol·L-1): 0, 1.67, 3.34, 5.01, 6.68, 8.35, 10.02, 11.69, 13.36, 15.03, 16.7, 18.37, 20.04, 21.71, 23.38, 25.05, 26.72, 28.39, 30.06, 31.73, 33.4, 35.07, 36.74, 38.41 and 40.08); (B)Plot of(F0-F)/F0 against OTC concentration
样品 Sample | 加入量 Added ρ/(μg·mL-1) | 测定量 Detected ρ/(μg·mL-1) | 回收率 Recovery R/% | 相对标准偏差 RSD St/% |
---|---|---|---|---|
1 | 3.07 | 3.15 | 102.60 | 4.32 |
2 | 4.60 | 4.52 | 98.30 | 3.81 |
3 | 6.13 | 6.00 | 97.90 | 3.42 |
Table 1 Determination of oxytetracycline (OTC) in milk by the standard recovery method
样品 Sample | 加入量 Added ρ/(μg·mL-1) | 测定量 Detected ρ/(μg·mL-1) | 回收率 Recovery R/% | 相对标准偏差 RSD St/% |
---|---|---|---|---|
1 | 3.07 | 3.15 | 102.60 | 4.32 |
2 | 4.60 | 4.52 | 98.30 | 3.81 |
3 | 6.13 | 6.00 | 97.90 | 3.42 |
1 | LI L L, GE H W, GUO H Y, et al. Focusing on luminescent graphene quantum dots: current status and future perspectives[J]. Nanoscale, 2013, 5(10): 4015-4039. |
2 | ZHOU X, GAO X, SONG F, et al. A sensing approach for dopa mine determination by boronic acid-functionalized molecularly imprinted graphene quantum dots composite[J]. Appl Surf Sci, 2017, 423(30): 810-816. |
3 | WANG Y, LI X, SONG J, et al. All-inorganic colloidal perovskite quantum dots: a new class of lasing materials with favorable characteristics[J]. Adv Mater, 2015, 47(5): 7101-7108. |
4 | PANDIT S, BANERJEE T, SRIVASTAVA I, et al. Machine learning-assisted array-based biomolecular sensing using surface-functionalized carbon dots[J]. ACS Sens, 2019, 4(10): 2730-2737. |
5 | 颜范勇, 邹宇, 王猛, 等. 荧光碳点的制备及应用[J]. 化学进展, 2014, 26(1): 61-74. |
YAN F Y, ZOU Y, WANG M, et al. Synthesis and application of the fluorescent carbon dots[J]. Prog Chem, 2014, 26(1): 61-74. | |
6 | YU C Y, XUAN T T, CHEN Y W, et a1. Gadolinium-doped carbon dots with high quantum yield as an effective fluorescence and magnetic resonance bimodal imaging probe[J]. J Alloys Compd, 2016, 688: 611-619. |
7 | ZHUO K L, SUN D, XU P P, et a1. Green synthesis of sulfur- and nitrogen-co-doped carbon dots using ionic liquid as a precursor and their application in Hg2+ detection[J]. J Lumin, 2017, 187: 227-234. |
8 | MIAO X, YAN X L, QU D, et a1. Red emissive sulfur, nitrogen codoped carbon dots and their application in ion detection and theraonostics[J]. ACS Appl Mater Interfaces, 2017, 9(22): 18549-18556. |
9 | 温广明, 焦婷, 杜孝艳, 等. 硫氮共掺杂碳量子点的制备及应用[J]. 应用化学, 2021, 38(6): 722-730. |
WEN G M, JIAO T, DU X Y, et al. Preparation and application of sulfur and nitrogen co-doped carbon quantum dots[J]. Chinese J Appl Chem, 2021, 38(6): 722-730. | |
10 | 胡国文, 乔玉玲. 叶酸修饰的碳量子点在体外癌细胞成像中的应用[J]. 应用化学, 2020, 37(9): 1003-1009. |
HU G W, QIAO Y L. Folic acid-carbon dot conjugates for cancer cell targeting[J]. Chinese J Appl Chem, 2020, 37(9): 1003-1009. | |
11 | 徐丽萍, 刘清士, 董芷辰, 等. 基于氮掺杂碳点的荧光增强简便、快速而准确地检测环丙沙星[J]. 应用化学, 2020, 37(7): 830-838. |
XU L P, LIU Q S, DONG Z C, et al. Simple, fast and accurate detection of ciprofloxacin based on fluorescence enhancement of nitrogen-doped carbon dots[J]. Chinese J Appl Chem, 2020, 37(7): 830-838. | |
12 | 陈桂秀, 吴银宝. 兽药土霉素的环境行为研究进展[J]. 动物医学进展, 2011, 32(5): 102-107. |
CHEN G X, WU Y B. Progress on environmental behavior of oxytetracycline[J]. Prog Veter Med, 2011, 32(5): 102-107. | |
13 | 宓捷波, 许迪明, 李淑静, 等. 奶粉中残留兽药的QuEChERS方法应用研究[J]. 食品研究与开发, 2015, 36(2): 121-125. |
FU J B, XU D M, LI S J, et al. Applied research on QuEChERS using to determine veterinary drugs residues in milk powder[J]. Food Res Dev, 2015, 36(2): 121-125. | |
