A New Mesoporous Cobalt Metal-organic Framework was Synthesized by Post-functionalization and Its Application for the Epoxidation of Olefins

doi:10.3724/SP.J.1095.2014.30511

Chinese Journal of Applied Chemistry

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A New Mesoporous Cobalt Metal-organic Framework was Synthesized by Post-functionalization and Its Application for the Epoxidation of Olefins

SHA Sha^1,2, LI Jun², ZHUANG Changfu², LIU Shuxia^1*, GAO Shuang^2*

(1.Key Lab of Polyoxometalate Science,Department of Chemistry,Northeast Normal University,Changchun 130024,China;
2.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China)

Received:2013-10-14 Revised:2013-11-19 Published:2014-07-10 Online:2014-07-10
Contact: Shuang GAO

Abstract

Abstract: A newly Co²⁺ coordinated metal-organic framework had been successfully synthesized via one-step post-functionalization hydrothermal method and characterized through Fourier Transform Infrared Spectrometer, N₂ adsorption and Inductively Coupled Plasma. Using O₂ as oxidant, mesoporous cobalt metal-organic framework was investigated as a good performed heterogeneous catalytic material for various olefins epoxidation. Among them, the conversion of cyclooctene and selectivity of epoxycyclooctane were 94% and 91%, respectively, the turnover frequency was 509 h^-1. The PCN-100(Co) exhibited excellent stabilities in 5 recycles without any loss of its catalytic performance.

Key words: metal-organic framework, post-functionalization, olefins epoxidation, molecular oxygen

CLC Number:

O643.3

SHA Sha1,2, LI Jun2, ZHUANG Changfu2, LIU Shuxia1*, GAO Shuang2*. A New Mesoporous Cobalt Metal-organic Framework was Synthesized by Post-functionalization and Its Application for the Epoxidation of Olefins[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30511.

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A New Mesoporous Cobalt Metal-organic Framework was Synthesized by Post-functionalization and Its Application for the Epoxidation of Olefins

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