Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries

doi:10.11944/j.issn.1000-0518.2020.04.190243

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (4): 387-404.DOI: 10.11944/j.issn.1000-0518.2020.04.190243

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Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries

WANG Chunli^a^b,SUN Lianshan^a^c,ZHONG Ming^d,WANG Limin^a^b,CHENG Yong^a^*()

^aState Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
^bSchool of Applied Chemistry and Engineering,University of Science and Technology of China,Hefei 230026,China
^cInstitute for Energy Research,Key Laboratory of Zhenjiang, Jiangsu University,Zhenjiang,Jiangsu 212013,China
^dJiangxi JXTC Haoyun High-tech Co.,Ltd,Nanchang 330096,China

Received:2019-09-11 Accepted:2019-12-17 Published:2020-04-01 Online:2020-04-10
Contact: CHENG Yong
Supported by:
Supported by the National Key Research and Development Program of China(No.2017YFE9128100)

Abstract

Abstract:

Lithium-sulfur batteries are considered to be the next-generation secondary batteries with development potentials due to high theoretical specific capacity and low cost. However, there are several limitations of the sulfur cathodes due to the insulating nature of sulfur and Li₂S, the “shuttle effect” caused by the intermediate lithium polysulfides(Li₂S_x, 4≤x≤8) dissolved and migrated in the electrolyte and serious side effects, resulting in low utilization of the active materials, poor cycling stability and rate performances. In this paper, the research progress of transition metal nano materials in lithium-sulfur batteries is reviewed. Especially, the synthetic methods of materials and the reaction mechanism for inhibiting the dissolution of lithium polysulfide and promoting the conversion are introduced and the development of cathode carrier materials for lithium-sulfur batteries is forecasted.

Key words: transition metal compounds, nanomaterials, lithium sulfur battery, electrochemical performances, chemical adsorption

WANG Chunli,SUN Lianshan,ZHONG Ming,WANG Limin,CHENG Yong. Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries[J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 387-404.

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Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries

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