14 | 高广慧, 李阳, 孙晓娟, 等. HPLC法测定牛羊肉中土霉素、四环素、金霉素残留量[J]. 食品研究与开发, 2013, 34(16): 94-96. |
GAO G H, LI Y, SUN X J, et al. Determination of oxytetracycline, tetracycline and chlortetracycline residues in beef and mutton by HPLC[J]. Food Res Dev, 2013, 34(16): 94-96. | |
15 | 刘玲. HPLC法测定土霉素片中土霉素的含量[J]. 海峡药学, 2018, 30(10): 77-78. |
LIU L. Determination of oxytetracycline in oxytetracycline tablets by HPLC[J]. Strait Pharm J, 2018, 30(10): 77-78. | |
16 | TARPARN L, MENCARELLI E, NOCCHETTI M, et al. Spectrophotometric analysis of nickel colloid performances as catalysts for hydrogenation of nitro-phenol: influence of the stabilizing agents[J]. Catal Commu, 2016, 74: 28-32. |
17 | DENG H, SU X, WANG H. Simultaneous determination of aflatoxin B1, bisphenol A, and 4-nonylphenol in peanut oils by liquid-liquid extraction combined with solid-phase extraction and ultra-high performance liquid chromatography-tandem mass spectrometry[J]. Food Anal Methods, 2018, 11(5): 1303-1311. |
18 | HIRA S A, NALLAL M, PARK K H. Fabrication of PdAg nanoparticle infused metal-organic framework for electrochemical and solution-chemical reduction and detection of toxic 4-nitrophenol[J]. Sens Actuators B: Chem, 2019, 298: 126861. |
19 | 严拯宇, 赵娜, 刘贞, 等. 生物质碳点的合成及初步用于盐酸土霉素的测定[J]. 无机化学学报, 2014, 30(4): 937-944. |
YAN C Y, ZHAO N, LIU Z, et al. Biomass-based carbon dots: synthesis and application in oxytetracycline hydrochloride determination[J]. Chinese J Inorg Chem, 2014, 30(4): 937-944. | |
20 | KORKMAZ S D, KUPLULU O, CIL G I, et al. Detection of sulfonamide and tetracycline antibiotic residues in Turkish pine honey[J]. Int J Food Prop, 2017, 34(4): 50-55. |
21 | 屈瑞红, 郑国柱. 基于碳量子点荧光猝灭法测定牛奶中的土霉素[J]. 广东化工, 2020, 47(23): 120-121. |
QU R H, ZHENG G Z. Determination of oxytetracycline in milk based on fluorescence quenching of carbon quantum cots[J]. Guangdong Chem Ind, 2020, 47(23): 120-121. | |
22 | 徐铭泽, 廖秀芬, 陶慧林, 等. 基于CdS@ZnS量子点与罗丹明B能量转移荧光猝灭法检测牛奶中土霉素[J]. 分析测试学报, 2013, 32(10): 1217-1221. |
XU M Z, LIAO X F, TAO H L, et al. Study on fluorescence resonance energy transfer between CdS@ZnS QDs and rhodamine B and its application in determination of oxytetracycline in milk[J]. J Instrumental Anal, 2013, 32(10): 1217-1221. | |
23 | WANG Y L, NI P J, JIANG S, et al. Highly sensitive fluorometric determination of oxytetracycline based on carbon dots and Fe3O4 MNPs[J]. Sens Actuators B: Chem 2018, 254: 1118-1124. |
24 | FU Y Z, HUANG L, ZHAO S J, et al. A carbon dot-based fluorometric probe for oxytetracycline detection utilizing a frster resonance energy transfer mechanism[J]. Spectrochim Acta A, 2020, 246: 118947. |
25 | FAN J, QI L, LI Y, et al. A single probe-based sensor array for fingerprinting biothiols in serum and urine via surfactant modulation strategy[J]. Sens Actuators B: Chem, 2019, 301: 127144. |
26 | 孙雪花, 李浩, 杨娇莉, 等. 曲克芦丁对发光碳量子点的荧光猝灭作用[J]. 化学研究与应用, 2018, 30(11): 1857-1860. |
SUN X H, LI H, YANG J L, et al. Fluorescence quenching of luminous carbon quantum dots by troxerutin[J]. Chem Res Appl, 2018, 30(11): 1857-1860. |
[1] | Yue-Xia ZHANG, Xiao-Peng FAN, Yu-Juan CAO, Xin-Tong YANG, Zhong-Ping LI, Zhen-Hua YANG, Chuan DONG. Synthesis of Oil-soluble Carbon Quantum Dots by Pyrolysis Method for the Detection of Oxytetracycline [J]. Chinese Journal of Applied Chemistry, 2023, 40(4): 509-517. |
[2] | Rui-Zhe WANG, Guang-Qi HU, Wei-Hao YE, Chao-Fan HU, Jian-Le ZHUANG, Bing-Fu LEI, Wei LI, Ying-Liang LIU. Hydrothermal Preparation and Application of Oil-soluble Carbon Dots with High Ultraviolet-short-wave Blue Light Shielding [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 59-68. |
[3] | Lian-Bo TANG, Da-You FU, Qi CHEN, Yang-Run FENG, Ya-Lin XIONG, Zhu-Qing WANG. Enhanced Gas⁃Liquid Chemiluminescence by Carbon Dots for Determination of Carbon Dioxide [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1294-1302. |
[4] | Hai-Yan QI, Chen-Qi ZHANG, Jin-Long LI, Jun LI. Synthesis of Sulfur and Nitrogen Doped Carbon Dots for Cu(Ⅱ) Detection [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 980-989. |
[5] | Jin-Ping SONG, Qi MA, Xiao-Min LIANG, Jian-Peng SHANG, Chuan DONG. Neodymium and Nitrogen Co‑doped Carbon Dots with High Fluorescence Quantum Yield for Detection of Sulfasalazine and Hela Cell Imaging [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1726-1734. |
[6] | Dan MENG, Kai-Yuan ZHENG, Shan-Shan CHEN, Zhao-Long ZHUO, Li-Li WANG. Preparation and Luminescence Properties of Silicon and Nitrogen Co⁃doped Carbon Dots Phosphors [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1766-1773. |
[7] | Yuan-Hao JIAO, Hong-Yan CUI, Liu-Wei ZHANG, Shuang ZENG, Hao WANG, Ming ZHANG, Jing-Yun WANG, Qi-Xian CHEN. Fabrication of Multifunctional Gene Delivery Systems Responsible to Intracellular Microenvironments Through in situ Polymerization [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1510-1522. |
[8] | TANG Jun, DU Yang, ZHAO Feng-Jiao, CUI Meng, LIU Zhi-Qiang. Electrospray Ionization Tandem Mass Spectrometry on the Interaction of Baicalin and Glutathione [J]. Chinese Journal of Applied Chemistry, 2021, 38(3): 331-342. |
[9] | LIU Qiao-Ling, REN Bo-Rong, LIU Rui-Rong, LI Yu-Xia, WANG Gui-Xiang, REN Zi-Wei, DONG Chuan. N-Doped Carbon Dots with Ratio Fluorescent Detection for Ag+ [J]. Chinese Journal of Applied Chemistry, 2021, 38(11): 1512-1520. |
[10] | HU Guowen, QIAO Yuling. Folic Acid-Carbon Dot Conjugates for Cancer Cell Targeting [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1003-1009. |
[11] | HU Guowen, QIAO Yuling. Folic Acid-Carbon Dot Conjugates for Cancer Cell Targeting [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 0-0. |
[12] | XU Liping, LIU Qingshi, DONG Zhichen, GUO Xingjia, DONG Wei. Simple, Fast and Accurate Detection of Ciprofloxacin Based on Fluorescence Enhancement of Nitrogen-Doped Carbon Dots [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 830-838. |
[13] | ZHANG Chenglu, SUN Yuedong, DING Yanwei, WANG Jing, LIU Xingbing, WANG Nan, SONG Fulu. A Quinolinone-Based Fluorescent Probe for Rapid and Highly Selective Detection of Glutathione [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 847-854. |
[14] | MENG Yating, JIAO Yuan, ZHANG Yuan, GAO Yifang, LU Wenjing, LIU Yang, DONG Chuan. Synthesis of Red Emission Fluorescent Carbon Dots and Its Application for Detection of Persulfate [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 719-725. |
[15] | GONG Hui, KANG Yu, ZHANG Rong, REN Guodong, HOU Xiaoyu, ZHANG Min, LI Lihong, LIU Wen, WANG Haojiang, DIAO Haipeng. Preparation of Nitrogen-Doped Carbon Dots for Highly Sensitive Detection of Amoxicillin [J]. Chinese Journal of Applied Chemistry, 2020, 37(2): 227-234. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||